Free form fabrication of metallic components

• US 5,745,834 A
• Filed: 09/19/1995
• Issued: 04/28/1998
• Est. Priority Date: 09/19/1995
• Status: Expired due to Term

• Current Assignee: Teledyne Scientific & Imaging, LLC (Teledyne Technologies Incorporated)
• Original Assignee: Rockwell International Corporation
• Inventors: Burkett, Robert, Bampton, Clifford C., Ryang, Hong-Son
• Primary Examiner(s): Jordan, Charles T.
• Assistant Examiner(s): CHI, ANTHONY
• Application Number:
  US08/530,770
• Time in Patent Office: 952 Days
• Field of Search: 419/37, 419/47, 419/49, 419/52, 419/54
• US Class Current: 419/37
• CPC Class Codes: B22F 1/09 Mixtures of metallic powders
• CPC Class Codes: B22F 1/10 Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
• CPC Class Codes: B22F 10/16 by embedding the binder within the powder bed
• CPC Class Codes: B22F 10/34 of powder characteristics, e.g. density, oxidation or flowability
• CPC Class Codes: B22F 10/37 of powder bed aspects, e.g. density
• CPC Class Codes: B22F 10/43 characterised by material
• CPC Class Codes: B22F 10/47 characterised by structural features
• CPC Class Codes: B22F 2003/1042 with support for articles to be sintered
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B22F 2998/10 Processes characterised by the sequence of their steps
• CPC Class Codes: B22F 3/10 Sintering only
• CPC Class Codes: B22F 3/1021 Removal of binder or filler removal of binder from ceramics C04B35/638
• CPC Class Codes: B29K 2503/06 Metal powders, metal carbides or the like
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 40/00 Auxiliary operations or equipment, e.g. for material handling
• CPC Class Codes: B33Y 40/20 Post-treatment, e.g. curing, coating or polishing
• CPC Class Codes: B33Y 70/00 Materials specially adapted for additive manufacturing
• CPC Class Codes: Y02P 10/25 Process efficiency

Abstract

A method of free form fabrication of metallic components, typically using computer aided design data, comprises selective laser binding and transient liquid sintering of blended powders. The powder blend includes a base metal alloy, a lower melting temperature alloy, and a polymer binder that constitutes approximately 5-15% of the total blend. A preform part is built up, layer-by-layer, by localized laser melting of the polymer constituent, which rapidly resolidifies to bind the metal particles. The binder is eliminated from the preform part by heating in a vacuum furnace at low atmospheric pressure. The preform part may require support during elimination of the polymer binder and subsequent densification by controlled heat treatment. Densification is performed at a temperature above the melting point of the lower temperature alloy but below the melting point of the base metal alloy to produce transient liquid sintering of the part to near full density with desired shape and dimensional tolerances. The densified part may be subjected to a final hot isostatic pressing (HIP) treatment to close residual porosity and complete the chemical homogenization of the part. Elimination of residual porosity improves fatigue properties of part, and homogenization improves ambient temperature ductility, toughness, and high temperature strength. An advantage of the process is rapid production of complex shaped metal prototypes and complete small batch production runs of high cost metal components without special tooling or machining operations.

Claims

1. A method of selective sintering of a powder, comprising the steps of:

mixing powders of a base metal, a lower melting temperature metal, and a polymer binder to form a powder blend;

spreading a layer of said powder blend on a platform;

directing a beam of energy onto selected areas of said layer of said powder blend to melt said polymer binder, said polymer binder resolidifying to bind said metal powders in said selected areas; and

heating said selected areas of bound metal powders to eliminate said polymer binder and to densify said selected areas by transient liquid sintering and isothermal resolidification at a temperature sufficient to melt said lower melting temperature powder but not said base metal powder.

2. The method of claim 1, further comprising the step of repeating said steps of spreading said powder blend and directing said energy beam onto selected areas layer-by-layer to build up a preform part of bound powders.

3. The method of claim 2, wherein said heating step comprises heating said preform part to vaporize and eliminate said polymer binder and to densify said preform part.

4. The method of claim 3, further comprising the step of supporting said preform part during said heating step in a bed of support powder selected from the group consisting of ceramic powders and ceramic coated metal powders.

5. The method of claim 4, wherein said step of supporting said preform part in a bed of support powder includes selecting said support powder from the group consisting of yttria, zirconia, silicon nitride, boron nitride, and surface nitrided nickel aluminide powders.

6. The method of claim 4, wherein said step of supporting said preform part in a bed of support powder includes the step of providing a fluidized bed of support powder.

7. The method of claim 3, further comprising the steps of:

providing preform support shapes;

coating said preform support shapes with a release agent; and

positioning said coated preform support shapes to support said preform part during said heating step.

8. The method of claim 7, further comprising the step of placing said preform part and support shapes on a low friction plate during said heating step.

9. The method of claim 3, further comprising the step of hot isostatic pressing said densified part to close residual porosity and complete chemical homogenization of said part.

10. The method of claim 1, wherein said polymer binder comprises high purity nylon in the form of fine spherical particles.

11. A method of free form fabrication of metallic components, comprising the steps of:

blending powders of a base metal, a lower melting temperature metal, and a polymer binder to form a powder blend;

spreading a layer of said powder blend on a platform;

directing a beam of energy onto selected areas of said layer of blended powder to cause localized melting of said polymer binder, said polymer binder resolidifying to bind said metal powders in said selected areas;

repeating said steps of spreading said powder blend and directing said energy beam onto selected areas to build up a preform part of bound powders;

providing support for said preform part;

heating said preform part to vaporize and eliminate said polymer binder from said preform part; and

densifying said preform part by transient liquid sintering and isothermal resolidification at a temperature sufficient to melt said lower melting temperature powder but not said base metal powder.

12. The method of claim 11, further comprising the step of hot isostatic pressing said densified part to close residual porosity and complete chemical homogenization of said part.

13. The method of claim 11, wherein said step of providing support comprises supporting said preform part in a bed of support powder selected from the group consisting of ceramic powders and ceramic coated metal powders.

14. The method of claim 13, wherein said step of supporting said preform part in a bed of support powder includes the step of providing a fluidized bed of support powder.

15. The method of claim 13, wherein said step of providing support further comprises the steps of:

providing preform support shapes;

coating said preform support shapes with a release agent; and

positioning said coated preform support shapes to support said preform part during said heating and densifying steps.

16. The method of claim 11, wherein said polymer binder comprises a high purity nylon powder comprising fine spherical particles.

17. A method of free form fabrication of metallic components, comprising the steps of:

forming a powder blend comprising powders of a base metal, a lower melting temperature alloy of said base metal, and a high purity nylon binder comprising fine spherical particles;

spreading a layer of said powder blend on a platform;

directing a laser beam onto selected areas of said layer of blended powder to cause localized melting of said nylon binder, said melted nylon binder resolidifying to bind said metal powders in said selected areas;

repeating said steps of spreading said powder blend and directing said laser beam onto selected areas to build up a preform part of bound powders;

providing support for said preform part;

heating said preform part to vaporize and eliminate said nylon binder from said preform part; and

densifying said supported preform part by transient liquid sintering and isothermal resolidification at a temperature sufficient to melt said lower melting temperature alloy powder but not said base metal powder.

18. The method of claim 17, further comprising the step of hot isostatic pressing said densified part to close residual porosity and complete chemical homogenization of said part.

19. The method of claim 17, wherein said step of providing support comprises supporting said preform part in a bed of powder selected from the group consisting of ceramic coated metal powders and yttria, zirconia, silicon nitride, and surface nitrided nickel aluminide powders.

20. The method of claim 19, wherein said step of providing support further comprises the steps of:

providing preform support shapes;

coating said preform support shapes with a release agent; and

positioning said coated preform support shapes to support said preform part on a low-friction plate during said heating and densifying steps.