Electrochemical gas sensor

• US 5,746,899 A
• Filed: 11/14/1996
• Issued: 05/05/1998
• Est. Priority Date: 12/20/1995
• Status: Expired due to Fees

• Current Assignee: City Technology Ltd. (Honeywell International Inc.)
• Original Assignee: City Technology Ltd. (Honeywell International Inc.)
• Inventors: Bulpitt, Malcolm Robert, Finbow, John Robert
• Primary Examiner(s): Bell, Bruce F.
• Application Number:
  US08/749,176
• Time in Patent Office: 537 Days
• Field of Search: 204/415, 204/431, 204/432, 204/426
• US Class Current: 204/415
• CPC Class Codes: G01N 27/404 Cells with anode, cathode and cell electrolyte on the same side of a permeable membrane which separates them from the sample fluid , e.g. Clark-type oxygen sensors

Abstract

An electrochemical gas sensor comprises sensing and counter electrodes mounted on the same side of a planar support. An electrolyte is in contact with the sensing and counter electrodes. A capillary controls the access of gas to the sensing electrode. A barrier layer extends over the sensing and counter electrodes, the barrier layer being positioned relative to the capillary and the support being non-electrically conductive and being sufficiently porous such that gas from the capillary is guided transversely and laterally through the support first to reach the sensing electrode and then to reach the counter electrode.

Claims

1. An electrochemical gas sensor comprising sensing and counter electrodes mounted on the same side of a planar support;

an electrolyte in contact with said sensing and counter electrodes;

means for controlling the access of gas to said sensing electrode; and

a barrier layer provided on said support on the opposite side to and extending over said sensing and counter electrodes, said barrier layer being positioned relative to said gas access control means and said support being non-electrically conductive and being sufficiently porous such that gas from said gas access control means is guided transversely and laterally through said support first to reach said sensing electrode and then to reach said counter electrode.

2. A sensor according to claim 1, further comprising a reference electrode mounted on the same side of said support as said sensing and counter electrodes, the arrangement being such that gas can only reach said reference electrode after passing said sensing electrode.

3. A sensor according to claim 2, wherein said barrier layer is positioned also to force gas to diffuse laterally through said support to reach said reference electrode.

4. A sensor according to claim 1, further comprising an auxiliary sensing electrode mounted on the same side of said support as said sensing and counter electrodes, the arrangement being such that gas can only reach said auxiliary sensing electrode after passing said sensing electrode.

5. A sensor according to claim 3, wherein said barrier layer is positioned also to force gas to diffuse laterally through said support to reach said auxiliary electrode.

6. A sensor according to claim 1, wherein said barrier layer comprises polyethylene.

7. A sensor according to claim 1, wherein said support comprises porous polytetrafluoroethylene (PTFE).

8. A sensor according to claim 1, wherein said electrodes are screen printed on said support.

9. A sensor according to claim 1, wherein said means for controlling the access of gas to said sensing electrode comprises one of a gas phase diffusion barrier, a Knudsen barrier, and a solid membrane.

10. A sensor according to claim 9, wherein said means for controlling the access of gas to said sensing electrode is a capillary.

11. A sensor according to claim 1, wherein said means for controlling the access of gas to said sensing electrode is laterally offset from said barrier layer.

12. A sensor according to claim 1, wherein said electrolyte is an aqueous electrolyte, and wherein said support is hydrophobic.

13. A sensor according to claim 1, wherein said electrolyte is a solid electrolyte.

14. A sensor according to claim 13, wherein said solid electrolyte is chosen from the group consisting of perfluorosulfonic acid, polyvinyl alcohol (PVA), poly 2-hydroxy ethyl methacrylate (p-HEMA), polyvinylpyrolidone (PVP), and polyacrylamide (and substituted polyacrylamides).