Aqueous microemulsions comprising alkoxylated alcohol nonionic surfactant in substainially water-insoluble solvent and oil

• US 5,736,500 A
• Filed: 03/29/1995
• Issued: 04/07/1998
• Est. Priority Date: 03/31/1994
• Status: Expired due to Fees

• Current Assignee: Lever Brothers Company, Division Of Conopco, Inc.
• Original Assignee: Lever Brothers Company, Division Of Conopco, Inc.
• Inventors: Martin, Alexander, Farnworth, Donald Michael
• Primary Examiner(s): HERTZOG, ARDITH E
• Application Number:
  US08/413,069
• Time in Patent Office: 1,105 Days
• Field of Search: 252/174, 252/173, 252/DIG. 14, 252/174.21, 252/DIG. 1, 252/170, 252/162, 252/174.11, 252/171, 510/417, 510/197, 510/238, 510/365, 510/421, 510/432, 510/505, 510/506
• US Class Current: 510/417
• CPC Class Codes: C11D 1/02 Anionic compounds C11D1/002, C11D1/004, C11D1/008 take precedence
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 1/83 Mixtures of non-ionic with anionic compounds
• CPC Class Codes: C11D 17/0021 Aqueous microemulsions
• CPC Class Codes: C11D 3/43 Solvents

Abstract

Improved microemulsions having a lower level of solvent, a lower level of oil, a more robust formulation and/or exhibiting equivalent if not better performance on fatty soils can be obtained by simultaneous selection of specific surfactants, specific oils and specific solvents. When all three of these components are selected in the manner described herein, a synergistic benefit is attained. The present invention provides a liquid, aqueous cleaning composition in the form of a stable emulsion having a dispersed phase diameter of 10-100 nanometres comprising:

a) at least 30 wt % water,

b) at least l wt % but not more than 40 wt % of a surfactant system comprising at least one alkoxylated alcohol nonionic surfactant and not more than 10 wt % on alkoxylated alcohol nonionic surfactant of anionic surfactant,

c) at least 2 wt % but not more than 20 wt % of a solvent having a solubility of less than 12% w/w in water, and,

d) at least 0.2 wt % but less than 10 wt % of a substantially water-insoluble oil which is a solvent for fats.

Claims

1. A liquid, aqueous cleaning composition in the form of a stable emulsion having a dispersed phase diameter of 10-100 nanometers comprising:

a) at least 30 wt. % water;

b) 1 to 24 wt. % ethoxylated nonionic surfactant selected from the group consisting of condensation products of ethylene oxide with aliphatic alcohols having from 8 to 22 carbon atoms in either straight or branched chain configuration,

c) 2.0 to 16 wt. % of a solvent selected from the group consisting of n-butanol, iso-butanol, n-butoxy propanol, di-propylene glycol monobutyl ether and mixtures thereof,

d) at least 0.2 but less than 10 wt. % of an oil selected from the group consisting of limonene, para-cymene, di-butyl ether, butyl butyrate, amyl acetate and mixtures thereof, and

wherein said composition comprises not more than 10 wt. % anionic surfactant based on the weight of total ethoxylated nonionic surfactant present.

2. Composition according to claim 1 comprising less than 5 wt. % anionic surfactant based on the weight of total ethoxylated nonionic surfactant present.

3. Composition according to claim 1 comprising 5.0 to 10 wt. % of said ethoxylated nonionic surfactant, 3.0 to 8.0 wt. % of said solvent and 0.8 to 4.0 wt. % of said oil.

4. Composition according to claim 1 comprising 20 to 24 wt. % of said ethoxylated nonionic surfactant, 12 to 16 wt. % of said solvent and 4.0 to 10.0 wt. % of said oil.

5. A method of cleaning a hard surface which comprises the step of contacting the surface with a composition according to claim 1.