Acoustically active plastisols

• US 5,741,824 A
• Filed: 12/07/1995
• Issued: 04/21/1998
• Est. Priority Date: 06/07/1993
• Status: Expired due to Fees

• Current Assignee: Teroson G.M.B.H. (Henkel AG & Co KGaA)
• Original Assignee: Teroson G.M.B.H. (Henkel AG & Co KGaA)
• Inventors: Butschbacher, Gunter, Wesch, Karl, Rein, Manfred, Ruch, Klaus
• Primary Examiner(s): COONEY, JOHN M
• Application Number:
  US08/557,038
• Time in Patent Office: 866 Days
• Field of Search: 521/149, 521/73, 521/75, 521/146, 428/461, 428/500, 427/100, 427/195, 427/421
• US Class Current: 427/195
• CPC Class Codes: B60R 13/08 Insulating elements, e.g. for sound insulation sound insulating linings for trains B61D17/185; drivers' cabs for load-carrying vehicles insulated against vibrations or noise B62D33/0604; thermal or acoustic insulation of engines F02B77/11; damping of sounds using compensation by electro-acoustic methods G10K11/178
• CPC Class Codes: B60R 13/0861 for covering undersurfaces of vehicles, e.g. wheel houses
• CPC Class Codes: C08K 5/0016 Plasticisers
• CPC Class Codes: C08L 25/08 Copolymers of styrene C08L29/08, C08L35/06, C08L55/02 take precedence
• CPC Class Codes: C08L 2666/28 Non-macromolecular organic substances
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C08L 33/12 Homopolymers or copolymers of methyl methacrylate
• CPC Class Codes: C09D 125/08 Copolymers of styrene C09D129/08, C09D135/06, C09D155/02 take precedence
• CPC Class Codes: C09D 133/12 Homopolymers or copolymers of methyl methacrylate
• CPC Class Codes: G10K 11/162 Selection of materials
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers

Abstract

The invention relates to acoustically active sprayable plastisol compositions based on styrene copolymers and/or alkyl methacrylate homopolymers and/or copolymers of methyl methacrylate which, in addition to the favorable abrasion properties and corrosion-preventing properties of the plastisols, have a good vibration-damping effect and distinctly reduce the noise caused by particle impact (chippings, water, sand).

Claims

1. In a method of reducing sound emission and mechanical vibration in a metal plate, the improvement comprising;

applying to the metal plate a sprayable plastisol composition comprising a powder-form organic polymer and a plasticizer for the organic polymer and gelling the pastisol composition, wherein said plastisol composition comprises;

a) 5 to 60% by weight of at least one powder-form polymer selected from the group consisting of i) copolymers consisting essentially of styrene residues and 2 to 20% by weight of the polymer of residues of an olenfinically unsaturated carboxylic acid coupling monomer, ii) copolymers consisting essentially of styrene, 2 to 20% by weight of residues of an olefinically unsaturated carboxylic acid coupling monomer, and 0.2 to 5% by weight of residues of an olefinically unsaturated crosslinking comonomer having a functional group which is not a carboxyl group and which does not react during the radical polymerization, iii) alkyl methacrylate homopolymers, iv) copolymers consisting essentially of alkyl methacrylate residues and from 0.5% to 4% by weight of residues of an olefinically unsaturated coupling or crosslinking comonomer having a functional group which does not react during the radical polymerization, v) copolymers of alkyl methacrylate and methyl methacrylate, vi) copolymers consisting essentially of alkyl methacrylate residues, methyl methacrylate residues, and from 0.5% to 4% by weight of residues of an olefinically unsaturated coupling or crosslinking comonomer having a functional group which does not react during the radical polymerization, and vii) mixtures of at least two of said homopolymers and copolymers of groups i) to vi);

b) 5 to 65% by weight of plasticizers;

c) 0 to 40% by weight of fillers; and

d) 2 to 40% by weight of reactive additives.

2. The method as claimed in claim 1 wherein said coating reduces the noise caused by particle impact.

3. The method as claimed in claim 1 wherein the copolymer of alkyl methacrylate and methyl methacrylate contains 5 to 48% by weight of residues of a C_2-8 alkyl ester of methacrylic acid and 0.5 to 4% by weight of residues a coupling or crosslinking comonomer, based on the monomer composition.

4. The method as claimed in claim 1 wherein said alkyl methacrylate homopolymer is a C_1-8 a alkyl ester of methacrylic acid.

5. The method as claimed in claim 1 wherein said alkyl methacrylate of said copolymer of an alkyl methacrylate and 0.5 to 4% by weight of a coupling or crosslinking comonomer is a C₁.8 alkyl ester of mathacrylic acid.

6. The method as claimed in claim 1 wherein said plastisol composition further contains a blowing agent.

7. The method as claimed in claim 6 wherein said blowing agent is selected from the group consisting of azo compounds, N-nitroso compounds, sulfonyl hydrazides or sulfonyl semicarbazides.

8. The method as claimed in claim 1 wherein said coating also protects said metal plate against abrasion or corrosion.

9. The method as claimed in claim 1 wherein said metal plate is in the wheel arches or underbody of a motor vehicle.

10. The method as claimed in claim 1 wherein said olefinically unsaturated carboxylic acid is selected from the group consisting of methacrylic acid, acrylic acid, itaconic acid, and mixtures thereof.

11. In a method of reducing sound emission and mechanical vibration in automotive vehicles, the improvement comprising applying to a rigid substrete of the automotive vehicle a sprayable plastisol composition comprising powder-form organic polymers and plasticizers, wherein said plastisol composition is comprised of:

a) 5 to 60% by weight of at least one powder-form polymer selected from the group consisting of i) copolymers consisting essentially of styrene residues end 2 to 20% by weight of the copolymer of residues of an olefinically unsaturated carboxylic acid selected from the group consisting of methacrylic acid, acrylic acid, itaconic acid, and mixtures thereof, ii) copolymers consisting essentially of styrene residues, 2 to 20% by weight of residues of an olefinically unsaturated carboxylic acid selected from the group consisting of methacrylic acid, acrylic acid, itaconic acid, and mixtures of two or more thereof, and 0.2 to 5% by weight of residues of an olefinically unsaturated crosslinking comonomer having a functional group which is not a carboxyl group and which does not react during the radical polymerization, iii) C_2-8 alkyl methacrylate homopolymers, iv) copolymers consisting essentially of C₂₈ alkyl methacrylate residues and from 0.5% to 4% by weight of residues a coupling or crosslinking comonomer selected from the group consisting of N-vinyl imidazole, acrylic acid, methacrylic acid, and itaconic acid, v) copolymers of a C_2-8 alkyl methacrylate and methyl methacrylate, vi) copolymers consisting essentially of C_2-8 alkyl methacrylate residues, methyl methacrylate residues, and from 0.5% to 4% by weight of a coupling or crosslinking comonomer selected from the group consisting of N-vinyl imidazole, acrylic acid, end methacrylic acid, and vii) mixtures of at least two of said homopolymers and copolymers of groups i) to vi);

b) 5 to 65% by weight of plasticizers;

c) 0 to 40% by weight of fillers;

d) 2 to 40% by weight of reactive additives;

end

e) a blowing agent selected from the group consisting of azo compounds, N-nitroso compounds, sulfonyl hydrazides or sulfonyl semicarbazides and gelling the plastisol composition.

12. In a method of reducing sound emission and mechanical vibration in automotive vehicles comprising metal, the improvement comprising filling the cavities of the vehicle with a sprayable plastisol composition comprising powder-form organic polymers end plasticizers, wherein said plastisol composition is comprised of:

a) 5 to 60% by weight of at least one powder-form polymer selected from the group consisting of i) copolymers comprised of styrene residues and 2 to 20% by weight of residues of an olefinically unsaturated carboxylic acid, ii) copolymers comprised of styrene residues, 2 to 20% by weight of residues of an olefinically unsaturated carboxylic acid, and 0.2 to 5% by weight of residues of crosslinking comonomer having olefinic unsaturation and having a functional group which is not a carboxyl group end which does not react during radical polymerization, iii) alkyl methacrylate homopolymers, iv) copolymers of an alkyl methacrylate and from 0.5% to 4% by weight of a coupling or cross-linking comonomer, v) copolymers of an alkyl methacrylate and methyl methacrylate, vi) copolymers of an alkyl methacrylate, methyl methacrylate, and from 0.5% to 4% by weight of a coupling or crosslinking comonomer, and vii) mixtures of at least two of said homopolymers and copolymers of groups i) to vi);

b) 5 to 65% by weight of plasticizers;

c) 0 to 40% by weight of fillers; and

d) 2 to 40% by weight of reactive additives; and

celling the plastisol composition.

13. The method as claimed in claim 12 wherein said filling prevents air vibration in the cavities.

14. The method as claimed in claim 12 wherein the copolymer of an alkyl methacrylate and methyl methacrylate copolymer contains 5 to 48% by weight of a C_2-8 alkyl ester of methacrylic acid and 0.5 to 4% by weight of a coupling or crosslinking comonomer, based on the monomer composition.

15. The method as claimed in claim 12 wherein said alkyl methacrylate homopolymer is a polymer of C_1-8 alkyl esters of methacrylic acid.

16. The method as claimed in claim 12 wherein said alkyl methacrylate of said copolymer of an alkyl methacrylate and 0.5 to 4% by weight of a coupling or crosslinking comonomer is a C_1-8 alkyl ester of methacrylic acid.

17. The method as claimed in claim 12 wherein said plastisol composition further contains a blowing agent.

18. The method as claimed in claim 17 wherein said blowing agent is selected from the group consisting of azo compounds, N-nitroso compounds, sulfonyl hydrazides or sulfonyl semicarbazides.

19. The method as claimed in claim 12 wherein said filling also protects said metal against abrasion or corrosion.

20. The method as claimed in claim 12 wherein said cavity is in the roof cross-ties or the A-, B-, or, C-pillars of a motor vehicle.

21. The method as claimed in claim 12 wherein said olefinically unsaturated carboxylic acid is selected from the group consisting of methacrylic acid, acrylic acid, itaconic acid, and mixtures of two or more thereof.

22. In a method of reducing sound emission and mechanical vibration in automotive vehicles, the improvement comprising applying to a cavity of a motor vehicle a sprayable plastisol composition comprising a powder-form organic polymer and a plasticizer, wherein said plastisol composition is comprised of;

a) 5 to 60% by weight of at least one powder-form polymer selected from the group consisting of i) copolymers comprised of styrene residues and 2 to 20% by weight of residues of an olefinically unsaturated carboxylic acid selected from the group consisting of methacrylic acid, acrylic acid, itaconic acid, and mixtures of two or more thereof, ii) copolymers comprised of styrene residues, 2 to 20% by weight of residues of an olefinically unsaturated carboxylic acid selected from the group consisting of methacrylic acid, acrylic acid, itaconic acid, and mixtures of two or more thereof, and 0.2 to 5% by weight of residues of another crosslinking comonomer, iii) C_2-8 alkyl methacrylate homopolymers, iv) copolymers of a C₂₈ alkyl methacrylate and from 0.5% to 4% by weight of a coupling or crosslinking comonomer selected from the group consisting of N-vinyl imidazole, acrylic acid, methacrylic acid, and itaconic acid, v) copolymers of a C_2-8 alkyl methacrylate and methyl methacrylate, vi) copolymers of a C₂₈ alkyl methacrylate, methyl methacrylate, and from 0.5% to 4% by weight of a coupling or crosslinking comonomer selected from the group consisting of N-vinyl imidazole, acrylic acid, and methacrylic acid, and vii) mixtures of at least two of said homopolymers and copolymers of groups i) to vi);

b) 5 to 65% by weight of plasticizers;

c) 0 to 40% by weight of fillers;

d) 2 to 40% by weight of reactive additives; and

e) a blowing agent selected from the group consisting of azo compounds, N-nitroso compounds, sulfonyl hydrazides or sulfonyl semicarbazides.