Antistatic composition containing anionic and cationic surface active agents wherein both surface active agents comprises polyoxyalkylene groups

• US 5,744,295 A
• Filed: 08/30/1994
• Issued: 04/28/1998
• Est. Priority Date: 09/24/1993
• Status: Expired due to Term

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Caesar, Julian Claudius, Gray, Colin James, Pitt, Alan Robert
• Primary Examiner(s): Young, Christopher G.
• Application Number:
  US08/298,009
• Time in Patent Office: 1,337 Days
• Field of Search: 430/527, 430/529, 252/500, 252/511
• US Class Current: 430/527
• CPC Class Codes: C09K 3/16 Anti-static materials
• CPC Class Codes: G03C 1/38 Dispersants; Agents facilitating spreading
• CPC Class Codes: G03C 1/89 Macromolecular substances therefor
• CPC Class Codes: G03C 2200/48 Polyoxyethylene

Abstract

An antistatic composition comprises a hydrophilic colloid, e.g. gelatin, and a plurality of surface active agents comprising an anionic surface active agent and a cationic surface active agent. At least one of the anionic and cationic surface active agents comprises at least one polyoxyalkylene group. The accumulation of electrostatic charge on an element, e.g a photographic element, may be prevented by coating a surface of the element with an aqueous dispersion of the antistatic composition and drying the coated surface.

Claims

1. An antistatic composition comprising a hydrophilic colloid, an anionic surface active agent and a cationic surface active agent, wherein both the cationic and anionic surface active agents comprise at least one polyoxyalkylene group.

2. A composition according to claim 1 wherein the hydrophilic colloid is gelatin.

3. A composition according to claim 1 wherein the cationic surface active agent and anionic surface active agent are present in the antistatic composition in a combined amount of from 0.5 to 1.5 percent by weight based on the weight of the composition.

4. A composition according to claim 1 wherein the molar ratio of cationic to anionic surface active agent is from 1:

2 to 2;

1.

5. A composition according to claim 1 wherein the cationic surface active agent is a quaternised ethoxylated amine.

6. A composition according to claim 1 wherein the anionic surface active agent is an ethoxylated phosphate, sulphate, sulphonate or sulphosuccinate.

7. An element comprising a support having thereon a layer of an antistatic composition according to claim 1.

8. An element according to claim 7, further comprising at least one photographic silver halide emulsion layer.

9. An element according to claim 8 wherein the hydrophilic colloid of the antistatic composition is gelatin.

10. An element according to claim 8 wherein the cationic surface active agent and anionic surface active agent are present in the antistatic composition in a combined amount of from 0.5 to 1.5 percent by weight based on the weight of the composition.

11. An element according to claim 8 wherein the molar ratio of cationic to anionic surface active agent in the antistatic composition is from 1:

2 to 2;

1.

12. An element according to claim 8 wherein the cationic surface active agent in the antistatic composition is a quaternised ethoxylated amine.

13. An element according to claim 12 wherein the anionic surface active agent in the antistatic composition is an ethoxylated phosphate, sulphate, sulphonate or sulphosuccinate.

14. An element according to claim 8 wherein the anionic surface active agent in the antistatic composition is an ethoxylated phosphate, sulphate, sulphonate or sulphosuccinate.

15. An element according to claim 8 wherein the layer of an antistatic composition is coated on the opposite surface of the support from the photographic silver halide emulsion layer.

16. A method of preventing the accumulation of electrostatic charge on an element which comprises coating a surface of the element with an aqueous dispersion of an antistatic composition according to claim 1 and drying the coated surface.

17. A method according to claim 16 wherein the hydrophilic colloid of the antistatic composition is gelatin.

18. A method according to claim 16 wherein the cationic surface active agent is a quaternised ethoxylated amine, the anionic surface active agent is an ethoxylated phosphate, sulphate, sulphonate or sulphosuccinate, and the molar ratio of cationic to anionic surface active agent in the antistatic composition is from 1:

2 to 2;

1.