Lithiated manganese oxide

• US 5,759,510 A
• Filed: 10/03/1996
• Issued: 06/02/1998
• Est. Priority Date: 10/03/1996
• Status: Expired due to Term

• Current Assignee: Carus Chemical Company
• Original Assignee: Carus Chemical Company
• Inventors: Pillai, G. Chithambarathanu
• Primary Examiner(s): BOS, STEVEN J
• Application Number:
  US08/726,323
• Time in Patent Office: 607 Days
• Field of Search: 423/599
• US Class Current: 423/599
• CPC Class Codes: C01G 45/02 Oxides; Hydroxides
• CPC Class Codes: C01G 45/1242 of the type [Mn2O4]-, e.g. LiMn2O4, Li[MxMn2-x]O4
• CPC Class Codes: C01P 2002/72 by d-values or two theta-values, e.g. as X-ray diagram
• CPC Class Codes: C01P 2006/40 Electric properties
• CPC Class Codes: H01M 10/05 Accumulators with non-aqueous electrolyte H01M10/39 takes precedence
• CPC Class Codes: H01M 4/505 of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention is directed to making a lithiated manganese dioxide using low and high temperature calcination steps.

Claims

1. A method for making lithiated manganese oxide, the method comprising:

providing amorphous manganese dioxide which includes an alkali metal selected from the group consisting of sodium, potassium and mixtures thereof;

blending the amorphous manganese dioxide with a lithium compound to provide a lithium compound/manganese dioxide blend, the lithium compound being in molar excess of at least about 1.6 moles of lithium compound per mole of manganese dioxide;

calcining the lithium compound/manganese dioxide blend at from about 150°

to about 550°

C. for about 2 to about 72 hours to provide an initially calcined lithium/manganese complex;

washing the initially calcined lithium/manganese complex with aqueous lithium hydroxide to provide a washed initially calcined lithium/manganese complex, the washing being effective to provide the washed initially calcined lithium/manganese complex which when slurried with water at a ratio of about 1 part complex to about 3 parts water will result in an aqueous slurry with a pH in the range of from about 11 to about 13;

slurrying the washed initially calcined lithium/manganese complex with water to provide an aqueous slurry and adjusting the pH of the aqueous slurry of the washed lithium/manganese complex to a pH of less than about 7, the pH adjustment effective to provide a lithium/manganese complex which when calcined will provide a lithiated manganese compound having the formula Li_x Mn₂ O₄ where x is greater than 0 and less than about 2; and

calcining the lithium/manganese complex from about 500°

to about 900°

C. for a time effective to provide the lithiated manganese compound having the formula Li_x Mn₂ O₄ where x is greater than 0 and less than about 2.

2. A method as recited in claim 1 wherein the lithium compound is lithium hydroxide.

3. A method as recited in claim 1 or 2 wherein the pH of the aqueous slurry of the washed initially calcined lithium/manganese complex is adjusted to a range of from about 6.0 to about 6.5.

4. A method as recited in claim 1 wherein x is about 1.

5. A method as recited in claim 3 wherein x is about 1.

6. A method as recited in claims 1 or 3 wherein the aqueous slurry which has its pH adjusted to less than about 7 comprises about one part washed initially calcined lithium/maganese complex and about three parts water.

7. A method for making lithiated manganese oxide, the method comprising:

chemically reducing an alkali metal permanganate or alkali metal manganate under alkaline conditions to provide an amorphous reduced manganese dioxide which includes an alkali metal selected from the group consisting of sodium, potassium and mixtures thereof;

blending the reduced manganese dioxide with a lithium compound to provide a lithium/manganese dioxide blend, the lithium compound being in molar excess of the manganese dioxide to remove the alkali metal from the reduced manganese dioxide;

calcining the lithium/manganese dioxide blend at from about 150°

to about 550°

C. for about 2 to about 72 hours to provide an initially calcined lithium/manganese complex;

washing the initially calcined lithium/manganese complex with aqueous lithium hydroxide to provide a washed initially calcined lithium/manganese complex, the washing being effective to provide the washed initially calcined lithium/manganese complex which when slurried with water at a ratio of about 1 part complex to about 3 parts water will result in an aqueous slurry with a pH in the range of from about 11 to about 13;

slurrying the washed initially calcined lithium/maganese complex with water to provide an aqueous slurry and adjusting the pH of the aqueous slurry of the washed lithium/maganese complex to a pH of less than about 7, the pH adjustment effective to provide a lithium/maganese complex which when calcined will provide a lithiated manganese compound having the formula Li_x Mn₂ O₄ where x is greater than 0 and less than about 2; and

calcining the lithium/maganese complex from about 500°

to about 900°

C. for a time effective to provide the lithiated manganese compound having the formula Li_x Mn₂ O₄ where x is greater than 0 and less than about 2.

8. A method as recited in claim 7 wherein the lithium compound is lithium hydroxide.

9. A method as recited in claim 7 or 8 wherein the pH of the aqueous slurry of the washed initially calcined lithium/manganese complex is adjusted to a range of from about 6.0 to about 6.5.

10. A method as recited in claim 7 wherein x is about 1.

11. A method as recited in claim 9, wherein x is about 1.

12. A method as recited in claims 7 or 8 wherein the aqueous slurry which has its pH adjusted to less than about 7 comprises about one part washed initially calcined lithium/maganese complex and about three parts water.

13. A method for making lithiated manganese oxide, the method comprising:

chemically reducing an alkali metal permanganate selected from the group consisting of potassium permanganate, sodium permanganate and mixtures thereof under alkaline conditions to provide a permanganate reduced manganese dioxide;

blending the permanganate reduced manganese dioxide with a lithium compound to provide a lithium/manganese dioxide blend, the lithium compound being in molar excess of from about 1.6 to about 3.0 moles of lithium compound per mole of manganese dioxide;

calcining the lithium/manganese dioxide blend at from about 150°

to about 550°

C. for about 2 to about 72 hours to provide an initially calcined lithium/manganese complex;

washing the initially calcined lithium/manganese complex with aqueous lithium hydroxide to provide a washed initially calcined lithium/manganese complex, the washing being effective to provide the washed initially calcined lithium/manganese complex which when slurried with water at a ratio of about 1 part complex to about 3 parts water will result in an aqueous slurry with a pH in the range of from about 11 to about 13;

slurrying the washed initially calcined lithium/manganese complex with water to provide an aqueous slurry and adjusting the pH of the aqueous slurry of the washed lithium/manganese complex to a pH of less than about 7, the pH adjustment effective to provide a lithium/manganese complex which when calcined will provide a lithiated manganese compound having the formula Li_x Mn₂ O₄ where x is greater than 0 and less than about 2; and

calcining the lithium/manganese complex from about 500°

to about 900°

C. for a time effective to provide the lithiated manganese compound having the formula Li_x Mn₂ O₄ where x is greater than 0 and less than about 2.

14. A method as recited in claim 13 wherein lithium compound is lithium hydroxide.

15. A method as recited in claims 13 or 14 wherein the pH of the aqueous slurry of the washed initially calcined lithium/manganese complex is adjusted to a ranged of from about 6.0 to about 6.5.

16. A method as recited in claim 15 where x is about 1.

17. A method as recited in claim 13 wherein x is about 1.

18. A method as recited in claim 14 wherein x is about 1.

19. A method as recited in claim 13 wherein the alkali metal permanganate is reduced with an organic reducing compound which includes side chains having from about 1 to about four carbon atoms.

20. A method as recited in claim 13 wherein the alkali metal permanganate is reduced with an organic reducing compound which has the general formula ##STR2## where at least one of x and y are methyl, ethyl, propyl and butyl, but one x or y may be H.

21. A method as recited in claim 14 wherein the alkali metal permanganate is reduced with an organic reducing compound which includes side chains having from about 1 to about four carbon atoms.

22. A method as recited in claim 15 wherein the alkali metal permanganate is reduced with an organic reducing compound which has the general formula ##STR3## where at least one of x and y are methyl, ethyl, propyl and butyl, but one x or y may be H.

23. A method as recited in claims 13 or 17 wherein the aqueous slurry which has its pH adjusted to less than about 7 comprises about one part washed initially calcined lithium/manganese complex and about three parts water.

24. A method for making lithiated manganese oxide, the method comprising:

reducing an alkali metal permanganate selected from the group consisting of potassium permanganate and sodium permanganate with an organic reducing compound which includes side chains having from about 1 to about four carbon atoms under alkaline conditions to provide a permanganate reduced manganese dioxide;

blending the permanganate reduced manganese dioxide with a lithium compound to provide a lithium/manganese dioxide blend, the lithium compound being in molar excess of from about 1.6 to about 3.0 moles of lithiated compound per mole of manganese dioxide;

calcining the lithium/manganese dioxide blend at time and temperature such that not more than about 10 weight percent of Li₂ MnO₄ is formed, but sodium or potassium in the blend is converted into M₂ MnO₄ or M₂ MnO₄ wherein M is Na or K to provide an initially calcined lithium/manganese complex;

washing the initially calcined lithium/manganese complex with aqueous lithium hydroxide to provide a washed initially calcined lithium/manganese complex, the washing being effective to provide the washed initially calcined lithium/manganese complex which when slurried with water at a ratio of about 1 part complex to about 3 parts water will result in a slurry with a pH in the range of from about 11 to about 13;

slurrying the washed initially calcined lithium/manganese complex with water to provide an aqueous slurry and adding acid to the aqueous slurry in an amount effective to provide a pH of less than about 7 and effective to provide a lithium/manganese complex which when calcined will provide a lithiated manganese compound having the formula Li_x Mn₂ O₄ where x is greater than 0 and less than about 2; and

calcining the lithium/manganese complex for a time and temperature effective to provide the lithiated manganese compound having the formula Li_x Mn₂ O₄ where x is greater than 0 and less than about 2, the time and temperature also effective to provide the lithiated manganese compound with an electromotive force of from about 3 to about 4 volts when it is used as a cathodic material.

25. A method as recited in claim 24 wherein the lithium/manganese dioxide blend is calcined at from about 150°

to about 550°

C. for about 2 to about 72 hours and the lithium/manganese complex from about 500°

to about 900°

C.

26. A method as recited in claims 24 or 25 wherein a molar ratio of about two manganese atoms to about one lithium atom is provided under conditions of a pH of less than about 7.

27. A method as recited in claims 24 or 25 wherein the alkali metal permanganate is reduced with an organic reducing compound which has the general formula ##STR4## where at least one of x and y are methyl, ethyl, propyl and butyl, but one x or y may be H.

28. A method as recited in claim 24 wherein the aqueous slurry which has its pH adjusted to less than about 7 comprises about one part washed initially calcined lithium/manganese complex and about three parts water.