Multicolor organic light emitting devices

• US 5,757,026 A
• Filed: 04/15/1996
• Issued: 05/26/1998
• Est. Priority Date: 12/13/1994
• Status: Expired due to Term

• Current Assignee: The Trustees of Princeton University (Princeton University)
• Original Assignee: The Trustees of Princeton University (Princeton University)
• Inventors: McCarty, Dennis Matthew, Burrows, Paul Edward, Sapochak, Linda Susan, Forrest, Stephen Ross, Thompson, Mark Edward
• Primary Examiner(s): MINTEL, WILLIAM A
• Application Number:
  US08/632,322
• Time in Patent Office: 771 Days
• Field of Search: 257/89, 257/90, 257/88, 257/40, 257/91, 257/92, 257/93, 257/103
• US Class Current: 257/40
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: H01L 24/82 by forming build-up interconnects at chip-level, e.g. for high density interconnects [HDI] interconnection structure between a plurality of semiconductor chips H01L23/5389
• CPC Class Codes: H01L 27/156 two-dimensional arrays
• CPC Class Codes: H01L 2924/00 Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
• CPC Class Codes: H01L 2924/12033 Gunn diode
• CPC Class Codes: H01L 2924/12041 LED
• CPC Class Codes: H01L 2924/12042 LASER
• CPC Class Codes: H01L 2924/12044 OLED
• CPC Class Codes: H10K 2102/3031 Two-side emission, e.g. transparent OLEDs [TOLED]
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/125 specially adapted for multicolour light emission, e.g. for emitting white light
• CPC Class Codes: H10K 50/14 Carrier transporting layers
• CPC Class Codes: H10K 50/828 Transparent cathodes, e.g. comprising thin metal layers
• CPC Class Codes: H10K 59/32 Stacked devices having two or more layers, each emitting at different wavelengths
• CPC Class Codes: H10K 85/10 Organic polymers or oligomers
• CPC Class Codes: H10K 85/111 comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
• CPC Class Codes: H10K 85/113 Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
• CPC Class Codes: H10K 85/114 Poly-phenylenevinylene; Derivatives thereof
• CPC Class Codes: H10K 85/146 poly N-vinylcarbazol; Derivatives thereof
• CPC Class Codes: H10K 85/30 Coordination compounds
• CPC Class Codes: H10K 85/322 : comprising boron
• CPC Class Codes: H10K 85/324 : comprising aluminium, e.g. Alq3
• CPC Class Codes: H10K 85/341 : Transition metal complexes, e.g. Ru(II)polypyridine complexes H10K85/331 takes precedence
• CPC Class Codes: H10K 85/60 : Organic compounds having low molecular weight H10K85/10 - H10K85/50 take precedence
• CPC Class Codes: H10K 85/611 : Charge transfer complexes
• CPC Class Codes: H10K 85/631 : Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
• CPC Class Codes: Y10T 428/26 : Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/265 : 1 mil or less
• CPC Class Codes: Y10T 428/31678 : Of metal

Abstract

A multicolor organic light emitting device employs vertically stacked layers of double heterostructure devices which are fabricated from organic compounds. The vertical stacked structure is formed on a glass base having a transparent coating of ITO or similar metal to provide a substrate. Deposited on the substrate is the vertical stacked arrangement of three double heterostructure devices, each fabricated from a suitable organic material. Stacking is implemented such that the double heterostructure with the longest wavelength is on the top of the stack. This constitutes the device emitting red light on the top with the device having the shortest wavelength, namely, the device emitting blue light, on the bottom of the stack. Located between the red and blue device structures is the green device structure. The devices are configured as stacked to provide a staircase profile whereby each device is separated from the other by a thin transparent conductive contact layer to enable light emanating from each of the devices to pass through the semitransparent contacts and through the lower device structures while further enabling each of the devices to receive a selective bias.

Claims

1. A multicolor display, comprising:

a plurality of multicolor light emitting device pixel structures arranged in rows and columns to provide a display surface with each pixel structure consisting of at least one multicolor light emitting device structure wherein each device structure comprises first, second and third light emitting devices (LED'"'"'s) stacked one upon the other to form a layered structure, with each LED separated by a transparent conductive layer, and whereby said display can be biased via said conductive layers to cause said multicolor light emitting devices to emit light when biased.

2. The multicolor display of claim 1, wherein said first LED emits blue light (B), said second LED emits green light (G) and said third LED emits red light (R).

3. The multicolor display of claim 1, wherein each LED device is a double heterostructure (DH) device capable of emitting light as a function of an organic compound employed in said device.

4. The multicolor display of claim 1, wherein each of said LED devices is a single heterostructure (SH) device capable of emitting light as a function of an organic compound employed in said device.

5. The multicolor display of claim 1, wherein each of said LED devices is a polymer structured device capable of emitting light as a function of an organic compound employed in said device.

6. The display of claim 1, wherein said plurality of multicolor device structures as arranged in rows and columns on a glass substrate coated with a thin transparent layer of ITO and with each of said first, second and third LED devices of each pixel stacked on said substrate to form a separate pixel location.

7. A multicolor, energizable, light emitting display comprising:

a plurality of energizable, light emitting structures;

each of said structures comprising a plurality of transparent, light emitting devices (LED) that are stacked on each other;

each of said LEDs in each of said structures being operative to emit a different color light when energized; and

means for selectively energizing at least one of said LEDs in each of said structures so that the color produced by each of said light emitting structures is determined by which LED or LEDs in each light emitting structure is energized so that light emitted from said structures creates an image having a predetermined shape and color.

8. The display of claim 7, wherein said energizable, light emitting structures are arranged in an array, said array including at least two axes, and each of said light emitting structures is at the intersection of at least two of said axes.

9. The display of claim 8, wherein said axes define a horizontal axis and a vertical axis.

10. The display of claim 8, wherein said means for selectively energizing at least one of said LEDs in each of said structures includes:

means for selecting the structures and the LEDs in those structures to be energized; and

means for serially scanning each of said axes so that said means for selectively energizing at least one of said LEDs scans along said axes so that said selected ones of said LEDS at the intersection of said axes are serially energized to emit light so that said image and said colors are created serially.

11. The display of claim 7, wherein said means for selectively energizing at least one of said LEDs in each of said structures includes:

means for substantially serially energizing said LEDs that are in said structures so that said image and said colors are created serially by said structures.

12. The display of claim 7, wherein said for means for selectively energizing said LEDs is operative to simultaneously energize selected ones of said LEDs in selected ones of said structures so that said image and said colors are created simultaneously by said selected ones of said LEDs in said selected ones of said structures.

13. The display of claim 7, wherein each of said structures further includes:

a transparent substrate;

said LEDs each having a bottom and a top and defining a stack of LEDs having a bottom and a top, said stack being supported on said transparent substrate;

a first layer of substantially transparent, electrically conductive material, said first layer being disposed between said bottom LED and said transparent substrate;

at least one second layer of substantially transparent, electrically conductive material, said second layers being disposed between adjacent ones of said LEDs;

a first layer of electrically conductive material, said first layer being disposed adjacent the top of said top LED; and

means on each of said layers of electrically conductive material for being connected to a bias for selectively energizing each of said LEDs.

14. The display of claim 13, wherein each of said layers of substantially transparent, electrically conductive material and said layer of electrically conductive material includes a layer of indium-tin-oxide.

15. The display of claim 13, wherein each of said layers of substantially transparent, electrically conductive material, and said layer of electrically conductive material, includes a layer of metal and a layer of indium-tin-oxide.

16. The display of claim 15, wherein said metal has a work function of less than about four electron volts.

17. The display of claim 13, further including:

a layer of reflective material disposed on the layer of electrically conductive material adjacent the top of said top LED so that light from said LEDs is reflected through said transparent substrate by said layer of reflective material.

18. The display of claim 17, further including:

said stack of LEDs is supported by said transparent substrate in an order that corresponds to the wavelength of the light that said LEDs emit; and

said LED emitting the shortest wavelength is closest to said transparent substrate so that the light emitted from each of said LEDs when it is energized is transmitted through the other LEDs and through said transparent substrate.

19. The display of claim 18, further including a layer of anti-reflecting material disposed between said LED emitting the shortest wavelength and said transparent substrate so that the light emitted from each of said LEDs when it is energized is not reflected from said transparent substrate.

20. The display of claim 7, further including:

a transparent substrate;

each of said LEDs having a top and a bottom;

at least two layers of substantially transparent, electrically conductive material, one of said layers being disposed on said transparent substrate;

the bottom of one of said LEDs in each of said structures being supported on said one layer of substantially transparent, electrically conductive material;

the others of said layers of substantially transparent, electrically conductive material being disposed between the remainder of said LEDs so that said LEDs define a stack;

a layer of electrically conductive material supported on the top of said LED in said stack that is furthest from said transparent substrate; and

means on each of said layers of substantially transparent, electrically conductive material, and on said layer of electrically conductive material, for connecting these layers to a source of bias voltage for selectively energizing each of said LEDs.

21. The display of claim 20, wherein each of said layers of substantially transparent, electrically conductive material, and said layer of electrically conductive material include a layer of indium-tin-oxide.

22. The display of claim 20, wherein said layers of substantially transparent, electrically conductive material and each of said layers of electrically conductive material include a layer of metal and a layer of indium-tin-oxide.

23. The display of claim 22, wherein said metal has a work function of less than about four electron volts.

24. The display of claim 20, further including:

a layer of reflective material disposed on said layer of substantially transparent, electrically conductive material adjacent the top of said top LED so that light is reflected through said transparent substrate by said layer of reflective material.

25. The structure of claim 24, wherein

said stack of LEDs is supported by said transparent substrate in an order that corresponds to the wavelength of the light that said LEDs emit, and

said LED emitting the shortest wavelength is closest to said transparent substrate so that the light emitted from each of said LEDs when it is energized is transmitted through the other LEDs and through said transparent substrate.

26. The structure of claim 25, further including:

a layer of anti-reflecting material disposed between said LED emitting the shortest wavelength and said transparent substrate so that the light emitted from each of said LEDs when it is energized is not reflected from said transparent substrate.

27. The display of claim 7, wherein said plurality of LED'"'"'s include:

three LEDs;

each of said LEDs being a double heterostructure (DH);

said LED closest to said transparent substrate being operative when energized to emit blue light;

said LED furthest from said transparent substrate being operative when energized to emit red light; and

said other LED being operative when energized to emit green light.

28. The multicolor light emitting display of claim 27, wherein each of said LEDs includes an emission layer containing an organic material selected from the group consisting of trivalent metal quinolate complexes, trivalent metal bridged quinolate complexes, Schiff base divalent metal complexes, tin (iv) metal complexes, metal acetylacetonate complexes, metal bidentate ligand complexes, bisphosphonates, divalent metal maleonitriledithiolate complexes, molecular charge transfer complexes, aromatic and heterocyclic polymers and rare earth mixed chelates.

29. The display of claim 7, wherein said plurality of LED'"'"'s include:

three LEDs;

each of said LEDs being single heterostructures (SH);

said LED closest to said transparent substrate being operative when energized to emit blue light;

said LED furthest from said transparent substrate being operative when energized to emit red light; and

said other LED being operative when energized to emit green light.

30. The multicolor light emitting display of claim 29, wherein each of said LEDs includes an emission layer containing an organic material selected from the group consisting of trivalent metal quinolate complexes, trivalent metal bridged quinolate complexes, Schiff base divalent metal complexes, tin (iv) metal complexes, metal acetylacetonate complexes, metal bidentate ligand complexes, bisphosphonates, divalent metal maleonitriledithiolate complexes, molecular charge transfer complexes, aromatic and heterocyclic polymers and rare earth mixed chelates.