PEM fuel cell monitoring system

• US 5,763,113 A
• Filed: 08/26/1996
• Issued: 06/09/1998
• Est. Priority Date: 08/26/1996
• Status: Expired due to Term

• Current Assignee: GM Global Technology Operations LLC (General Motors Company)
• Original Assignee: General Motors Corporation (Motors Liquidation Co. GUC Trust)
• Inventors: Grot, Stephen Andreas, Meltser, Mark Alexander
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US08/702,895
• Time in Patent Office: 652 Days
• Field of Search: 429/12, 429/13, 429/22, 429/23, 429/30, 429/33, 204/431
• US Class Current: 429/432
• CPC Class Codes: H01M 2008/1095 Fuel cells with polymeric electrolytes
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 8/0447 of cathode exhausts
• CPC Class Codes: H01M 8/04552 of the individual fuel cell
• CPC Class Codes: H01M 8/04559 of fuel cell stacks
• CPC Class Codes: H01M 8/04671 of the individual fuel cell
• CPC Class Codes: H01M 8/04753 of fuel cell reactants
• CPC Class Codes: H01M 8/04992 characterised by the implementation of mathematical or computational algorithms, e.g. feedback control loops, fuzzy logic, neural networks or artificial intelligence
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

Method and apparatus for monitoring the performance of H₂ --O₂ PEM fuel cells. Outputs from a cell/stack voltage monitor and a cathode exhaust gas H₂ sensor are corrected for stack operating conditions, and then compared to predetermined levels of acceptability. If certain unacceptable conditions coexist, an operator is alerted and/or corrective measures are automatically undertaken.

Claims

1. A method for monitoring the performance of a stack of H₂ --O₂ PEM fuel cells and alerting the stack'"'"'s operator and/or triggering corrective action when said performance degrades to an unacceptable level, said stack having an exhaust gas manifold communicating with, and receiving a cathode exhaust gas from, each of said cells, comprising the steps of:

1. determining the flow rate of said exhaust gas in said manifold;

2. measuring the concentration of hydrogen in said exhaust gas;

3. correcting the hydrogen concentration measured in step 2 to make allowances for hydrogen concentrations in said exhaust gas attributable to variations in said flow rate;

2. from the corrected hydrogen concentration determined in step 3, determining the rate of change in hydrogen concentration in said exhaust gas with respect to time (i.e. dH₂ /dt);

5. comparing the dH₂ /dt determined in step 4 to a first predetermined value which is the maximum acceptable rate of hydrogen increase in said exhaust gas;

6. outputting a first signal from step 5 when dH₂ /dt is equal to or exceeds said first predetermined value;

7. comparing the corrected hydrogen concentration from step 3 to a second predetermined value which is the maximum acceptable total hydrogen content in said exhaust gas;

8. outputting a second signal from step 7 when the corrected hydrogen concentration from step 3 is equal to or exceeds said second predetermined value;

9. measuring the total voltage (V_s) across said stack;

10. determining the rate of any decrease in stack voltage with respect to time (dV_s /dt);

11. reading the power demand on the stack;

12. correcting the rate of stack voltage decrease (dV_s /dt) determined in step 10 to make allowances for stack voltage changes attributable to said power demand;

3. comparing the rate of corrected stack voltage decrease from step 12 to a third predetermined value which is the maximum acceptable rate of decrease in corrected stack voltage;

14. outputting a third signal from step 13 when the corrected stack voltage decrease is equal to or greater than said third predetermined value; and

15. automatically initiating corrective measures to reduce the hydrogen concentration in said exhaust manifold when the conditions producing said first, second and third signals coexist.

4. A method for monitoring the performance of a stack of H₂ --O₂ PEM fuel cells and alerting the stack'"'"'s operator and/or triggering corrective action when said performance degrades to an unacceptable level, said stack having an exhaust gas manifold communicating with, and receiving cathode exhaust gas from, each of said cells, comprising the steps of:

1. determining the flow rate of said exhaust gas in said manifold;

2. measuring the concentration of hydrogen in said exhaust gas;

3. correcting the hydrogen concentration measured in step 2 to make allowances for hydrogen concentrations in said exhaust gas attributable to variations in said flow rate;

4. from the corrected hydrogen concentration determined in step 3, determining the rate of change in hydrogen concentration in said exhaust gas with respect to time (i.e. dH₂ /dt);

5. comparing the dH₂ /dt determined in step 4 to a first predetermined value which is the maximum acceptable rate of hydrogen increase in said exhaust gas;

6. outputting a first signal from step 5 when dH₂ /dt is equal to or exceeds said first predetermined value;

7. comparing the corrected hydrogen concentration from step 3 to a second predetermined value which is the maximum acceptable total hydrogen content in said exhaust gas;

8. outputting a second signal from step 7 when the corrected hydrogen concentration from step 3 is equal to or exceeds said second predetermined value;

9. measuring the total voltage (V_s) across said stack;

10. determining the rate of any decrease in stack voltage with respect to time (dV_s /dt);

11. reading the power demand on the stack;

12. correcting the rate of stack voltage decrease (dV_s /dt) determined in step 10 to make allowances for stack voltage changes attributable to said power demand;

13. comparing the corrected rate of stack voltage decrease from step 12 to a third predetermined value which is the maximum acceptable decrease in corrected stack voltage;

6. outputting a third signal from step 13 when the corrected stack voltage decrease is equal to or greater than said third predetermined value;

15. comparing the corrected hydrogen concentration from step 3 to a fourth predetermined value which is the maximum acceptable hydrogen concentration in said exhaust gas attributable to seepage of hydrogen gas through said membrane;

16. outputting a fourth signal from step 15 when the corrected hydrogen concentration exceeds said fourth predetermined value;

17. outputting a fifth signal from step 7 when the corrected hydrogen concentration from step 3 is less than said second predetermined value;

18. measuring a first individual voltage, V₁, of a first of said PEM fuel cells in said stack;

19. memorizing said first individual voltage, V₁ ;

20. measuring a second individual voltage, V₂, of a second of said PEM fuel cells in said stack;

21. determining any difference Δ

V between said first individual voltage V₁ and said second individual voltage V₂ ;

22. comparing said difference Δ

V from step 21 to a fifth predetermined value which is the maximum acceptable voltage difference between any two individual cells in said stack;

7. repeating steps 18-22 for each individual cell in the stack;

24. outputting a sixth signal from step 23 when the voltage difference Δ

V between any two cells in said stack is less than or equal to said fifth predetermined value;

25. outputting a seventh signal from step 23 when said voltage difference Δ

V is greater than said fifth predetermined value;

26. automatically initiating an alert that undesirable hydrogen leakage into the exhaust gas is evident when the conditions producing the fourth, fifth and seventh signals coexist;

27. automatically initiating an alert that stack performance is degrading when the conditions producing the third, fifth and sixth signals coexist; and

28. automatically initiating corrective measures to reduce the hydrogen concentration in said exhaust manifold when the conditions producing said first, second and third signals coexist.