Method for gas absorption across a membrane

• US 5,749,941 A
• Filed: 09/17/1996
• Issued: 05/12/1998
• Est. Priority Date: 03/25/1994
• Status: Expired due to Term

• Current Assignee: Nederlandse Organisatie Voor
• Original Assignee: Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno
• Inventors: Feron, Paul Hubert Maria, Jansen, Albert Edward
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US08/716,159
• Time in Patent Office: 602 Days
• Field of Search: 95/44, 95/49, 95/51, 96/4, 96/5, 96/8, 96/10
• US Class Current: 95/44
• CPC Class Codes: B01D 53/1468 Removing hydrogen sulfide
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/229 Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

The invention relates to a method for the absorption of one or more gaseous components from a gas phase, in that the gas phase with the component(s) to be absorbed present therein is brought into contact with a liquid phase, wherein the gas phase and the liquid phase are separated by a hydrophobic membrane of a material other than polytetrafluoroethene, wherein the liquid phase comprises water and a water-miscible and/or water-soluble absorbent, and wherein the liquid phase does not give rise to any leakage from the membrane or is effective in preventing or counteracting leakage from the membrane. According to a first preferred aspect, the liquid phase comprises waterand a water-miscible and/or water-soluble organic absorbent, wherein the surface tension at 20° C. has been brought to at least 60×10^-3 N/m by adding a water-soluble salt. According to a second preferred aspect, the liquid phase comprises an aqueous solution of a water-soluble amino acid or a salt thereof, such as taurine and derivatives. According to a third preferred aspect, the liquid phase comprises an aqueoussolution of a water-soluble phosphate salt. The membranes are preferably in the form of hollow fibres of, for example, polypropene or polyethene. The method is suitable in particular for the absorption of carbon dioxide.

Claims

1. Method for the absorption of one or more gaseous components from a gas phase in a membrane system, in that the gas phase with the component(s) to be absorbed present therein is brought into contact with a liquid phase, wherein the gas phase and the liquid phase are separated by a hydrophobic membrane, and the gaseous components are absorbed into said liquid phase through the hydrophobic membrane and then removed from the membrane system while absorbed in said liquid phase, wherein

the gaseous components are chosen from carbon dioxide and/or hydrogen sulfide;

the membranes are composed of polypropene, polyethene, polyvinylidene fluoride or polysulfone;

the liquid phase comprises water and a water-miscible and/or water-soluble absorbent;

the liquid phase has a surface tension at 20°

C. of more than 60×

10^-3 N/m;

the liquid phase does not give rise to any leakage from the membrane or is effective in preventing or counteracting leakage from the membrane;

with the proviso that the liquid phase is not an aqueous solution consisting solely of monoethanolamine (MEA) and water.

2. Method according to claim 1 characterised in that the liquid phase comprises an aqueous solution of a water-soluble amino acid or a water-soluble salt thereof.

3. Method according to claim 2, characterised in that the amino acid contains a carboxylic acid group or a sulphonic acid group.

4. Method according to claim 2 characterised in that the solution of the amino acid or the salt thereof has a pH of 9-13.

5. Method according to one of claim 2, characterised in that the amino acid is present in a concentration of 0.1-10M.

6. Method according to one of claim 2, characterised in that the amino acid is a non-sterically hindered amino acid.

7. Method according to claim 6, characterised in that the amino acid is taurine or a derivative thereof.

8. Method according to one of claim 2, characterised in that the amino acid is selected from the naturally occurring amino acids.

9. Method according to one of claim 1, characterised in that the liquid phase comprises an aqueous solution of a water-soluble phosphate salt.

10. Method according to claim 9, characterised in that the solution of the water-soluble phosphate salt has a pH of 9-13.

11. Method according to claim 9, characterised in that the phosphate salt is present in a concentration of 0.5-5M.

12. A method for the absorption of one or more gaseous components from a gas phase in a membrane system, wherein the gas phase containing the component(s) to be absorbed is brought into contact with a liquid phase, wherein the gas phase and the liquid phase are separated by a hydrophobic membrane, and the gaseous components are absorbed into said liquid phase through the hydrophobic membrane and then removed from the membrane system while absorbed in said liquid phase, wherein

the gaseous components are selected from the group consisting of carbon dioxide, hydrogen sulfide, and mixtures thereof;

the membranes are composed of polypropene, polyethene, polyvinylidene fluoride or polysulfone;

the liquid phase comprises water and an absorbent which is selected from the group consisting of water-miscible absorbent, water-soluble absorbents, and mixtures thereof;

the liquid phase has a surface tension at 20°

C. of more than 60×

10^-3 N/m;

the liquid phase does not give rise to any leakage from the membrane or is effective in preventing or counteracting leakage from the membrane;

with the proviso that the liquid phase is not an aqueous solution consisting solely of monoethanolamine and water and with the further proviso that the membrane is not a liquid membrane.

13. A method for absorption, in a membrane system, of at least one gaseous component from a gas phase into a liquid phase, said membrane system having at least one hydrophobic membrane permeable to said at least one gaseous component, which membrane system defining at least one gas feed channel on one side of the membrane and at least one liquid feed channel on the opposite side of the membrane, wherein the gas phase with the components to be absorbed present therein is led into the gas feed channel and brought into contact with one side of the membrane, and the liquid phase is led into the liquid feed channel and brought into contact with the opposite side of said membrane, in such a way that the at least one gaseous component is absorbed from the gas phase into the liquid phase through the hydrophobic membrane;

the gas phase and the liquid phase being separated by the hydrophobic membrane, and the liquid phase containing the one or more gaseous components absorbed therein is then removed from the membrane system, wherein

the gaseous components are selected from the group consisting of carbon dioxide, hydrogen sulfide, and mixtures thereof;

the membranes are made of polypropene, polyethene, polyvinylidene fluoride or polysulfone;

the liquid phase comprises water and an absorbent selected from the group consisting of water soluble absorbents, water miscible absorbents, and mixtures thereof;

the liquid phase has a surface tension at 20°

C. of more than 60×

10^-3 N/m;

the liquid phase does not leak from the membrane;

with the proviso that the liquid phase is not an aqueous solution consisting solely of monoethanolamine and water.

14. A method for absorption, in a membrane system, of at least one gaseous component from a gas phase into a liquid phase, said membrane system having at least one hydrophobic membrane permeable to said at least one gaseous component, which membrane defines at least one gas feed channel on one side of the membrane and at least one liquid feed channel on the opposite side of the membrane, wherein the gas phase with the at least one component to be absorbed present therein is led into the gas feed channel and brought into contact with one side of the membrane, and the liquid phase is led into the liquid feed channel and brought into contact with the opposite side of said membrane, in such a way that the at least one gaseous component is absorbed from the gas phase into the liquid phase through the hydrophobic membrane;

the gas phase and the liquid phase being kept separated by the hydrophobic membrane, and the liquid phase containing the at least one gaseous component absorbed therein is removed from the membrane system, wherein

the gaseous components are selected from the group consisting of carbon dioxide, hydrogen sulfide, and mixtures thereof;

the membranes are made of polypropene, polyethene, polyvinylidene fluoride or polysulfone;

the liquid phase comprises water and an absorbent selected from the group consisting of water soluble absorbents, water miscible absorbents, and mixtures thereof;

the liquid phase has a surface tension at 20°

C. of more than 60×

10^-3 N/m;

the liquid phase does not leak from the membrane;

with the proviso that the liquid phase is not an aqueous solution consisting solely of monoethanolamine and water; and

with the further proviso that the membrane is not a liquid membrane.

15. A method for the absorption, in a membrane system, of one or more gaseous components from a gas phase, said system having

a wall surrounding a space, said space being provided with at least one hydrophobic membrane, which is permeable to said at least one gaseous component;

said at least one membrane defining, within said space, at least one liquid channel and at least one gas channel;

at least one liquid inlet and and least one liquid outlet operably connected to said at least one liquid channel;

at least one gas input and at least one gas output operably connected to said at least one gas channel;

wherein a gas phase with the at least one component to be absorbed present therein is introduced via the at least one gas input into the at least one gas channel;

wherein a liquid phase is introduced into the at least one liquid channel via the at least one liquid input;

wherein in such a way that the gas phase is brought into contact with the liquid phase, and the at least one gaseous component is absorbed from the gas phase into the liquid phase through the hydrophobic membrane, the gas phase and the liquid phase being separated by the hydrophobic membrane;

wherein the liquid phase with the at least one gaseous component absorbed therein is removed from the membrane system via the at lease one liquid output, and the gas phase, from which the at least one gaseous component is at least partially removed, is removed from the reactor via the at least one gas outlet, wherein

the gaseous components are selected from the group consisting of carbon dioxide, hydrogen sulfide, and mixtures thereof;

the membranes are made of polypropene, polyethene, polyvinylidene fluoride or polysulfone;

the liquid phase comprises water and an organic absorbent selected from the group consisting of water soluble absorbents, water miscible absorbents, and mixtures thereof;

the liquid phase has a surface tension at 20°

C. of more than 60×

10^-3 N/m;

the liquid phase does not leak from the membrane;

with the proviso that the liquid phase is not an aqueous solution consisting solely of monoethanolamine and water.

16. Method according to claim 15, wherein the liquid phase contains a water-soluble salt which is selected from water-soluble carbonates.

17. A method according to claim 16 wherein the water-soluble carbonate is selected from the group consisting of potassium carbonate and sodium carbonate.

18. Method according to claim 15, characterised in that the organic absorbent is selected from monoethanolamine, diethanolamine (DEA), methyldiethanolamine (MDEA), methyl ethyl ketone (MEK), methyl isobutyl ketone (MBK), (poly)ethene glycols, ethers, alcohols and N-methylpyrrolidone.

19. Method according to one of claims 15, characterised in that the organic absorbent is used in a concentration of 0.05-10M.

20. Method according to claim 15, wherein the liquid phase contains a salt, which is used in a concentration of 0.05-10M.

21. Method according to claim 15, wherein the liquid phase contains a salt and said salt is a water-soluble carbonate and the organic absorbent used is a monoethanolamine.

22. A method according to claim 21 wherein the water-soluble carbonate is selected from the group consisting of potassium carbonate and sodium carbonate.

23. Method according to claim 15, wherein a water-soluble carbonate is present in the liquid phase in a concentration of 1.5-2.5M and the monoethanolamine is used in a concentration of 0.5-1.5M.