Current interrupter for electrochemical cells

• US 5,750,277 A
• Filed: 10/02/1996
• Issued: 05/12/1998
• Est. Priority Date: 04/10/1996
• Status: Expired due to Term

• Current Assignee: Duracell U.S. Operations, Inc. (Berkshire Hathaway Incorporated), Sensata Technologies Massachusetts Incorporated (Sensata Technologies Holding Plc)
• Original Assignee: Duracell Incorporated (Berkshire Hathaway Incorporated), Texas Instruments, Inc.
• Inventors: Johnson, Stephen S., Pinault, Robert J., Paquin, Geoffrey J., Cambra, Lance E., Sullivan, Steven K., Vu, Viet H., Fontaine, Lucien P., McHugh, William T., Blasi, Jane A., Maus, Gary K.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US08/720,585
• Time in Patent Office: 587 Days
• Field of Search: 429/7, 429/53, 429/56, 429/57, 429/58, 429/61, 429/62
• US Class Current: 429/7
• CPC Class Codes: H01H 2037/769 characterised by the composition of insulating fusible materials, e.g. for use in the thermal pellets
• CPC Class Codes: H01H 35/34 actuated by diaphragm
• CPC Class Codes: H01H 37/043 Mountings on controlled apparatus
• CPC Class Codes: H01H 37/54 wherein the bimetallic element is inherently snap acting
• CPC Class Codes: H01H 37/764 in which contacts are held closed by a thermal pellet
• CPC Class Codes: H01M 50/3425 in the form of rupturable membranes or weakened parts, e.g. pierced with the aid of a sharp member
• CPC Class Codes: H01M 50/578 in response to pressure
• CPC Class Codes: H01M 50/581 in response to temperature
• CPC Class Codes: H01M 50/583 in response to current, e.g. fuses
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A current interrupt mechanism for electrochemical cells is disclosed. A thermally activated current interrupt mechanism is integrated into an end cap assembly for an electrochemical cell. The thermally responsive mechanism preferably includes a free floating bimetallic disk which deforms when exposed to elevated temperature causing a break in an electrical pathway within the end cap assembly. This prevents current from flowing through the cell and effectively shuts down an operating cell. Alternatively, the thermally responsive mechanism may include a meltable mass of material which melts when exposed to elevated temperature to break an electrical pathway within the end cap assembly. The end cap assembly may also include integrated therein a pressure responsive current interrupt mechanism. If the internal gas pressure within an operating cell exceeds a predetermined value, the pressure responsive mechanism activates to sever an electrical pathway within the end cap assembly to prevent current from passing through the cell. The pressure responsive mechanism may include a diaphragm which ruptures when there is extreme gas pressure buildup. Gas is allowed to escape from the cell interior to the external environment through a series of vent apertures within the end cap assembly.

Claims

1. An end cap assembly for application to an electrochemical cell having a positive and a negative terminal and a pair of internal electrodes (anode and cathode), said end cap assembly comprising a housing and an end cap plate, said plate functional as a cell terminal, said end cap assembly having an electrically conductive pathway therethrough permitting the end cap plate to be electrically connected to a cell electrode when said end cap assembly is applied to a cell, said end cap assembly further comprising a) thermally responsive means for preventing current from flowing through said electrical pathway, wherein said thermally responsive means is activatable when the temperature within said end cap assembly reaches a predetermined level causing a break in said electrical pathway and b) pressure responsive means for preventing current from flowing through said electrical pathway, wherein said pressure responsive means is activatable when gas pressure applied to at least a portion of said electrical pathway reaches a predetermined level causing a break therein.

2. The end cap assembly of claim 1 wherein said end cap assembly is applied to an electrochemical cell by inserting it into the open end of a casing of said cell and welding the end cap assembly to the casing.

3. The end cap assembly of claim 1 wherein said thermally responsive means comprises a bimetallic member and a resilient electrically conductive member, the resilient member forming a portion of said electrical pathway, wherein when the temperature within said assembly reaches a predetermined level the bimetallic member deforms thereby pushing against said resilient metallic member causing a break in said electrical pathway.

4. The end cap assembly of claim 3 wherein the conductive member has a portion of reduced cross sectional area to act as a disintegrable fuse link to protect against power surge conditions.

5. The end cap assembly of claim 3 wherein the bimetallic member is movably positioned to engage a disk seat on a surface of an electrically insulating member within said end cap assembly.

6. The end cap assembly of claim 5 wherein a portion of said resilient conductive member is sandwiched between a portion of said end cap plate and a portion of said electrically insulating member.

7. The end cap assembly of claim 3 wherein said resilient conductive member includes a retainer means for limiting movement of said bimetallic member while not restricting its deforming action when the temperature within said assembly reaches a predetermined level.

8. The end cap assembly of claim 3 wherein said pressure responsive means comprises a diaphragm plate adapted to be electrically connected to a cell electrode when said end cap assembly is applied to an electrochemical cell, wherein said diaphragm plate deforms to cause a break in said electrical pathway thereby severing electrical connection between said end cap plate and said electrode when said end cap assembly is applied to a cell and the cell internal gas pressure reaches a first predetermined level.

9. The end cap assembly of claim 8 further comprising a support plate placed across the interior width of the end cap assembly, said support plate dividing the interior of the end cap assembly into an upper chamber and a lower chamber, the upper chamber being closer to the end cap plate than the lower chamber.

10. The end cap assembly of claim 9 further comprising an electrically conductive pressure resistant plate located at the end of the end cap assembly opposite said end cap plate, wherein said diaphragm plate is welded to the electrically conductive pressure resistant plate, said pressure resistant plate having at least one aperture therethrough, wherein a portion of said pressure resistant plate and a portion of said diaphragm forms at least part of said electrically conductive pathway.

11. The end cap assembly of claim 10 wherein said diaphragm plate ruptures when said end cap assembly is applied to a cell and gas pressure within the cell reaches a second predetermined level greater than said first predetermined level, whereupon gas from the interior of the cell passes through said ruptured diaphragm plate and into said lower chamber.

12. The end cap assembly of claim 10 wherein said diaphragm plate has a grooved path therein of reduced thickness.

13. The end cap assembly of claim 12 wherein said grooved path conforms generally to a major portion of the outer peripheral shape of the diaphragm plate wherein said grooved path provides a rupture path for said diaphragm.

14. The end cap assembly of claim 13 wherein said grooved path is of substantially "C" shape.

15. The end cap assembly of claim 11 wherein the support plate has at least one aperture therethrough so that gas from the interior of the cell which accumulates in the lower chamber may pass through said support plate aperture and into the upper chamber.

16. The end cap assembly of claim 15 wherein the end cap plate has at least one aperture therethrough so that gas which passes into said upper chamber may pass through said end cap aperture to the external environment.

17. The end cap assembly of claim 9 further comprising an electrically conductive contact plate welded to a surface of said support plate, wherein a portion of said resilient conductive member contacts said contact plate and wherein at least a portion of said contact plate and said resilient conductive member form a part of said electrically conductive pathway.

18. The end cap assembly of claim 9 wherein the peripheral edge of said support plate contacts the peripheral edge of said diaphragm plate and the diaphragm plate is electrically connectable to a cell electrode when the end cap assembly is applied to a cell.

19. The end cap assembly of claim 17 wherein when said bimetallic member reaches a predetermined temperature it deforms causing the resilient conductive member to sever its electrical connection with said contact plate.

20. The end cap assembly of claim 11 further comprising an electrically insulating grommet in contact with the peripheral edge of the end cap plate and the peripheral edge of the diaphragm plate, said end cap assembly further comprising a metallic crimping member mechanically crimped around said grommet to hold said diaphragm plate and said support plate under mechanical compression.

21. The end cap assembly of claim 20 further comprising a metallic cover contacting a portion of said crimping member and protecting the outside surface of said crimping member.

22. The end cap assembly of claim 17 wherein the end cap assembly is applied to a cell by inserting it into the open end of a cylindrical casing for the cell and welding the outside surface of said cover to the inside surface of said casing, whereupon the end cap assembly becomes tightly sealed within the cylindrical case with the end cap plate comprising a terminal of the cell being exposed to the external environment.

23. The end cap assembly of claim 1 wherein the thermally responsive means comprises a resilient conductive member in electrical contact with said end cap plate, and a meltable mass of material holding said resilient conductive member in electrical connection between said end cap plate and another conductive portion of the end cap assembly, said other conductive portion adapted to be electrically connected to a cell electrode when the end-cap assembly is applied to a cell thereby providing an electrical connection between said end cap plate and said electrode during cell operation, wherein when the cell temperature reaches a predetermined level said mass of material melts thereby causing movement in said resilient metallic member to sever the electrical connection between said end cap plate and said cell electrode thereby preventing operation of the cell.

24. In an electrochemical cell of the type formed by an end cap assembly inserted into an open ended cylindrical case for the cell, said cell further having a positive and a negative terminal and a pair of internal electrodes (anode and cathode), wherein said end cap assembly has a housing and an exposed end cap plate, said end cap plate functional as a cell terminal, the improvement comprising said end cap plate being electrically connected to one of said electrodes through an electrically conductive pathway within said end cap assembly, said end cap assembly further comprising a) thermally responsive means for preventing current from flowing through the cell, wherein said thermally responsive means is activatable when the temperature within the cell reaches a predetermined level causing a break in said electrical pathway between said end cap plate and said electrode thereby preventing current from flowing through the cell and b) pressure responsive means for causing a break in said electrical pathway between said end cap plate and said electrode when the internal gas pressure within the cell reaches a predetermined level thereby preventing current from-flowing through the cell.

25. The electrochemical cell of claim 24 wherein said thermally responsive means for preventing current flow through the cell comprises a bimetallic member and a resilient electrically conductive member, the resilient member being in electrical contact with said end cap plate and a cell electrode, thereby providing an electrical pathway therebetween, wherein when the cell temperature reaches a predetermined level the bimetallic member deforms and pushes against said resilient member causing said resilient member to sever said electrical pathway between the end cap plate and said cell electrode thereby preventing operation of the cell.

26. The electrochemical cell of claim 25 wherein the bimetallic member is movably positioned to engage a disk seat on a surface of an electrically insulating member within said end cap assembly.

27. The end cap assembly of claim 25 wherein the resilient conductive member has a portion of reduced cross sectional area to act as a disintegrable fuse link to protect against power surge conditions.

28. The electrochemical cell of claim 26 wherein a portion of said resilient conductive member is sandwiched between a portion of said end cap plate and a portion of said electrically insulating member.

29. The electrochemical cell of claim 24 wherein said pressure responsive means comprises a diaphragm plate adapted to be placed in electrical contact with a cell electrode when said end cap assembly is applied to an electrochemical cell, wherein said diaphragm plate deforms to cause a break in said electrical pathway thereby severing electrical connection between said end cap plate and said electrode when the cell internal gas pressure reaches a first predetermined level.

30. The electrochemical cell of claim 29 further comprising a support plate placed across the interior width of the end cap assembly, said support plate dividing the interior of the end cap assembly into an upper chamber and a lower chamber, the upper chamber being closer to the end cap plate than the lower chamber.

31. The electrochemical cell of claim 30 further comprising an electrically conductive pressure resistant plate located at the end of the end cap assembly opposite said end cap plate, wherein said diaphragm plate is welded t o an electrically conductive pressure resistant plate, said pressure resistant plate having a t least one aperture therethrough, wherein at least a portion of said pressure resistant plate and said diaphragm plate forms a part of said electrical pathway.

32. The electrochemical cell of claim 31 wherein said diaphragm plate ruptures when said end cap assembly is applied to a cell and gas pressure within the cell reaches a second predetermined level greater than said first predetermined level whereupon gas from the interior of the cell passes through said ruptured diaphragm plate and into said lower chamber.

33. The end cap assembly of claim 31 wherein said diaphragm plate has a grooved path therein of reduced thickness.

34. The end cap assembly of claim 33 wherein said grooved path conforms generally to a major portion of the outer peripheral shape of the diaphragm plate wherein said grooved path provides a rupture path for said diaphragm.

35. The end cap assembly of claim 34 wherein said grooved path is of substantially "C" shape.

36. The electrochemical cell of claim 32 wherein the support plate has at least one aperture therethrough so that gas from the interior of the cell which accumulates in the lower chamber may pass through said support plate aperture and into the upper chamber.

37. The electrochemical cell of claim 36 wherein the end cap plate has at least one aperture therethrough so that gas which passes into said upper chamber may pass through said end cap aperture to the external environment.

38. The electrochemical cell of claim 30 further comprising an electrically conductive contact plate welded to a surface of said support plate, wherein a portion of said resilient member contacts said contact plate and said support plate is electrically connectable to an electrode of the cell when the end cap assembly is applied to a cell.

39. The electrochemical cell of claim 30 wherein the peripheral edge of said support plate contacts the peripheral edge of said diaphragm plate and the diaphragm plate is electrically connectable to a cell electrode when the end cap assembly is applied to a cell.

40. The electrochemical cell of claim 38 wherein when the cell temperature reaches a predetermined temperature said bimetallic member deforms causing the metallic resilient member to sever its electrical connection with said contact plate.

41. The electrochemical cell of claim 37 further comprising an electrically insulating grommet in contact with the peripheral edge of the end cap plate and the peripheral edge of the diaphragm plate, said end cap assembly further comprising a metallic crimping member mechanically crimped around said grommet to hold said diaphragm plate and said support plate under mechanical compression.

42. The electrochemical cell of claim 41 further comprising a metallic cover contacting a portion of said crimping member and protecting the outside surface of said crimping member.

43. The electrochemical cell of claim 42 wherein the end cap assembly is applied to a cell by inserting it into the open end of a cylindrical casing for the cell and welding the outside surface of said cover to the inside surface of said casing, whereupon the end cap assembly becomes tightly sealed within the cylindrical case with the end cap plate comprising a terminal of the cell being exposed to the external environment.

44. The electrochemical cell of claim 24 wherein the thermally responsive means comprises a resilient conductive member in electrical contact with said end cap plate, and a meltable mass of material holding said resilient member in electrical connection between said end cap plate and another conductive portion of the end cap assembly, said other conductive portion adapted to be electrically connected to a cell electrode when the end cap assembly is applied to a cell thereby providing an electrical connection between said end cap plate and said electrode during cell operation, wherein when the cell temperature reaches a predetermined level said mass of material melts thereby causing movement in said resilient member to sever the electrical connection between said end cap plate and said cell electrode thereby preventing operation of the cell.

45. A current interrupter for providing protection to a device being supplied with electrical current comprising a housing member having an electrically conductive pathway therethrough in electrical connection with said device, a thermally responsive means contained within said housing member for preventing current from flowing through said electrical pathway, wherein said thermally responsive means is activated when the temperature within said housing reaches a predetermined level causing a break in said electrical pathway, and a pressure responsive means contained within said housing separate from said thermally responsive means for preventing current from flowing through said electrical pathway, wherein said pressure responsive means is activated when fluid pressure reaches a predetermined level causing a break in said electrical pathway.

46. The current interrupter of claim 45 wherein said thermally responsive means comprises a bimetallic member and a resilient electrically conductive member, the resilient member forming a portion of said electrical pathway, wherein when said bimetallic member reaches a predetermined level, it snaps thereby causing said resilient member to move causing a break in said electrical pathway.

47. The current interrupter of claim 46 wherein said resilient electrically conductive member has a portion of reduced cross-sectional area to act as fuse link to protect against power surge conditions.

48. The current interrupter of claim 45 wherein said pressure responsive means comprises an electrically conductive diaphragm member adapted to be electrically connected to said electrical pathway wherein when said pressure on said diaphragm member reaches a first predetermined level said diaphragm member deforms to cause a break in said electrical pathway.

49. The current interrupter of claim 48 wherein said diaphragm m ember ruptures when said fluid pressure upon said diaphragm member reaches a second predetermined level higher than said first predetermined level thereby allowing fluid to pass through said diaphragm member.

50. The current interrupter of claim 49 wherein said diaphragm member has a grooved path of reduced material thickness therein, wherein said grooved path acts as the rupture point when the fluid pressure on said diaghragm member reaches said second predetermined level.

51. The current interrupter of claim 50 wherein said grooved path conforms generally to a major portion of the outer peripheral shape of the diaphragm element.