Solid freeform fabrication methods

• US 5,738,817 A
• Filed: 02/08/1996
• Issued: 04/14/1998
• Est. Priority Date: 02/08/1996
• Status: Expired due to Term

• Current Assignee: University State Rutgers
• Original Assignee: Rutgers University
• Inventors: Safari, Ahmad, Jamalabad, Vikram R., Danforth, Stephen C., Langrana, Noshir, Bandyopadghyay, Amit, Agarwala, Mukesh, van Weeren, Remco
• Primary Examiner(s): Tentoni, Leo B.
• Application Number:
  US08/598,276
• Time in Patent Office: 796 Days
• Field of Search: 264/60, 264/63, 264/255, 264/308, 264/401, 264/497, 264/603, 264/604, 264/678, 419/1, 419/5, 419/36, 364/468.26
• US Class Current: 264/603
• CPC Class Codes: B22F 1/10 Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
• CPC Class Codes: B22F 1/103 containing an organic binding agent comprising a mixture of, or obtained by reaction of, two or more components other than a solvent or a lubricating agent
• CPC Class Codes: B22F 10/18 by mixing binder with metal in filament form, e.g. fused filament fabrication [FFF]
• CPC Class Codes: B22F 2999/00 Aspects linked to processes or compositions used in powder metallurgy
• CPC Class Codes: B29B 7/48 with intermeshing devices, e.g. screws
• CPC Class Codes: B29B 7/582 for discharging, e.g. doors
• CPC Class Codes: B29B 7/72 Measuring, controlling or regulating
• CPC Class Codes: B29B 7/823 Temperature control
• CPC Class Codes: B29B 7/826 Apparatus therefor
• CPC Class Codes: B29C 41/36 Feeding the material on to the mould, core or other substrate
• CPC Class Codes: B29C 64/165 using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
• CPC Class Codes: B32B 18/00 Layered products essentially comprising ceramics, e.g. refractory products
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 40/00 Auxiliary operations or equipment, e.g. for material handling
• CPC Class Codes: B33Y 40/20 Post-treatment, e.g. curing, coating or polishing
• CPC Class Codes: B33Y 50/02 for controlling or regulating additive manufacturing processes
• CPC Class Codes: B33Y 70/10 Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
• CPC Class Codes: C03B 19/066 for the production of quartz or fused silica articles other processes specially adapted for the production of quartz or fused silica articles C03B20/00
• CPC Class Codes: C04B 2235/383 Alpha silicon carbide
• CPC Class Codes: C04B 2235/6021 Extrusion moulding
• CPC Class Codes: C04B 2235/6026 : Computer aided shaping, e.g. rapid prototyping
• CPC Class Codes: C04B 2235/6562 : Heating rate
• CPC Class Codes: C04B 2235/6565 : Cooling rate
• CPC Class Codes: C04B 2235/658 : Atmosphere during thermal treatment
• CPC Class Codes: C04B 2235/6583 : Oxygen containing atmosphere, e.g. with changing oxygen pressures
• CPC Class Codes: C04B 2235/767 : Hexagonal symmetry, e.g. beta-Si3N4, beta-Sialon, alpha-SiC or hexa-ferrites
• CPC Class Codes: C04B 2235/77 : Density
• CPC Class Codes: C04B 2235/85 : Intergranular or grain boundary phases
• CPC Class Codes: C04B 2235/96 : Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
• CPC Class Codes: C04B 2235/9615 : Linear firing shrinkage
• CPC Class Codes: C04B 2235/9623 : Ceramic setters properties
• CPC Class Codes: C04B 2237/368 : Silicon nitride
• CPC Class Codes: C04B 2237/704 : of one or more of the ceramic layers or articles
• CPC Class Codes: C04B 35/14 : based on silica
• CPC Class Codes: C04B 35/584 : based on silicon nitride
• CPC Class Codes: C04B 35/62665 : Flame, plasma or melting treatment
• CPC Class Codes: C04B 35/62695 : Granulation or pelletising devices for shaping artificial aggregates from ceramic mixtures B28B1/004
• CPC Class Codes: C04B 35/632 : Organic additives
• CPC Class Codes: C04B 35/63408 : Polyalkenes
• CPC Class Codes: C04B 35/63432 : Polystyrenes
• CPC Class Codes: C04B 35/63436 : Halogen-containing polymers, e.g. PVC
• CPC Class Codes: C04B 35/6346 : Polyesters
• CPC Class Codes: C04B 35/63488 : Polyethers, e.g. alkylphenol polyglycolether, polyethylene glycol [PEG], polyethylene oxide [PEO]
• CPC Class Codes: C04B 35/63492 : Natural resins, e.g. rosin
• CPC Class Codes: C04B 35/638 : Removal thereof
• CPC Class Codes: C04B 35/64 : Burning or sintering processes C04B33/32 takes precedence ; powder metallurgy B22F
• CPC Class Codes: D01F 1/10 : Other agents for modifying properties
• CPC Class Codes: Y02P 10/25 : Process efficiency
• CPC Class Codes: Y02P 40/57 : Improving the yield, e-g- reduction of reject rates

Abstract

A fused deposition process is used to form three-dimensional solid objects from a mixture including a particulate composition dispersed in a binder. The article is formed by depositing the mixture in repeated layers of predefined thickness, with each layer solidifying before the next adjacent layer is dispensed. Following formation and a binder removal step, the article may be at least partially densified to achieve preselected properties. The process permits three-dimensional articles to be formed relatively quickly and inexpensively, without the need for molds or other tooling.

Claims

1. A process for making a three-dimensional article, comprising the steps of:

providing a mixture of a particulate composition dispersed in a binder;

feeding said mixture to a dispensing apparatus;

dispensing said mixture from said dispensing apparatus onto a build platform;

during said dispensing step, moving said dispensing apparatus and said build platform relative to one another in a plane defined by first and second directions and in a third direction orthogonal to said plane to form said mixture into a three-dimensional article; and

removing at least a portion of said binder from said article.

2. A process as claimed in claim 1, further comprising the step of forming said mixture into a solid flexible filament prior to said feeding step.

3. A process as claimed in claim 2, wherein said feeding step includes the step of feeding said filament to said dispensing apparatus in a solid state, and said dispensing step includes the step of heating said filament to place said mixture in a flowable fluid state.

4. A process as claimed in claim 2, further comprising the step of winding said filament around a spool prior to said feeding step, said filament being sufficiently flexible to uniformly wrap in a smooth curve around said spool and being sufficiently rigid to not be deformed by compressive forces during said feeding step.

5. A process as claimed in claim 1, wherein said particulate composition is selected from the group consisting of ceramic materials, elemental metals, steels, metal alloys and combinations thereof.

6. A process as claimed in claim 1, wherein said mixture includes at least about 10 volume percent of said particulate composition.

7. A process as claimed in claim 6, wherein said mixture includes at least about 40 volume percent of said particulate composition.

8. A process as claimed in claim 7, wherein said mixture includes at least about 50 volume percent of said particulate composition.

9. A process as claimed in claim 1, wherein said particulate composition includes between about 0.3 volume percent and about 19.0 volume percent of a dispersing agent.

10. A process as claimed in claim 9, wherein said dispersing agent is selected from the group consisting of oleyl alcohol (9-octadecen-1-ol), 3-aminopropyltriethoxysilane, and KRTTS (Titanium IV 2-propanolato tris (isooctadecanoato-o)).

11. A process as claimed in claim 1, wherein said binder is selected from the group consisting of thermoplastic binders, thermosetting binders, water soluble binders and organic solvent soluble binders.

12. A process as claimed in claim 1, wherein said mixture has an initial flowable fluid state and a solid state, said dispensing step including the steps of dispensing said mixture in said flowable fluid state and permitting said mixture to solidify on said build platform.

13. A process as claimed in claim 12, wherein said moving step includes the steps of moving said dispensing apparatus and said build platform relative to one another in a direction parallel to said plane to form a first layer of said mixture on said build platform, moving said dispensing apparatus and said build platform away from one another in said third direction by a predetermined layer thickness, and after the portion of said first layer adjacent said dispensing apparatus has solidified, dispensing a second layer of said mixture in said fluid state onto said first layer while simultaneously moving said build platform and said dispensing apparatus relative to one another in said direction parallel to said plane, whereby said second layer solidifies and adheres to said first layer.

14. A process as claimed in claim 13, further comprising the steps of forming multiple layers of said mixture on top of one another by repeated dispensing of said mixture in said fluid state from said dispensing apparatus as said build platform and said dispensing apparatus are moved relative to one another in said direction parallel to said plane, with said dispensing apparatus and said build platform being moved away from one another in said third direction by said predetermined layer thickness after each preceding layer has been formed, and with the dispensing of each successive layer being controlled to take place after said mixture in the preceding layer immediately adjacent said dispensing apparatus has solidified.

15. A process as claimed in claim 1, further comprising the steps of:

creating an image of said three-dimensional article on a computer, said image including a plurality of segments defining said article;

generating programmed signals corresponding to each of said segments in a predetermined sequence; and

moving said dispensing apparatus and said build platform relative to one another in response to said programmed signals.

16. A process as claimed in claim 1, wherein said binder removal step removes a major portion of said binder from said article.

17. A process as claimed in claim 1, wherein said binder removal step includes the steps of heating said article to a selected temperature according to a predetermined heating cycle.

18. A process as claimed in claim 17, wherein said binder removal step further includes the step of embedding said article in a powder material prior to said heating step.

19. A process as claimed in claim 17, further comprising the step of heating said article to a temperature greater than said selected temperature to at least partially bond said particulate composition together.

20. A process as claimed in claim 1, further comprising the step of at least partially densifying said article.

21. A process as claimed in claim 20, wherein said densification step includes the step of heating said article to a predetermined temperature to at least partially bond said particulate composition together.

22. A process as claimed in claim 1, further comprising the step of subjecting said article to a pressing step prior to said step of removing at least a portion of said binder.

23. A process as claimed in claim 1, wherein said moving step includes the step of moving said dispensing apparatus and said build platform relative to one another in a direction parallel to said plane according to a first predetermined pattern to form an outer boundary of said mixture on said build platform, said outer boundary defining an exterior surface of said article.

24. A process as claimed in claim 23, wherein said outer boundary defines an interior space in said article, and said moving step further includes the step of moving said dispensing apparatus and said build platform relative to one another in said direction parallel to said plane according to at least one other predetermined pattern to fill said interior space with said mixture.

25. A process as claimed in claim 24, further comprising the steps of creating an image of said three-dimensional article on a computer, said image including a plurality of segments defining said article, and

generating program signals corresponding to each of said segments in a predetermined sequence, wherein said program signals determine said movement of said dispensing apparatus and said build platform relative to one another in said first predetermined pattern and said at least one other predetermined pattern.

26. A process as claimed in claim 25, wherein said at least one other predetermined pattern includes a plurality of raster segments contacting said outer boundary at points of intersection, and said step of generating program signals includes the step of generating additional program signals to dispense an additional amount of said mixture at said points of intersection.

27. A process for making a three-dimensional article, comprising in the steps of:

creating an image of said three-dimensional article on a computer, said image including a plurality of segments defining said article;

generating program signals corresponding to each of said segments in a predetermined sequence;

providing a mixture of a particulate composition dispersed in a binder;

feeding said mixture to a dispensing apparatus;

dispensing said mixture in a flowable fluid state from said dispensing apparatus onto a build platform;

during said dispensing step, moving said dispensing apparatus and said build platform in response to said programmed signals relative to one another in a plane defined by first and second directions and in a third direction orthogonal to said plane in a predetermined sequence of movements such that said mixture is dispensed in free space as a plurality of segments sequentially formed so that the last dispensed segment overlies at least a portion of the preceding segment in contact therewith to thereby form said three-dimensional article; and

removing at least a portion of said binder from said article.

28. A process as claimed in claim 27, further comprising the step of at least partially densifying said article.

29. A process for making a three-dimensional article, comprising the steps of:

providing a mixture of a particulate composition dispersed in a binder;

feeding said mixture to a dispensing apparatus;

dispensing said mixture from said dispensing apparatus onto a build platform;

during said dispensing step, moving said dispensing apparatus and said build platform relative to one another in a plane defined by first and second directions and in a third direction orthogonal to said plane to form said mixture into a three-dimensional article;

removing at least a portion of said binder from said article by heating said article to a first temperature according to a predetermined heating cycle; and

heating said article to a second temperature greater than said first temperature to at least partially bond said particulate composition together.

30. A process for making a three-dimensional article, comprising of steps of:

providing a first mixture of one particulate composition dispersed in a binder;

providing a second mixture of another particulate composition dispersed in a binder, said second mixture being different than said first mixture;

feeding said first and second mixtures to a least one dispensing apparatus;

dispensing said first and second mixtures from said at least one dispensing apparatus onto a build platform;

during said dispensing step, moving said at least one dispensing apparatus and said build platform relative to one another in a plane defined by first and second directions and in a third direction orthogonal to said plane to form said first and second mixtures into a three-dimensional article, wherein said first and second mixtures are dispensed in preselected regions of said article; and

removing at least a portion of said binder from said article.

31. A process as claimed in claim 30, wherein said moving step includes the steps of moving said at least one dispensing apparatus and said build platform relative to one another in a direction parallel to said plane according to a first predetermined pattern while dispensing said first mixture to form an outer boundary of said first mixture on said build platform, said outer boundary defining an interior space, and moving said at least one dispensing apparatus and said build platform relative to one another in said direction parallel to said plane according to at least one other predetermined pattern while dispensing said second mixture to fill said interior space with said second mixture.

32. A process as claimed in claim 30, wherein said moving step includes the steps of moving said at least one dispensing apparatus and said build platform relative to one another in a direction parallel to said plane while dispensing said first mixture to form a first layer of said first mixture on said build platform, moving said at least one dispensing apparatus and said build platform away from one another in said third direction by a predetermined layer thickness, and moving said at least one dispensing apparatus and said build platform relative to one another in said direction parallel to said plane while dispensing said second mixture to form a layer of said second mixture on said first layer.

33. A process as claimed in claim 30, wherein said moving step includes the steps of moving said at least one dispensing apparatus and said build platform relative to one another in a direction parallel to said plane while simultaneously dispensing said first and second mixtures to form a layer of said first and second mixtures on said build platform, selected portions of said layer consisting essentially of said first mixture and remaining portions of said first layer consisting essentially of said second mixture.