Pre-fractionation of cracked gas or olefins fractionation by one or two mixed refrigerant loops and cooling water

• US 5,746,066 A
• Filed: 09/17/1996
• Issued: 05/05/1998
• Est. Priority Date: 09/17/1996
• Status: Expired due to Term

• Current Assignee: David B. Manley
• Original Assignee: David B. Manley
• Inventors: Manley, David B.
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US08/714,807
• Time in Patent Office: 595 Days
• Field of Search: 62/612, 62/613, 62/619, 62/935
• US Class Current: 62/612
• CPC Class Codes: C10G 70/043 by fractional condensation
• CPC Class Codes: F25J 2200/38 using pre-separation or distributed distillation before a main column system, e.g. in a at least a double column system
• CPC Class Codes: F25J 2210/12 Refinery or petrochemical off-gas
• CPC Class Codes: F25J 2215/62 Ethane or ethylene
• CPC Class Codes: F25J 2270/12 External refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/66 Closed external refrigeration cycle with multi component refrigerant [MCR], e.g. mixture of hydrocarbons
• CPC Class Codes: F25J 2270/902 Details about the refrigeration cycle used, e.g. composition of refrigerant, arrangement of compressors or cascade, make up sources, use of reflux exchangers etc.
• CPC Class Codes: F25J 2290/10 Mathematical formulae, modeling, plot or curves; Design methods
• CPC Class Codes: F25J 2290/40 Vertical layout or arrangement of cold equipments within in the cold box, e.g. columns, condensers, heat exchangers etc.
• CPC Class Codes: F25J 3/0219 Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more
• CPC Class Codes: F25J 3/0242 separation of CnHm with 3 carbon atoms or more
• CPC Class Codes: F25J 3/0252 separation of hydrogen production of hydrogen containing gas in general C01B3/00, e.g. separation of hydrogen or hydrogen containing gases form gaseous mixtures at low temperatures C01B3/506

Abstract

The present invention is a plurality of stages for partial condensation and phase separation a process gas stream, preferably containing substantial amounts of light olefins, methane, and hydrogen, but containing initially at least substantial amounts of methane and ethylene. Each condensation and separation stage is refrigerated with a subcooled and flashed high pressure liquid of a mixed refrigerant refrigeration loop, wherein throughout the loop the relative component ratios of the mixed refrigerant components are constant, contrasted with the several mixed refrigerant processes of the prior art where for all the streams of each closed refrigeration loop. In addition, rectification and/or stripping sections of an ethylene separation train have a common support construction taking advantage of relatively similar column diameters to reduce the total number of columns in the process.

Claims

1. A process for partial condensation of a process gas which initially comprises significant amounts of methane and ethylene comprising:

(a) a plurality of sequential. condensation and separation stages comprising, at each condensation and separation stage, condensation of at least part of the process gas and separation of the resulting condensate and remaining process gas; and

(b) supplying refrigeration for condensation at each condensation and separation stage by a first mixed refrigerant refrigeration loop, wherein a first mixed refrigerant used therein is comprised substantially of ethylene, ethane, and propylene and the relative proportions of those components remain constant through the first mixed refrigerant refrigeration loop.

2. The process of claim 1 wherein rectification of the process gas occurs between at least two of the sequential condensation and separation stages.

3. The process of claim 2 wherein the rectification of the process gas occurs in demethanization, deethylenization, deethanization, depropylenization or depropanization of the process gas.

4. The process of claim 1 wherein the first mixed refrigerant loop further comprises:

(a) a first compression stage compressing first mixed refrigerant vapor to a first pressure from a second pressure and condensation of the compressed mixed refrigerant vapor to form a high pressure liquid;

(b) subcooling the high pressure liquid;

(c) separating the high pressure liquid to form a first stage refrigerating stream and a first remaining high pressure liquid and flashing the first stage refrigerating stream to the second pressure;

(d) supplying refrigeration to the first condensation and separation stage by vaporizing the flashed first stage refrigerating stream;

(e) subcooling the first remaining high pressure liquid;

(f) separating at least part of the first remaining high pressure liquid to form a second stage refrigerating stream and, if any high pressure liquid remains, a subsequent stage remaining high pressure liquid and flashing the second stage refrigerating stream to a subsequent stage pressure;

(g) supplying refrigeration to a second condensation and separation stage by vaporizing the flashed second stage refrigerating stream;

(h) in a second compression stage, compressing to the second pressure from the subsequent stage pressure the vaporized second stage refrigerating stream; and

(i) mixing the compressed vapor of the second compression stage with the vaporized first stage refrigerating stream and compressing the mixed stream in the first compression stage.

5. The process of claim 4 wherein condensation and separation stages subsequent to the second condensation and separation stage comprise:

(a) a subsequent-stage remaining high pressure liquid formed as a diverted portion of the high pressure liquid subcooled to a temperature appropriate for refrigeration of a condensation and separation stage immediately previous to the subsequent condensation and separation stage;

(b) further subcooling the subsequent-stage remaining high pressure liquid;

(c) separating at least part of the subsequent-stage remaining high pressure liquid to form a subsequent stage refrigerating stream and, if any high pressure liquid remains, a next subsequent-stage remaining high pressure liquid;

(d) flashing the subsequent stage refrigerating stream to a subsequent stage pressure, which is significantly lower than the pressure of the vaporized refrigerating stream of the previous condensation and separation stage;

(e) supplying refrigeration to a subsequent stage condensation and separation stage by vaporizing the flashed subsequent stage refrigerating stream;

(f) in a subsequent compression stage, combining the vaporized subsequent stage refrigerating stream and, if any, the vaporized and compressed refrigerating streams of the condensation and separation stages after the subsequent condensation and separation stage to form a subsequent mixed stream and compressing in a subsequent compression stage the subsequent mixed stream to the pressure of the vaporized refrigerating stream of the previous condensation and separation stage; and

(g) combining the compressed subsequent mixed stream with the vaporized refrigerating stream of the previous condensation and separation stage to form a previous mixed stream and compressing in a previous compression stage the previous mixed stream.

6. The process of claim 5 wherein one or more condensing process steps in rectification of a cracked or pyrolyzed gas are at least in part accomplished at one or more of the condensation and separation steps.

7. The process of claim 6 wherein first and second high level mixed refrigerant heat transfer stages comprise cooling for portions of the cracked gas with approximate inlet process temperatures of greater than about 100°

F. and greater than about 70°

F., respectively.

8. The process of claim 6 wherein third and fourth high level mixed refrigerant heat transfer stages comprise cooling for portions of the cracked gas with approximate inlet process temperatures of greater than about 35°

F. and greater than about -10°

F., respectively.

9. The process of claim 6 wherein a fifth high level mixed refrigerant heat transfer stage comprises cooling for portions of the cracked gas with approximate inlet process temperatures of greater than about -45°

F.

10. A process for a thermally linked fractionation combination comprising:

(a) an upper rectification section in a first pressure shell and a lower rectification section in a second pressure shell whereby an upper part of the lower rectification section pressure shell is supportively connected and located immediately inferior to a lower part of the upper rectification section pressure shell;

(b) an upper rectification section stripping section is located in third pressure shell which is supported separately from than that of the pressure shell of the lower or upper rectification section;

(c) the liquid bottom stage stream of the upper rectification section is divided between top stages of the lower rectification section and the upper rectification section stripping section for reflux and stripping feed respectively; and

(d) top stage vapor streams from the lower rectification section and the upper rectification section stripping section are combined and introduced to the bottom stage of the upper rectification section to provide stripping vapor.

11. The process of claim 10 wherein two, a first and a second, thermally linked fractionation combinations have an upper rectification section of the second thermally linked fractionation combination which consists of the lower rectification section of the first thermally linked fractionation combination.

12. The process of claim 11 wherein a third thermally linked fractionation combination has an upper rectification section of the third thermally linked fractionation combination which consists of the lower rectification section of the second thermally linked fractionation combination.

13. The process of claim 12 wherein a fourth thermally linked fractionation combination has an upper rectification section of the fourth thermally linked fractionation combination which consists of the lower rectification section of the third thermally linked fractionation combination.

14. The process of claim 13 wherein a fifth thermally linked fractionation combination has an upper rectification section of the fifth thermally linked fractionation combination which consists of the lower rectification section of the fourth thermally linked fractionation combination.

15. The process of claim 14 wherein a pyrolysis-derived gas is fed to the bottom stage of the lower rectification stage of the fifth thermally linked fractionation combination and intercondensing duty is provided to the rectification sections, wherein at least a part of the intercondensing duty is provided by a mixed refrigerant refrigeration loop.

16. The process of claim 14 wherein, between any rectification sections in inferior-superior relationship each other, mechanical barriers to the flow of vapor from an inferior rectification section to a superior rectification section consists essentially of a "chimney" tray or liquid holdup tray that has the capacity of maintaining a liquid level appropriate for withdrawal for use as reflux or column feed.

17. A process for partial condensation of a process gas which initially comprises significant amounts of methane and ethylene comprising:

(a) a plurality of sequential condensation and separation stages comprising, at each condensation and separation stage, condensation of at least part of the process gas and separation of the resulting condensate and remaining process gas, providing the resulting condensate for use as at least part of the refluxing liquid to rectification stages for the process gas; and

(b) supplying refrigeration for condensation at each condensation and separation stage by a first mixed refrigerant refrigeration loop, wherein a first mixed refrigerant used therein is comprised substantially of ethylene, ethane, and propylene and the relative proportions of those components remain constant through the first mixed refrigerant refrigeration loop.

18. The process of claim 17 wherein, below the top stage of the rectification stages wherein an intercondenser may operate as a condensation and separation stage, at least two theoretical stages of separation operate between a lower withdrawal stage and an upper return stage for, respectively, removal from and return to the rectification stages of a portion of the process gas.

19. The process of claim 17 wherein the first mixed refrigerant loop further comprises:

(a) a high pressure liquid consisting of first mixed refrigerant;

(b) dividing the high pressure liquid to produce a sequence of successively lower pressure refrigeration streams by;

(i) subcooling to successively lower temperatures at least refrigeration stream parts sequentially divided from the high pressure liquid to form a sequence of refrigeration streams at sequentially lower temperatures;

(ii) flashing each of the subcooled refrigeration streams to sequentially lower pressures lower than high pressure, such that the highest temperature refrigeration stream is flashed to the highest pressure of the sequence of refrigeration stream pressures;

(c) refrigerating condensation and separation stages with the sequence of flashed refrigeration streams to form a sequence of mixed refrigerant vapor streams with identical compositions at a sequence of pressures;

(d) forming a sequence of compression stages wherein a mixed refrigerant vapor at a lower pressure is compressed to and is combined with the next highest pressure mixed refrigerant vapor stream, such that the lowest pressure mixed refrigerant vapor stream is first compressed and mixed with the next highest pressure mixed refrigerant vapor stream and so on until all the mixed refrigerant vapor streams have been compressed to form a combined mixed refrigerant stream; and

(e) compressing the combined mixed refrigerant stream to high pressure and condensing the combined mixed refrigerant stream to form the high pressure liquid.

20. The process of claim 19 wherein subcooling of each refrigeration stream part as formed in claim 19(b)(i) comprising the refrigeration stream for a particular condensation and separation stage is done at least in final part at the condensation and separation stage which is refrigerated by that particular refrigerating stream.

21. The process of claim 19 wherein a second mixed refrigerant loop comprises:

(a) a second high pressure liquid at a second high pressure consisting of a second mixed refrigerant comprising substantially methane and ethylene and the relative proportions of those components remain constant through the second mixed refrigerant refrigeration loop;

(b) dividing the next high pressure liquid to produce one or a sequence of successively lower pressure refrigeration streams by;

(i) subcooling to successively lower temperatures at least refrigeration stream parts sequentially divided from the second high pressure liquid to form a sequence of refrigeration streams at sequentially lower temperatures;

(ii) flashing each of the subcooled refrigeration streams to sequentially lower pressures lower than second high pressure, such that the highest temperature refrigeration stream is flashed to the highest pressure of the sequence of refrigeration stream pressures;

(c) refrigerating one or more condensation and separation stages with process gas outlet temperatures lower than the process gas outlet temperatures for the condensation and separation stages refrigerated by the first refrigeration loop and with the sequence of flashed refrigeration streams to form a sequence of mixed refrigerant vapor streams with identical compositions at a sequence of pressures;

(d) forming a sequence of compression stages wherein a mixed refrigerant vapor at a lower pressure is compressed to and is combined with the next highest pressure mixed refrigerant vapor stream, such that the lowest pressure mixed refrigerant vapor stream is first compressed and mixed with the next highest pressure mixed refrigerant vapor stream and so on until all the mixed refrigerant vapor streams have been compressed to form a second combined mixed refrigerant stream; and

(e) compressing the combined mixed refrigerant stream to the second high pressure and condensing the second combined mixed refrigerant stream to form the second high pressure liquid.

22. The process of claim 21 wherein condensation and substantial subcooling of the second combined mixed refrigerant stream is done by heat transfer to the first mixed refrigerant refrigeration loop.

23. The process of claim 22 wherein cooling water provides all the condensing duty for forming the high pressure liquid from the combined mixed refrigerant stream.

24. The process of claim 23 wherein the first refrigerant loop comprises 2 to 5 condensation and separation stages and the second refrigerant loop comprises 1 to 4 condensation and separation stages, whereby are provided to a fractionation sequence of rectification sections for cracked gas substantially all external refrigeration by refrigerant streams at less than 100°

F. required for rectification of the fractionation sequence.