Mirror including a glass substrate and a pyrolytic silicon reflecting layer

• US 5,745,291 A
• Filed: 02/10/1997
• Issued: 04/28/1998
• Est. Priority Date: 07/11/1992
• Status: Expired due to Fees

• Current Assignee: Pilkington NA
• Original Assignee: Pilkington NA
• Inventors: Jenkinson, Timothy
• Primary Examiner(s): Henry, Jon W.
• Application Number:
  US08/796,457
• Time in Patent Office: 442 Days
• Field of Search: 359/584, 359/585, 359/586, 359/589, 359/580, 359/884
• US Class Current: 359/586
• CPC Class Codes: C03C 17/3435 comprising a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3482 comprising silicon, hydrogenated silicon or a silicide
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3615 Coatings of the type glass/metal/other inorganic layers, at least one layer being non-metallic
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3626 one layer at least containing a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3634 one layer at least containing carbon, a carbide or oxycarbide
• CPC Class Codes: C03C 17/3649 made of metals other than silver
• CPC Class Codes: C03C 17/3663 specially adapted for use as mirrors
• CPC Class Codes: C03C 2217/734 comprising an alternation of high and low refractive indexes
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: G02B 5/0833 comprising inorganic materials only
• CPC Class Codes: G02B 5/0858 the reflecting layers comprising a single metallic layer with one or more dielectric layers
• CPC Class Codes: G02B 5/26 Reflecting filters G02B5/28 takes precedence

Abstract

A method of producing mirrors comprising depositing onto a ribbon of hot glass during the production process a coating comprising a reflecting layer and at least two reflection enhancing layers whereby the mirrors have a visible light reflection of at least 70%. There is also provided a mirror having such a coating. In a preferred embodiment the coating comprises: an inner layer having a refractive index of at least 1.6; an intermediate layer of relatively low refractive index and; an outer layer having a refractive index of at least 1.6; the intermediate layer having a refractive index less than the refractive index of either said inner layer or said outer layer and less than 3, provided that at least one of said inner and outer layers is of silicon, the aggregate refractive index of the inner and outer layers is at least 5.5, and the thicknesses of the layers are such that the mirror has a visible light reflection of at least 70%. In an alternative embodiment, one of the inner and outer layers may instead be composed of a low refractive index reflective metal.

Claims

1. A mirror comprising a glass substrate and a reflective coating carried thereon wherein said coating is selected from the group consisting of:

coating (1);

a plurality of layers having at least an inner layer nearest the glass substrate, an outer layer furthest from the glass substrate, and an intermediate layer between the inner and outer layers, wherein the inner layer is a pyrolytic silicon reflecting layer of optical thickness λ

/4, where λ

is a wavelength of light in the visible region of the spectrum, and the intermediate and outer layers are reflection enhancing layers, and

coating (2);

a plurality of layers having at least an inner layer nearest the glass substrate, an outer layer furthest from the glass substrate, and an intermediate layer between the inner and outer layers, wherein the outer layer is a pyrolytic silicon reflecting layer of optical thickness λ

/4, where λ

is a wavelength of light in the visible region of the spectrum, and the intermediate and inner layers are reflection enhancing layers;

said mirror having a visible light reflection of at least 70%.

2. A mirror according to claim 1 wherein said reflecting layer and reflective enhancing layers each has an optical thickness of 125 nm+/-25%.

3. A mirror according to claim 2 wherein the inner and outer layers each independently has a refractive index within the range from about 1.9 to 3.0 and the intermediate layer has a refractive index of less than 1.8.

4. A mirror according to claim 1 wherein said inner layer is in contact with said glass substrate.

5. A mirror according to claim 2 wherein said intermediate layer comprises a plurality of sub-layers.

6. A mirror according to claim 1 wherein the reflection enhancing layers comprise an intermediate layer of the coating of relatively low refractive index and a layer adjacent to the intermediate layer of relatively high refractive index.

7. A mirror according to claim 6 wherein the reflecting layer is of relatively high refractive index.

8. A mirror according to claim 6 wherein the reflection enhancing layer of relatively high refractive index is silicon.

9. A mirror according to claim 6 wherein the reflection enhancing layer of relatively high refractive index is of tin oxide, titanium oxide or a silicon oxide material.

10. A mirror according to claim 9 wherein the silicon oxide material contains carbon.

11. A mirror according to claim 6 wherein the reflection enhancing layer of relatively low refractive index has a refractive index below 1.8.

12. A mirror according to claim 6 wherein the reflection enhancing layer of relatively low refractive index comprises a layer of silicon oxide.

13. A mirror according to claim 1 which additionally comprises a protective layer on the coating.

14. A mirror according to claim 1 further comprising an obscuring layer disposed over a back surface of the mirror.