Compositions based on an abrasive system and on a surfactant system

• US 5,756,074 A
• Filed: 01/23/1996
• Issued: 05/26/1998
• Est. Priority Date: 01/30/1995
• Status: Expired due to Fees

• Current Assignee: The Procter & Gamble Company
• Original Assignee: L'Oreal SA
• Inventors: Sterle, Pascal, Ascione, Jean-Marc
• Primary Examiner(s): Rose, Shep K.
• Application Number:
  US08/590,460
• Time in Patent Office: 854 Days
• Field of Search: 404/49-58
• US Class Current: 424/52
• CPC Class Codes: A61K 8/19 containing inorganic ingredients
• CPC Class Codes: A61K 8/39 Derivatives containing from 2 to 10 oxyalkylene groups
• CPC Class Codes: A61K 8/463 containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
• CPC Class Codes: A61Q 11/00 Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
• CPC Class Codes: C09K 3/1463 Aqueous liquid suspensions

Abstract

New compositions comprising an abrasive system comprising an alkali metal bicarbonate and a surfactant system comprising a non-ionic poly(hydroxypropyl ether) surfactant, which are characterized in that the said surfactant system further comprises an alkali metal, alkaline-earth metal or ammonium lauryl sulphate, particularly a sodium lauryl sulphate or a magnesium lauryl sulphate. Such compositions are in particular oral hygiene compositions.

The invention also relates to the use of these compositions as, or for the manufacture of, a dentifrice in the form of a paste, a gel, a liquid or a chewing gum.

Claims

1. A composition comprising an abrasive system including at least one alkali metal bicarbonate and a surfactant system including at least one non-ionic poly(hydroxypropyl ether) surfactant, wherein said surfactant system further comprises at least one alkali metal lauryl sulphate, alkaline-earth metal lauryl sulphate, or ammonium lauryl sulfate.

2. Composition according to claim 1 wherein said alkali metal bicarbonate is sodium bicarbonate or potassium bicarbonate.

3. Composition according to claim 1 wherein said lauryl sulphate is said alkali metal lauryl sulphate.

4. Composition according to claim 1 wherein said alkali metal lauryl sulphate is sodium lauryl sulphate.

5. Composition according to claim 1 wherein said lauryl sulphate is said alkaline-earth metal lauryl sulphate.

6. Composition according to claim 1 wherein said alkaline-earth metal lauryl sulphate is magnesium lauryl sulphate.

7. Composition according to claim 1 wherein said lauryl sulphate is ammonium lauryl sulphate.

8. Composition according to claim 1 wherein said non-ionic poly(hydroxypropyl ether) surfactant is one of the following compounds:

(A) the compounds corresponding to the formula (I);

##STR6## in which the ##STR7## group represents the following structures (I.a), (I.b) and (I.c), taken together or separately;

##STR8## and R and n have, together, one of the meanings below;

a) R denotes a C₁₀ -C₁₄ alkyl radical or a mixture of C₁₀ -C₁₄ alkyl radicals, and n is a whole or decimal number from 2 to 10;

b) R denotes a group of formula (II);

space="preserve" listing-type="equation">R.sub.2 --CONH--CH.sub.2 --CH.sub.2 --O--CH.sub.2 --CH.sub.2 --(II)

in which R₂ denotes a C₁₁ -C₁₇ -alkyl or -alkenyl radical, a mixture of C₁₁ -C₁₇ -alkyl radicals, a mixture of C₁₁ -C₁₇ -alkenyl radicals, or a mixture of C₁₁ -C₁₇ -alkyl radicals and C₁₁ -C₁₇ -alkenyl radicals, and n denotes a whole or decimal number from 1 to 5;

or

c) R denotes a group of formula (III);

space="preserve" listing-type="equation">R.sub.3 --CHOH--CH.sub.2 -- (III)

in which R₃ denotes a C₇ -C₂₁ aliphatic, C₇ -C₂₁ cycloaliphatic or C₇ -C₂₁ arylaliphatic radical, or a mixture of any of said C₇ -C₂₁ radicals, and

n denotes a whole or decimal number from 1 to 10;

(B) the non-ionic poly(hydroxypropyl ether) surfactants prepared by condensation and at a temperature ranging from 50°

to 120°

C., of 2 to 10 mole of glycidol per mole of either alcohol containing 10 to 14 carbon atoms or of alpha-diol containing 10 to 14 carbon atom; and

(C) the non-ionic poly(hydroxypropyl ether) surfactants prepared by polyaddition of glycerol monocholorodrin to a polyhydroxylated organic compound in the presence of a strong base, with removal of the water, by distillation, as said water is formed.

9. A composition according to claim 8, wherein:

in (A) a), n is a whole or decimal number from 3 to 6;

in (A) b), n is a whole or decimal number from 1.5 to 4;

in (A) c), the aliphatic chains denote alkyl chains which can contain from 1 to 6 ether groups, thioether groups, hydroxymethylene groups, and mixtures of any of said groups; and

in (B), there are 2.5 to 6 mole of glycidol per mole of either alcohol containing 10 to 14 carbon atoms or of alpha-diol containing 10 to 14 carbon atoms.

10. Composition according to claim 8 wherein said non-ionic poly(hydroxypropyl ether) surfactant is one of the following compounds:

##STR9## in which formula (V) R₁ denotes a mixture of C₁₀ H₂₁, and C₁₂ H₂₅ alkyl radicals;

ii) the compounds prepared by condensation of 3.5 mole of glycidol with an alpha-diol having 12 carbon atoms;

iii) the compounds of formula (VI);

##STR10## in which R₂ denotes a mixture of radicals comprising the following alkyl and alkenyl radicals;

C₁₁ H₂₃, C₁₃ H₂₇, the radicals derived from coconut fatty acids and the radical derived from oleic acid; and

iv) the compounds prepared by condensation of 3.5 mole of glycidol with a mixture of C₁₁ -C₁₄ alpha-diols.

11. Composition according to claim 8 wherein the non-ionic poly(hydroxypropyl ether) surfactant is a dodecanediol polyglycerolated with 3.5 mole of glycerol.

12. Composition according to claim 1 wherein said at least one alkali metal bicarbonate is present in a concentration by weight ranging from 0.5 to 80% with respect to the total weight of the composition.

13. Composition according to claim 12 wherein said concentration by weight ranges from 1 to 50%.

14. Composition according to claim 1 wherein said at least one non-ionic poly(hydroxypropyl ether) surfactant is present in a concentrations by weight ranging from 0.01 to 10% with respect to the total weight of the composition.

15. Composition according to claim 14 wherein said concentration by weight ranges from 0.05 to 5%.

16. Composition according to claim 1 wherein said at least one alkali metal lauryl sulphate, alkaline-earth metal lauryl sulphate, or ammonium lauryl sulphate is present in a concentrations by weight ranging from 0.01 to 10% with respect to the total weight of the composition.

17. Composition according to claim 16 wherein said concentration ranges from 0.05 to 5% with respect to the total weight of the composition.

18. An oral hygiene composition comprising a composition according to claim 1.

19. An oral hygiene composition according to claim 18, wherein said composition is a dentifrice.

20. Composition according to claim 18 wherein said oral hygiene composition further comprises at least one physiologically acceptable ingredient.

21. Composition according to claim 1 wherein said composition further comprises at least one ingredient selected from silica, alumina, calcium hydrogenphosphate and calcium carbonate, anticarious agents, antibacterial agents, antiinflammatory agents, antihalitosis agents, agents for combatting stains and/or tartar, agents for combatting free radicals, anti-oxidants, enzymes, vitamins, trace elements, haemostatic agents, and healing agents.

22. Composition according to claim 21 wherein said anticarious agents are sodium, potassium, amine fluorides, and sodium monofluorophosphate.

23. Composition according to claim 21 wherein said antibacterial agents are chlorhexidine, alexidine, hexetidine, cetylpyridinium chloride and 2,4,4'"'"'-trichloro-2'"'"'-hydroxydiphenyl ether.

24. Compositions according to claim 21 wherein said composition further comprises at least one ingredient selected from binding agents, sweeteners, humectants or fresheners, preservatives, dyes, fragrances, flavouring agents, peptizing agents and plasticizers.

25. A method of making a liquid dentifrice, a toothpaste, a tooth gel or a chewing gum comprising the step of including in said liquid dentifrice, toothpaste, tooth gel or chewing gum the composition according to claim 1.