Glasses for display panels

• US 5,741,746 A
• Filed: 02/14/1996
• Issued: 04/21/1998
• Est. Priority Date: 03/02/1995
• Status: Expired due to Term

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Kohli, Jeffrey T., Moffatt, Dawne M.
• Primary Examiner(s): Bell, Mark L.
• Assistant Examiner(s): TROILO, LOUIS
• Application Number:
  US08/593,097
• Time in Patent Office: 797 Days
• Field of Search: 501/65, 501/66, 501/69, 501/70
• US Class Current: 501/70
• CPC Class Codes: C03C 3/087 containing calcium oxide, e.g. common sheet or container glass
• CPC Class Codes: C03C 3/091 containing aluminium

Abstract

An aluminosilicate glass having a composition comprising, as calculated in weight percent on an oxide basis, of 40-57% SiO₂, 2.0-11% Al₂ O₃, 1-16% CaO, 8-21.5% SrO, 14-31.5% BaO, 0-3% MgO, and 0-4% B₂ O₃, the glass having a temperature not over 1450° C. at a viscosity of 20 MPa·s (200 poises), a CTE of 60-90×10^-7 /° C. and a strain point over 630° C.

Claims

1. A substrate for a flat panel display device wherein said substrate is comprised of a flat, transparent glass exhibiting a linear coefficient of thermal expansion (CTE) over the temperature range 0°

-300°

C. between 60-90×

10^-7 /°

C. and a strain point over 630°

C., said glass consisting essentially of an aluminosilicate having a composition as calculated in weight percent on an oxide basis, of 41-52% SiO₂, 2-12% Al₂ O₃, 4-16% CaO, 8-19% SrO, 16-29% BaO, 0-3% MgO, and 0-4% B₂ O₃.

2. A substrate glass in accordance with claim 1 which is manufactured by the float process, said glass having a liquidus viscosity greater than about 50 MPa·

s (500 poises).

3. A substrate according to claim 2, wherein said glass has a CTE of 79-85×

10^-7 /°

C. and a strain point over 645°

C.

4. A substrate according to claim 3, wherein said glass has a strain point over 655°

C.

5. A substrate according to claim 1, wherein the B₂ O₃ content of said glass is less than 1.5 weight percent.

6. A substrate according to claim 5, wherein the MgO content of said glass is less than about 1.5 weight percent.

7. In an emissive flat panel display comprising two glass substrates maintained in an opposed, spaced relationship, the improvement comprising a substrate in accordance with claim 3.

8. A substrate according to claim 5, wherein said glass has less than about 5 percent by weight alkali metal content.

9. A substrate according to claim 6, wherein said glass has less than about 1.0 percent alkali metal content.

10. In a direct current powered emissive flat panel display comprising two glass substrates maintained in an opposed, spaced relationship, the improvement comprising a substrate in accordance with claim 9.

11. A substrate according to claim 1, wherein said glass has a strain point over 655°

C.

12. A substrate according to claim 3, wherein the B₂ O₃ content of said glass is less than about 1.5 weight percent.

13. A substrate according to claim 3, wherein the MgO content of said glass is less than about 1.5 weight percent, and the alkali metal content is less than about 5 percent by weight.

14. A substrate according to claim 1, wherein the glass has a weight loss less than 5.0 mg/cm² when immersed in 5% HCl at 95°

C. for one hour.

21. A substrate in accordance with claim 1, wherein the glass in essentially free of B₂ O₃.

22. A substrate in accordance with claim 1, wherein said glass has an alkali content between 1-5 weight percent.

23. A substrate in accordance with claim 21, wherein the glass has an alkali content between about 1 and 5 weight percent.

15. A glass exhibiting a linear coefficient of thermal expansion (CTE) over the temperature range 0°

-300°

C. between 60-90×

10^-7 /°

C. and a strain point over 630°

C., said glass consisting essentially of an aluminosilicate having a composition as calculated in weight percent on an oxide basis, of 41-52% SiO₂, 2-12% Al₂ O₄, 4-16% CaO, 8-19% SrO, 16-29% BaO, 0-3% MgO, and 0-4% B₂ O₃.

16. A glass in accordance with claim 15 which is manufactured by the float process, said glass having a liquidus viscosity greater than about 50 MPa·

s (500 poises).

17. A glass according to claim 16, wherein said glass has a CTE of 79-85×

10^-7 /°

C. and a strain point over 645°

C.

18. A glass according to claim 17, wherein said glass has a strain point over 655°

C.

19. A glass according to claim 17, wherein the B₂ O₃ content of said glass is less than about 1.5 weight percent, and the alkali metal content is less than about 5 percent by weight.

20. A glass according to claim 19, wherein the MgO content of said glass is less than about 1.5 weight percent.