Oxygen electrode and its manufacture

• US 5,747,669 A
• Filed: 10/18/1996
• Issued: 05/05/1998
• Est. Priority Date: 12/28/1995
• Status: Expired due to Fees

• Current Assignee: Fujitsu Limited
• Original Assignee: Fujitsu Limited
• Inventors: Suzuki, Hiroaki
• Primary Examiner(s): Williams, Hezron E.
• Assistant Examiner(s): WIGGINS, JOHN DAVID
• Application Number:
  US08/733,929
• Time in Patent Office: 564 Days
• Field of Search: 73/23.31, 73/31.06, 204/410, 204/424, 422/83, 422/94
• US Class Current: 73/23.21
• CPC Class Codes: G01N 27/3271 Amperometric enzyme electrodes for analytes in body fluids, e.g. glucose in blood amperometry per se G01N27/49; aspects concerning the enzyme reagent C12Q1/001
• CPC Class Codes: H01L 2224/48091 Arched
• CPC Class Codes: H01L 2224/73215 Layer and wire connectors
• CPC Class Codes: H01L 2224/73265 Layer and wire connectors
• CPC Class Codes: H01L 2924/00014 the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details

Abstract

An oxygen electrode having: an electrode substrate; a first electrode and a first lead wire formed on the electrode substrate; an insulating layer formed on the electrode substrate covering the first lead wire; a second electrode and a second lead wire formed on the electrode substrate, and on the insulating layer; a container substrate bonded to the electrode substrate, and having a first recess with an opening over the first and second electrodes for containing electrolyte; and an oxygen permeable film covering the opening. The oxygen electrode may be provided with lead plates and partially molded in an insulating and fixing resin. An oxygen electrode for measuring an oxygen concentration having a novel structure is provided which can be made more compact and/or be used more easily.

Claims

1. An oxygen electrode comprising:

an electrode substrate having an insulating surface;

a first electrode member formed on the insulating surface of said electrode substrate, said first electrode member including a first electrode, a first lead wire, and a first connection pad electrically connected together;

a second electrode member formed on the insulating surface of said electrode substrate, said second electrode member including a second electrode, a second lead wire, and a second connection pad electrically connected together;

an electrolyte layer disposed over said electrode substrate so as to form a conductive path between the first and second electrodes;

an oxygen permeable film disposed over said electrode substrate, covering said electrolyte layer;

first and second lead plates each having one end directly fixed to said electrode substrate;

a first connection member for connecting said first connection pad to said first lead plate;

a second connection member for connecting said second connection pad to said second lead plate; and

an insulating mold member surrounding around and fixed to said electrode substrate and covering said first and second connection pads, said each one end of said first and second lead plates, and said first and second connection members.

2. An oxygen electrode according to claim 1, wherein each of said first and second connection members includes conductive paste.

3. An oxygen electrode according to claim 2, wherein said first and second connection members include conductive paste layers disposed between said first connection pad and said first lead plate and between said second connection pad and said second lead plate.

4. An oxygen electrode according to claim 2, further comprising an insulating resin layer disposed directly on said electrode substrate between said first and second connection pads.

5. An oxygen electrode according to claim 1, wherein each of said first and second connection members includes a metal wire.

6. An oxygen electrode according to claim 5, wherein said first and second lead plates are bonded to a surface opposite to the surface of said electrode substrate with said first and second electrode members.

7. An oxygen electrode according to claim 1, further comprising an insulating resin layer disposed directly on said electrode substrate, covering a connection area between said first and second lead wires and said first and second connection pads.

8. An oxygen electrode according to claim 1, further comprising an insulating resin layer disposed directly on said electrode substrate, covering a connection area between said first and second connection pads and said first and second lead plates.

9. An oxygen electrode according to claim 1, wherein said electrode substrate has a rectangular shape having a longer side and a shorter side, and said first and second lead plates extend in the longitudinal direction of said electrode substrate.

10. An oxygen electrode according to claim 1, wherein said electrode substrate has a rectangular shape having a longer side and a shorter side, and said first and second lead plates extend in a lateral direction transverse to a longitudinal direction of said electrode substrate.

11. An oxygen electrode according to claim 1, wherein said electrode substrate has a rectangular shape having a longer side and a shorter side, and each of said first and second lead plates having a portion folded along an outer surface of said mold member.

12. An oxygen electrode according to claim 1, wherein said mold member includes a loop groove circulating around said electrode substrate.

13. An oxygen electrode according to claim 1, wherein said mold member partially has a flat surface.

14. An oxygen electrode comprising:

an electrode substrate having an insulating surface;

a first electrode member formed on the insulating surface of said electrode substrate, said first electrode member including a first electrode, a first lead wire, and a first connection pad electrically connected together;

a second electrode member formed on the insulating surface of said electrode substrate, said second electrode member including a second electrode, a second lead wire, and a second connection pad electrically connected together;

an electrolyte layer disposed over said electrode substrate so as to form a conductive path between the first and second electrodes;

an oxygen permeable film disposed over said electrode substrate, covering said electrolyte layer;

first and second lead plates each having one end directly fixed to said electrode substrate;

a first connection member for connecting said first connection pad to said first lead plate;

a second connection member for connecting said second connection pad to said second lead plate; and

an insulating mold member fixed to said electrode substrate and covering said first and second connection pads, said each one end of said first and second lead plates, and said first and second connection members, the insulating mold member having a sufficient mechanical strength to absorb stress applied thereto.

15. An oxygen electrode according to claim 14, wherein each of said first and second connection members includes conductive paste.

16. An oxygen electrode according to claim 15, wherein said first and second connection members include conductive paste layers disposed between said first connection pad and said first lead plate and between said second connection pad and said second lead plate.

17. An oxygen electrode according to claim 15, further comprising an insulating resin layer disposed directly on said electrode substrate between said first and second connection pads.

18. An oxygen electrode according to claim 14, wherein each of said first and second connection members includes a metal wire.

19. An oxygen electrode according to claim 18, wherein said first and second lead plates are bonded to a surface opposite to the surface of said electrode substrate with said first and second electrode members.

20. An oxygen electrode according to claim 14, further comprising an insulating resin layer disposed directly on said electrode substrate, covering a connection area between said first and second lead wires and said first and second connection pads.

21. An oxygen electrode according to claim 14, further comprising an insulating resin layer disposed directly on said electrode substrate, covering a connection area between said first and second connection pads and said first and second lead plates.

22. An oxygen electrode according to claim 14, wherein said electrode substrate has a rectangular shape having a longer side and a shorter side, and said first and second lead plates extend in the longitudinal direction of said electrode substrate.

23. An oxygen electrode according to claim 14, wherein said electrode substrate has a rectangular shape having a longer side and a shorter side, and said first and second lead plates extend in a lateral direction transverse to a longitudinal direction of said electrode substrate.

24. An oxygen electrode according to claim 14, wherein said electrode substrate has a rectangular shape having a longer side and a shorter side, and each of said first and second lead plates having a portion folded along an outer surface of said mold member.

25. An oxygen electrode according to claim 14, wherein said mold member includes a loop groove circulating around said electrode substrate.

26. An oxygen electrode according to claim 14, wherein said mold member partially has a flat surface.

27. An oxygen electrode comprising:

an electrode substrate having an insulating surface;

a first electrode member formed on the insulating surface of said electrode substrate, said first electrode member including a first electrode, a first lead wire, and a first connection pad electrically connected together;

a second electrode member formed on the insulating surface of said electrode substrate, said second electrode member including a second electrode, a second lead wire, and a second connection pad electrically connected together;

an electrolyte layer disposed over said electrode substrate so as to form a conductive path between the first and second electrodes;

an oxygen permeable film disposed over said electrode substrate, covering said electrolyte layer;

first and second lead plates having each one end directly fixed to said electrode substrate;

a first connection member for connecting said first connection pad to said first lead plate;

a second connection member for connecting said second connection pad to said second lead plate; and

an insulating mold member fixed to said electrode substrate and covering said first and second connection pads, said each one end of said first and second lead plates, and said first and second connection members, said first and second lead plates having portions extending outside of said insulating mold member;

wherein the mold member or the lead plates can be gripped to handle the oxygen electrode, while the electrode substrate is protected from stress.

28. An oxygen electrode according to claim 27, wherein each of said first and second connection members includes conductive paste.

29. An oxygen electrode according to claim 28, wherein said first and second connection members include conductive paste layers disposed between said first connection pad and said first lead plate and between said second connection pad and said second lead plate.

30. An oxygen electrode according to claim 28, further comprising an insulating resin layer disposed directly on said electrode substrate between said first and second connection pads.

31. An oxygen electrode according to claim 27, wherein each of said first and second connection members includes a metal wire.

32. An oxygen electrode according to claim 31, wherein said first and second lead plates are bonded to a surface opposite to the surface of said electrode substrate with said first and second electrode members.

33. An oxygen electrode according to claim 27, further comprising an insulating resin layer disposed directly on said electrode substrate, covering a connection area between said first and second lead wires and said first and second connection pads.

34. An oxygen electrode according to claim 27, further comprising an insulating resin layer disposed directly on said electrode substrate, covering a connection area between said first and second connection pads and said first and second lead plates.

35. An oxygen electrode according to claim 27, wherein said electrode substrate has a rectangular shape having a longer side and a shorter side, and said first and second lead plates extend in the longitudinal direction of said electrode substrate.

36. An oxygen electrode according to claim 27, wherein said electrode substrate has a rectangular-shape having a longer side and a shorter side, and said first and second lead plates extend in a lateral direction transverse to a longitudinal direction of said electrode substrate.

37. An oxygen electrode according to claim 27, wherein said electrode substrate has a rectangular shape having a longer side and a shorter side, and each of said first and second lead plates having a portion folded along an outer surface of said mold member.

38. An oxygen electrode according to claim 27, wherein said mold member includes a loop groove circulating around said electrode substrate.

39. An oxygen electrode according to claim 27, wherein said mold member partially has a flat surface.