Method of preparing an alkaline earth metal tallate

• US 5,763,373 A
• Filed: 06/20/1996
• Issued: 06/09/1998
• Est. Priority Date: 06/20/1996
• Status: Expired due to Fees

• Current Assignee: High Point Chemical Corp.
• Original Assignee: High Point Chemical Corp.
• Inventors: Robinson, Peter M., Brooks, Robert E., Singleton, Terry E.
• Primary Examiner(s): MEDLEY, MARGARET B
• Application Number:
  US08/666,902
• Time in Patent Office: 719 Days
• Field of Search: 508/449, 162/5
• US Class Current: 508/449
• CPC Class Codes: C07C 51/412 by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
• CPC Class Codes: C07C 57/12 Straight chain carboxylic acids containing eighteen carbon atoms

Abstract

A stable, fluid alkaline earth metal tallate dispersion is prepared by (i) forming a pre-emulsion of fatty acids derived from tall oil, water, and a surfactant; (ii) forming an alkaline earth metal salt dispersion from an alkaline earth metal oxide and/or hydroxide, a lower carboxylic acid, and water; and (iii) incorporating the pre-emulsion into the alkaline earth metal salt dispersion under high shear and low pressure.

Claims

1. A double displacement method for preparing an alkaline earth metal tallate dispersion of enhanced stability comprising the steps of (i) forming a pre-emulsion of tall oil fatty acids, water, and surfactant having the formula:

space="preserve" listing-type="equation">RO (AO).sub.n -R.sup.o !.sub.m

wherein R is selected from the group consisting of (a) linear and branched alkyl and alkenyl groups having about 8 to about 22 carbon atoms;

(b) R¹ CO-- wherein R¹ is a linear or branched alkyl or alkenyl group having about 7 to about 24 carbon atoms;

(c) (R²)_a C₆ H.sub.(5-a) -- wherein R² is a linear or branched alkyl and alkenyl group having about 7 to 24 carbon atoms and "a" is 0 or 1;

(d) a group derived from a linear, branched, and cyclic aliphatic polyol having from about 2 to 14 carbon atoms; and

(e) a group derived from a linear, branched, and cyclic aliphatic diacid having about 8 to 20 carbon atoms;

AO is an oxyalkylene group having 2 to about 4 carbon atoms or a mixture of such groups in random or block configuration;

R^o is selected from the group consisting of H, R¹ and R¹ CO;

n is a number from about 5 to about 150; and

m is an integer from about 1 to 6;

(ii) separately forming an alkaline earth metal salt dispersion from an organic acid having a pKa of from about 2 to about 6, an alkaline earth metal compound selected from the group consisting of oxides, hydroxides, and mixtures thereof, and water, the alkaline earth metal compound present in an amount at least about 25% above the stoichiometric amount required to neutralize the acid; and

(iii) incorporating the pre-emulsion into the alkaline earth metal salt dispersion under conditions of high shear and low pressure.

2. The method of claim 1, wherein the tall oil fatty acids are partially de-rosinated tall oil.

3. The method of claim 1, wherein the alkaline earth metal compound is calcium oxide.

4. The method of claim 1, wherein the alkaline earth metal compound is calcium hydroxide.

5. The method of claim 1, wherein the tall oil fatty acids are present in an amount of about 15 to about 45 wt % based upon the total weight of the alkaline earth metal tallate dispersion.

6. The method of claim 1, wherein the pre-emulsion further contains rosin acids naturally present in tall oil in an amount ranging from about 1 to about 15% by weight, based upon the weight of the tall oil fatty acids.

7. The method of claim 1, wherein the pre-emulsion further contains at least one component selected from the group consisting of stearic acid, monomer acid, and dimer acid.

8. The method of claim 1, wherein the surfactant is present in the pre-emulsion in an amount of about 1 to 10 wt % based on the weight of the pre-emulsion.

9. The method of claim 8, wherein the surfactant is a mixture of alkoxylated alcohols.

10. The method of claim 1, wherein the pre-emulsion has sufficient stability to be stored for 30 days at a temperature of about 10°

to about 30°

C. before incorporation into the salt dispersion.

11. The method of claim 1, wherein the organic acid contains from 1 to about 12 carbon atoms.

12. The method of claim 1, wherein the organic acid is selected from the group consisting of formic, acetic, propionic, butyric, valeric, hexanoic, heptanoic, octanoic, nonanoic, decanoic, undecanoic, dodecanoic, hydroacetic, malonic, phenylacetic, vinylacetic, chloroacetic, 2-chloropropionic, 3-chloropropionic, and 4-chlorobutyric acids.

13. The method of claim 12, wherein the organic acid is acetic acid.

14. The method of claim 1, wherein the organic acid is added to form the salt dispersion in an amount of about 0.5 to about 1.0 wt %, based on the weight of the salt dispersion.

15. The method of claim 1, wherein the alkaline earth metal compound is present in an amount of at least 1000% more than the stoichiometric amount required to neutralize the acid.

16. The method of claim 1, wherein the incorporating occurs at a temperature from about 20°

to about 50°

C.

17. The method of claim 1, wherein the incorporating occurs in a Silverson in-line high shear low pressure mixer.

18. The method of claim 1, wherein the alkaline earth metal tallate dispersion has a bimodal particle size distribution of alkaline earth metal tallate particles in water.

19. The method of claim 18, wherein the bimodal particle size distribution exhibits a first maxima at about 10 to 30 microns and a second maxima at about 100 to 150 microns.

20. The method of claim 1, wherein the alkaline earth metal tallate dispersion exhibits a viscosity of less than about 500 cps after 120 days storage at a maximum temperature of 30°

C.

21. The method of claim 1, comprising the further step of adding a post-formation stabilizer to the dispersion.

22. The method of claim 21, wherein the post-formation stabilizer is a surfactant which is the same as or different from the surfactant used to form the pre-emulsion, and is selected from the group -consisting of anionic, cationic, and nonionic surfactants.

23. The method of claim 22, wherein the post-formation stabilizing surfactant is selected from the group consisting of dicarboxylic acid, sulfonate, and ether carboxylate anionic surfactants;

quaternary ammonium cationic surfactants; and

ethylene oxide;

propylene oxide block and random polymeric non-ionic surfactants.

24. The method of claim 21, wherein the post-formation stabilizer is added in an amount of about 0.5 to 2.5 wt % of the tallate dispersion.

25. The method of claim 21, wherein the alkaline earth metal tallate dispersion exhibits a viscosity of less than about 500 cps after 60 days storage at a maximum temperature of about 50°

C.