High power, high energy, hybrid electrode and electrical energy storage device made therefrom

• US 5,744,258 A
• Filed: 12/23/1996
• Issued: 04/28/1998
• Est. Priority Date: 12/23/1996
• Status: Expired due to Term

• Current Assignee: Amperex Technology Limited (TDK Corporation)
• Original Assignee: Motorola, Inc. (Motorola Solutions, Inc.)
• Inventors: Thomas, George, Anani, Anaba A., Li, Changming, Bai, Lijun, Howard, Jason N., Denton, III, Frank R., Lian, Ke Keryn, Wu, Han
• Primary Examiner(s): KALAFUT, STEPHEN J
• Application Number:
  US08/774,048
• Time in Patent Office: 491 Days
• Field of Search: 429/9, 429/209, 429/219, 429/213, 429/218, 429/3
• US Class Current: 429/3
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/0585 of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
• CPC Class Codes: H01M 4/04 Processes of manufacture in general
• CPC Class Codes: H01M 4/0402 Methods of deposition of the material
• CPC Class Codes: H01M 4/0404 by coating on electrode collectors
• CPC Class Codes: H01M 4/13 Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
• CPC Class Codes: H01M 4/131 Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
• CPC Class Codes: H01M 4/133 Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
• CPC Class Codes: H01M 4/137 Electrodes based on electro-active polymers
• CPC Class Codes: H01M 4/36 Selection of substances as active materials, active masses, active liquids
• CPC Class Codes: H01M 4/364 as mixtures
• CPC Class Codes: H01M 4/366 as layered products
• CPC Class Codes: H01M 4/602 Polymers
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A hybrid electrode for a high power, high energy, electrical storage device contains both a high-energy electrode material (42) and a high-rate electrode material (44). The two materials are deposited on a current collector (40), and the electrode is used to make an energy storage device that exhibits both the high-rate capability of a capacitor and the high energy capability of a battery. The two materials can be co-deposited on the current collector in a variety of ways, either in superimposed layers, adjacent layers, intermixed with each other or one material coating the other to form a mixture that is then deposited on the current collector.

Claims

1. A hybrid electrode for a high power, high energy, electrical storage device, said hybrid electrode comprising:

a current collector;

a first electroactive material; and

a second electroactive material,

wherein;

the first electroactive material has a higher energy density than the second electroactive material;

the second electroactive material has a higher rate capability than the first electroactive material; and

one of the first and second electroactive materials is formed as a first discrete layer in contact with the current collector, and the other of the first and second electroactive materials is formed as a second discrete layer deposited onto the first discrete layer.

2. The hybrid electrode as described in claim 1, wherein the hybrid electrode comprises an anode of the electrical storage device, and the first electroactive material is selected from the group consisting of cadmium, metal hydrides, lead, and zinc.

3. The hybrid electrode as described in claim 1, wherein the hybrid electrode comprises a cathode of the electrical storage device, and the first electroactive material is selected from the group consisting of nickel oxide, lead oxide, and silver.

4. The hybrid electrode as described in claim 1, wherein the second electroactive material is selected from the group consisting of high-surface area carbon, ruthenium oxide, silver oxide, cobalt oxide, and conducting polymers.

5. The hybrid electrode as described in claim 1, wherein the first electroactive material comprises one or more materials selected from the group consisting of La, Li, Na, Al, Fe, Zn, Cd, Pb, Sn, Bi, V, Mn, Co, Ni, Ag and their alloys, oxides, hydroxides, hydrides, carbides, nitride or sulfites, and carbon, polyaniline, polythiophene, polyfluorophenylthiopene, polypyrolle, n or p-doped polymers, redox polymers, and mixtures thereof.

6. The hybrid electrode as described in claim 1, wherein the second electroactive material comprises one or more materials selected from the group consisting of Nb, Hf Ti, Ta, Li, Fe, Zn, Sn, Ru, Ag, Pt, Ir, Pb, Mo, W, Ni, Co and their oxides, hydroxides, hydrides, carbides, nitride or sulfites, and carbon, polyaniline, polythiophene, polyfluorophenylthiopene, polypyrolle, n or p-doped polymers, redox polymers, and mixtures thereof.

7. The hybrid electrode as described in claim 1 wherein the electrical storage device comprises:

the hybrid electrode;

another electrode; and

an electrolyte positioned between the hybrid electrode and the other electrode.

8. A hybrid electrode for an energy storage device, the hybrid electrode comprising:

a current collector;

a first electroactive material; and

a second electroactive material,

wherein;

the first electroactive material has a higher energy density than the second electroactive material;

the second electroactive material has a higher rate capability than the first electroactive material; and

the second electroactive material is at least partially coated by the first electroactive material.

9. The hybrid electrode as described in claim 8, wherein the hybrid electrode comprises an anode of the electrical storage device, and the first electroactive material is selected from the group consisting of cadmium, metal hydrides, lead, and zinc.

10. The hybrid electrode as described in claim 8, wherein the hybrid electrode comprises a cathode of the electrical storage device, and the first electroactive material is selected from the group consisting of nickel oxide, lead oxide, and silver.

11. The hybrid electrode as described in claim 8, wherein the second electroactive material is selected from the group consisting of high-surface area carbon, ruthenium oxide, silver oxide, cobalt oxide, and conducting polymers.

12. The hybrid electrode of claim 8, wherein the first electroactive material comprises one or more materials selected from the group consisting of La, Li, Na, Al, Fe, Zn, Cd, Pb, Sn, Bi, V, Mn, Co, Ni, Ag and their alloys, oxides, hydroxides, hydrides, carbides, nitride or sulfites, and carbon, polyaniline, polythiophene, polyfluorophenylthiopene, polypyrolle, n or p-doped polymers, redox polymers, and mixtures thereof.

13. The hybrid electrode as described in claim 8, wherein the second electroactive material comprises one or more materials selected from the group consisting of Nb, Hf Ti, Ta, Li, Fe, Zn, Sn, Ru, Ag, Pt, Ir, Pb, Mo, W, Ni, Co and their oxides, hydroxides, hydrides, carbides, nitride or sulfites, and carbon, polyaniline, polythiophene, polyfluorophenylthiopene, polypyrolle, n or p-doped polymers, redox polymers, and mixtures thereof.

14. The hybrid electrode of claim 8, wherein the energy storage device comprises:

the hybrid electrode;

another electrode; and

an electrolyte positioned between the hybrid electrode and the other electrode.

15. A hybrid electrode for an energy storage device, the hybrid electrode comprising:

a current collector having separate first and second regions located on a surface thereof;

a first electroactive material disposed on the first region of the current collector; and

a second electroactive material disposed on the second region of the current collector,

wherein the fist electroactive material has a higher energy density than the second electroactive material, and the second electroactive material has a higher rate capability than the first electroactive material.

16. The hybrid electrode of claim 15, wherein the first electroactive material comprises one or more materials selected from the group consisting of La, Li, Na, Al, Fe, Zn, Cd, Pb, Sn, Bi, V, Mn, Co, Ni, Ag and their alloys, oxides, hydroxides, hydrides, carbides, nitride or sulfites, and carbon, polyaniline, polythiophene, polyfluorophenylthiopene, polypyrolle, n or p-doped polymers, redox polymers, and mixtures thereof.

18. The hybrid electrode of claim 15, wherein the second electroactive material comprises one or more materials selected from the group consisting of Nb, Hf Ti, Ta, Li, Fe, Zn, Sn, Ru, Ag, Pt, Ir, Pb, Mo, W, Ni, Co and their oxides, hydroxides, hydrides, carbides, nitride or sulfites, and carbon, polyaniline, polythiophene, polyfluorophenylthiopene, polypyrolle, n or p-doped polymers, redox polymers, and mixtures thereof.

17. A hybrid electrode consisting of a first electroactive material comprising amorphous carbon intercalated with lithium, and a second electroactive material comprising polyfluorophenylthiopene, wherein the first electroactive material has a higher energy density than the second electroactive material, and wherein the second electroactive material has a higher rate capability than the first electroactive material.