Process for the preparation of gas-generating compositions

• US 5,756,930 A
• Filed: 03/21/1996
• Issued: 05/26/1998
• Est. Priority Date: 03/21/1995
• Status: Expired due to Fees

• Current Assignee: ICI Canada, Inc. (Ici Paints), Imperial Chemical Industries PLC (IMPERIAL CHEMICAL INDUSTRIES)
• Original Assignee: ICI Canada, Inc. (Ici Paints), Imperial Chemical Industries PLC (IMPERIAL CHEMICAL INDUSTRIES)
• Inventors: Oliver, Ray, Hsu, Noel Yu Wee, Chan, Sek Kwan
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US08/621,193
• Time in Patent Office: 796 Days
• Field of Search: 149/35, 149/109.6
• US Class Current: 149/109.6
• CPC Class Codes: C06B 21/0066 by granulation, e.g. flaking
• CPC Class Codes: C06B 21/0091 Elimination of undesirable or temporary components of an intermediate or finished product, e.g. making porous or low density products, purifying, stabilising, drying; Deactivating; Reclaiming; porous inert particles or chemicals compounded for these purposes C06B23/00
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

A process for the production of a gas-generating composition containing a redox-couple including a water soluble azide component, for example, azide of sodium, potassium, lithium, calcium or barium, and an oxidizer component, for example, sodium nitrate, sodium perchlorate, potassium nitrate, potassium perchlorate or an oxide of iron, nickel, vanadium, copper, titanium, manganese, zinc, tantalum, silicon or aluminium, said oxidizer component being capable of reacting with said azide component to generate gas, said process comprising the steps of:

forming an aqueous dispersion of the redox-couple wherein the azide component is totally dissolved and the oxidizer is uniformly dispersed and stabilised in the azide solution;

passing said aqueous dispersion through a spray nozzle to form a stream of droplets; and

contacting said droplets with hot air whereby the water is removed to produce solid particles of gas-generating composition.

Claims

1. A process for the production of a gas-generating composition containing a redox-couple comprising a water soluble azide component and an oxidizer component said oxidizer component being capable of reacting with said azide component to generate gas, said process comprising the steps of:

forming an aqueous dispersion of the redox-couple wherein the azide component is totally dissolved and the oxidizer is uniformly dispersed and stabilised in the azide solution;

passing said aqueous dispersion through a spray nozzle to form a stream of droplets; and

contacting said droplets with hot air whereby water is removed from the droplets to produce solid particles of gas-generating composition.

2. A process as claimed in claim 1 wherein the said azide component comprises an azide selected from the group consisting of alkali metal azides and alkaline earth metal azides.

3. A process as claimed in claim 2 wherein said azide is selected from the group consisting of the azides of sodium, potassium, lithium, calcium and barium.

4. A process as claimed in claim 1 wherein said oxidizer component comprises a water-soluble oxidizing compound.

5. A process as claimed in claim 1 wherein the said oxidizer component comprises a water-insoluble oxidizer and the said aqueous dispersion is a slurry of the oxidizer in the azide solution.

6. A process as claimed in claim 1 wherein the oxidizer component comprises an oxide selected from the group consisting of the oxides of iron, nickel, vanadium, copper, titanium, manganese, zinc, tantalum, silicon and aluminium.

7. A process as claimed in claim 6 wherein the oxide particle size is in the range from 0.1 to 1.0 μ

m. in diameter.

8. A process as claimed in claim 5 wherein silica is incorporated in the aqueous dispersion in sufficient quantity to reduce or prevent migration of the oxidizer component.

9. A process as claimed in claim 8 wherein the silica particles are less than 0.2 μ

m in diameter.

10. A process as claimed in claim 5 wherein the said aqueous dispersion comprises 50 to 70 parts by weight of sodium azide, 20 to 30 parts by weight of iron oxide and 5 to 14 parts by weight of silica dispersed in sufficient water to dissolve all the azide.

11. A process as claimed in claim 10 wherein the dispersion comprises 100 pairs by weight of water for each 30 to 45 parts by weight of azide.

12. A process as claimed in claim 5 wherein the oxidizer is uniformly dispersed in the azide solution by vigorous agitation until the viscosity of the dispersion is sufficiently high to prevent substantial migration of the oxidizer in the dispersion.

13. A process as claimed in claim 1 wherein the aqueous dispersion is atomised into droplets 40 to 200 μ

m in diameter by passing the dispersion under pressure through a nozzle having one or more orifices of 0.5 to 2.5 mm in diameter.

14. A process as claimed in claim 1 wherein the droplets are spray-dried by allowing them to fall into a stream of air at a temperature in the range from 80°

to 250°

C.

15. A process cas claimed in claim 1 wherein the solid particulate gas-generating composition is pressed into pellets or grains.

16. A process as claimed in claim 15 wherein the said gas-generating composition is mixed before pressing with a pressing agent selected from the group consisting of graphite and mixtures of water and hydrophobic fumed silica.