Soft-magnetic dielectric high-frequency composite material and method for making the same
First Claim
1. A high-frequency composite material, having soft magnetic and dielectric characteristics, comprising a soft magnetic alloy powder represented by the general composition Aa Mb Dc and a synthetic resin,wherein A represents at least one element or mixture thereof selected from the group consisting of Fe, Co and Ni, M represents at least one element or mixture thereof selected from the group consisting of Hf, Zr, W, Ti, V, Nb, Mo, Cr, Mg, Mn, Al, Si, Ca, Sr, Ba, Cu, Ga, Ge, As, Se, Zn, Cd, In,Sn, Sb, Te, Pb, Bi, and rare earth elements, and D represents at least one element or mixture thereof selected from the group consisting of O, C and N,wherein the suffixes a, b, and c in said general formula Aa Mb Dc satisfy the following equations represented by atomic percent:
- 40<
a<
80,0<
b<
30, and0<
c<
50, andwherein soft magnetic alloy powder comprises agglomerates having an average particle size of 1 to 2 μ
m, where each agglomerate includes A in the form of body centered cubic (bcc) fine crystalline grains having an average grain size of a few nm to a few dozen nm, wherein the (bcc) fine crystalline phase is surrounded by an amorphous phase comprising M and D which occupies 50% or more of said agglomerates.
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Abstract
A high-frequency composite material, having soft magnetic and dielectric characteristics, comprising a soft magnetic alloy powder represented by the general composition Aa Mb Dc and a synthetic resin, wherein A represents at least one element or mixture thereof selected from the group consisting of Fe, Co and Ni; M represents at least one element or mixture thereof selected from the group consisting of Hf, Zr, W, Ti, V, Nb, Mo, Cr, Mg, Mn, Al, Si, Ca, Sr, Ba, Cu, Ga, Ge, As, Se, Zn, Cd, In, Sn, Sb, Te, Pb, Bi and rare earth elements; D represents at least one element or mixture thereof selected from the group consisting of O, C, N and B; and the suffixes a, b, and c in the general formula Aa Mb Dc satisfy the following equations represented by atomic percent: 40≦a<80, 0≦b≦30, and 0<c≦50.
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Citations
9 Claims
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1. A high-frequency composite material, having soft magnetic and dielectric characteristics, comprising a soft magnetic alloy powder represented by the general composition Aa Mb Dc and a synthetic resin,
wherein A represents at least one element or mixture thereof selected from the group consisting of Fe, Co and Ni, M represents at least one element or mixture thereof selected from the group consisting of Hf, Zr, W, Ti, V, Nb, Mo, Cr, Mg, Mn, Al, Si, Ca, Sr, Ba, Cu, Ga, Ge, As, Se, Zn, Cd, In,Sn, Sb, Te, Pb, Bi, and rare earth elements, and D represents at least one element or mixture thereof selected from the group consisting of O, C and N, wherein the suffixes a, b, and c in said general formula Aa Mb Dc satisfy the following equations represented by atomic percent: -
40<
a<
80,0<
b<
30, and0<
c<
50, andwherein soft magnetic alloy powder comprises agglomerates having an average particle size of 1 to 2 μ
m, where each agglomerate includes A in the form of body centered cubic (bcc) fine crystalline grains having an average grain size of a few nm to a few dozen nm, wherein the (bcc) fine crystalline phase is surrounded by an amorphous phase comprising M and D which occupies 50% or more of said agglomerates. - View Dependent Claims (2)
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3. A method for making a high-frequency composite material having soft magnetic and dielectric characteristics comprising:
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forming a soft magnetic alloy powder having a general formula Aa Mb Dc by a mechanical alloying process comprising mixing by grinding and stirring a powder A selected from the simple substance, oxide, carbide, carbonate, nitride and boride of at least one element selected from the group consisting of Fe, Co, and Ni, and a powder M selected from the simple substance, oxide, carbide, carbonate, nitride and boride of at least one element selected from the group consisting of Hf, Zr, W, Ti, V, Nb, Mo, Cr, Mg, Mn, Al, Si, Ca, Sr, Ba, Cu, Ga, Ge, As, Se, Zn, Cd, In, Sn, Sb, Te, Pb, Bi and rare earth elements, in an atmosphere of a gas D selected from the simple substance gas, oxide gas, and carbonate gas of at least one element selected from the group consisting of O, C and N, or of a gaseous mixture of the gas D and inert gas, wherein the suffixes a, b and c in said general formula Aa Mb Dc satisfy the following equations represented by atomic percent; 40<
a<
80,0<
b<
30, and0<
c<
50, andwherein soft magnetic alloy powder comprises agglomerates having an average particle size of 1 to 2 μ
m, where each agglomerate includes A in the form of body centered cubic (bcc) fine crystalline grains having an average grain size of a few nm to a few dozen nm, wherein the (bcc) fine crystalline phase is surrounded by an amorphous phase comprising M and D which occupies 50% or more of said agglomerates;dispersing to mix the soft magnetic alloy powder into a synthetic resin; and molding the mixture into the high-frequency composite material. - View Dependent Claims (5)
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4. A method for making a high-frequency composite material having soft magnetic and dielectric characteristics comprising:
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forming a soft magnetic alloy powder having a general formula Aa Mb Dc by grinding powder of an A--M alloy ribbon, obtained by a liquid quenching method in an atmosphere of a gas D selected from the simple substance gas, oxide gas, and carbonate gas of at least one element selected from the group consisting of O, C and N, or of a gaseous mixture of the gas D and inert gas, wherein the suffixes a, b, and c in said general formula A Mb Dc satisfy the following equations represented by atomic percent; 40<
a<
80,0<
b<
30, and0<
c<
50, andwherein soft magnetic alloy powder comprises agglomerates having an average particle size of 1 to 2 μ
m, where each agglomerate includes A in the form of body centered cubic (bcc) fine crystalline grains having an average grain size of a few nm to a few dozen nm, wherein the (bcc) fine crystalline phase is surrounded by an amorphous phase comprising M and D which occupies 50% or more of said agglomerates;dispersing to mix the soft magnetic alloy powder into a synthetic resin; and molding the mixture into the high-frequency composite material.
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6. A method for making a high-frequency composite material having soft magnetic and dielectric characteristics comprising:
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forming a soft magnetic alloy powder having the general formula Aa Mb Dc by a mechanical alloying process comprising mixing by grinding and stirring a powder A selected from the simple substance, oxide carbide, carbonate and nitride of at least one element selected from the group consisting of Fe, Co and Ni, a powder M selected from the simple substance, oxide, carbide, carbonate and nitride of at least one element selected from the group consisting of Hf, Zr, W, Ti, V, Nb, Mo, Cr, Mg, Mn, Al, Si, Ca, Sr, Ba, Cu, Ga, Ge, As, Se, Zn, Cd, In, Sn, Sb, Te, Pb, and Bi, and a powder D consists of C, wherein the suffixes a, b, and c in said general formula Aa Mb Dc satisfy the following equations represented by atomic percent; 40<
a<
80,0<
b<
30, and0<
c<
50, andwherein soft magnetic alloy powder comprises agglomerates having an average particle size of 1 to 2 μ
m, where each agglomerate includes A in the form of body centered cubic (bcc) fine crystalline grains having an average grain size of a few nm to a few dozen nm, wherein the (bcc) fine crystalline phase is surrounded by an amorphous phase comprising M and D which occupies 50% or more of said agglomerates;dispersing to mix the soft magnetic alloy powder into a synthetic resin; and molding the mixture into the high-frequency composite material. - View Dependent Claims (8, 9)
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7. A method for making a high-frequency composite material having soft magnetic and dielectric characteristics comprising:
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forming a soft magnetic alloy powder having the general formula Aa Mb Dc by grinding powder of an A--M alloy ribbon, obtained by a liquid quenching method in an atmosphere of a gas D selected from the simple substance gas, oxide gas and carbonate gas of C, wherein the suffixes a, b, and c in said general formula Aa Mb Dc satisfy the following equations represented by atomic percent; 40<
a<
80,0<
b<
30, and0<
c<
50, andwherein soft magnetic alloy powder comprises agglomerates having an average particle size of 1 to 2 μ
m, where each agglomerate includes A in the form of body centered cubic (bcc) fine crystalline grains having an average grain size of a few nm to a few dozen nm, wherein the (bcc) fine crystalline phase is surrounded by an amorphous phase comprising M and D which occupies 50% or more of said agglomerates;dispersing to mix the soft magnetic alloy powder into a synthetic resin; and molding the mixture into the high-frequency composite material.
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Specification