Mixtures of polymers including a halogen-containing polymer and compatibilized with a grafted aliphatic polyester

• US 5,747,605 A
• Filed: 11/08/1995
• Issued: 05/05/1998
• Est. Priority Date: 11/08/1994
• Status: Expired due to Fees

• Current Assignee: Elf Atochem S.A. (Arkema)
• Original Assignee: Elf Atochem S.A. (Arkema)
• Inventors: Bouilloux, Alain, Breant, Patrice
• Primary Examiner(s): Acquah, Samuel A.
• Application Number:
  US08/555,231
• Time in Patent Office: 909 Days
• Field of Search: 528/271, 528/272, 528/302, 528/354, 528/361, 525/437, 525/438, 525/439, 525/445, 525/447, 525/450
• US Class Current: 525/437
• CPC Class Codes: C08F 283/02 on to polycarbonates or saturated polyesters C08F283/004 takes precedence
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 27/00 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 51/08 grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds

Abstract

The invention relates to mixtures of polymers including at least one halogen-containing polymer and compatibilized with a grafted aliphatic polyester. The compatibilizing agent may be, for example, a polycaprolactone grafted with maleic anhydride or glycidyl methacrylate.

Claims

1. Mixtures of polymers consisting essentially of:

one halogen-containing polymer

another polymer which has substantially no compatibility with said one halogen-containing polymer, and

a grafted aliphatic polyester as compatibiizer wherein (i) the halogen-containing polymer is selected from the group consisting of PVC, chlorinated PVC, plasticized PVC, PVC-based compounds, PVDF and its copolymers and PVF3 and (ii) which include another polymer selected from the group consisting of EVOH, PB and PA.

2. Mixtures according to claim 1, wherein the aliphatic polyester is grafted with a monomer selected from the group consisting of:

unsaturated carboxylic acids;

unsaturated products carrying expoxidized functional groups, and

vinyl esters.

3. Mixtures according to claim 1, wherein the polyester is polycaprolactone.

4. Polymer having a substantially incompatible component consisting essentially of at least one halogen-containing polymer compatibilized with a grafted aliphatic polyester;

said halogen-containing polymer including polyvinyl chloride, chlorinated polyvinyl chloride, plasticized polyvinyl chloride, polyvinyl chloride-based compound, polyvinyl difluoride and its copolymers and polytrifluoroethylene;

said grafted aliphatic polyester compatibilizes said halogen-containing polymer with another polymer being substantially incompatible with it;

said other polymer including ethylene vinyl alcohol copolymers, polyesters including polyethylene terephthalate, and polybutylene terephthalate, polyamides, said aliphatic polyester including linear polylactones including polyaprolactone, polycaprolactone, polypivalolactone or polyenantholactone or polycaprylolactone, and at least one monomer being grafted onto the aliphatic polyester selected from the group consisting of unsaturated carboxylic acids, their salts, their esters and their anhydrides, unsaturated products carrying epoxidized functional groups, vinyl esters, styrene and its derivatives, the grafted monomer being less than 15% by weight of the aliphatic polyesters.

5. The polymer according to claim 4, wherein at least one monomer is selected from the group consisting of:

(meth)acrylic acid, fumaric acid, mesaconic acid,

alkyl(meth)acrylates such as methyl methacrylate, butyl acrylate, tert-butyl acrylate or hydroxyethyl acrylate,

citraconic anhydride, itaconic anhydride, tetrahydrophthalic anhydride, 2-methylmaleic anhydride, 2,3-dimethylmaleic anhydride and maleic anhydride,

aliphatic glycidyl esters and ethers such as glycidyl (meth)acrylate, glycidyl maleate, glycidyl itaconate, vinyl glycidyl ether and alkyl glycidyl ethers,

aliphatic glycidyl esters and ethers including 2-cyclohex-1-ene glycidyl ether, diglycidyl cyclohexane-4,5-dicarboxylate, glycidyl cyclohexene-4-carboxylate, glycidyl 2-methyl-5-norbornene-2-carboxylate and diglycidyl endocis-bicyclo(2.2.1) -5-heptene-2,3-dicarboxylate, vinylcyclohexene monoxide and METHB,

vinyl acetate.

6. The polymer according to claim 4 wherein the polymer is a 20% by weight of ethylene-vinyl alcohol-polyvinyl chloride mixture.

7. The polymer according to claim 4, wherein the polymer is a polyvinyl chloride-polyethylene terephthalate mixture.

8. The polymer according to claim 4, wherein the polyamide or polyamide oligomer compatibilizing agent comprises 1 to 10% by weight of the polymer.

9. The polymer according to claim 4, wherein the polyamide or polyamide oligomer compatibilizing agent comprises 2 to 5% by weight of the polymer.

10. The polymer according to claim 4, wherein the polymer is a polyvinyl chloride-polystyrene mixture.

11. The polymer according to claim 4, wherein the polymer is a polyvinyldifluoride-polystyrene mixture.

12. Mixtures of polymers consisting essentially of:

one halogen-containing polymer

another polymer which has substantially no compatibility with said one halogen-containing polymer, and

a grafted aliphatic polyester as compatibiizer wherein (i) the halogen-containing polymer is selected from the group consisting of PVC, chlorinated PVC, plasticized PVC, PVC-based compounds, PVDF and its copolymers and PVF3 and (ii) which include another polymer selected from the group consisting of EVOH, PBT, PS and PA.