System for removal of hydrogen sulfide from a gas stream

• US 5,738,834 A
• Filed: 04/04/1997
• Issued: 04/14/1998
• Est. Priority Date: 09/09/1996
• Status: Expired due to Term

• Current Assignee: URS Corporation (Aecom Incorporated)
• Original Assignee: Gas Research Institute (GTI Energy)
• Inventors: Deberry, David W.
• Primary Examiner(s): BHAT, NINA NMN
• Application Number:
  US08/835,140
• Time in Patent Office: 375 Days
• Field of Search: 422/171, 422/177, 55/223, 55/233, 55/238, 95/235, 423/242.7, 423/245.1, 423/226
• US Class Current: 422/177
• CPC Class Codes: B01D 53/1468 Removing hydrogen sulfide
• CPC Class Codes: B01D 53/52 Hydrogen sulfide
• CPC Class Codes: B01D 53/73 After-treatment of removed components
• CPC Class Codes: C01B 17/05 by wet processes

Abstract

A system for removing hydrogen sulfide from a gaseous stream such as one of natural gas. A sour gas stream containing H₂ S is contacted with a nonaqueous, water-insoluble sorbing liquor which comprises an organic solvent for elemental sulfur, dissolved elemental sulfur, an organic base to promote the reactions, and an organic solubilizing agent an agent suitable for maintaining the solubility of polysulfide intermediates which may otherwise separate when they are formed during operation of the process. Hydrogen sulfide (H₂ S) gas is sorbed into this liquor and then reacts with the dissolved sulfur in the presence of the base to form polysulfide molecules. The solution is then sent to a reactor where sufficient residence time is provided to allow the polysulfide forming reactions to reach the desired degree of completion. From the reactor, the solution flows to a regenerator where the solution is oxidized (e.g., by contact with air), forming dissolved elemental sulfur and water. The temperature of the solution is then lowered, forming sulfur crystals, which are easily removed by gravity settling, filtration, centrifuge, or other separation method. Enough sulfur remains dissolved in the solution following removal of the sulfur crystals that when this solution is reheated and returned to the absorber a sufficient amount of sulfur is present to react with the inlet H₂ S gas.

Claims

1. A system for removing H₂ S from a gaseous stream, comprising:

absorber means for receiving and contacting the H₂ S-containing gaseous stream with a sorbing liquor comprising a nonaqueous solvent containing dissolved sulfur, and a base having sufficient strength and concentration to drive the reaction converting H₂ S sorbed by said liquor to a nonvolatile polysulfide which is soluble in the sorbing liquor;

regenerator means downstream of said absorber means for oxidizing said sorbing liquor containing the dissolved polysulfide to convert said polysulfide to sulfur which remains dissolved in said liquor;

sulfur conversion means downstream of said regenerator means for converting at least part of said dissolved sulfur to solid particulate sulfur; and

separating and recycling means downstream of said regenerator means for separating said solid sulfur from the liquor and returning the regenerated liquor to said absorber means for recycling.

2. A system in accordance with claim 1, wherein said sulfur conversion means includes means for cooling the sorbing liquor, following oxidation of said polysulfide to sulfur, to a temperature at which solid sulfur particles precipitate.

3. A system in accordance with claim 1, further including a reaction chamber between said absorber means and said regenerator means, for increasing the residence time for said reaction converting said H₂ S to said polysulfide.

4. A system in accordance with claim 1, further including means for purifying said precipitated sulfur.

5. A system in accordance with claim 1, wherein said purifying means comprises a washing loop for removing residual traces of said nonaqueous solvent from said sulfur by washing the sulfur with methanol;

said loop including distillation means for recovering the methanol for recycling.

6. A system in accordance with claim 1, wherein byproduct sulfur salts are removed from the nonaqueous solvent, when said solvent is water insoluble, by water or aqueous alkalai washing said solvent.