Lubricating oil compositions of reduced high-temperature high-shear viscosity

• US 5,763,374 A
• Filed: 08/10/1995
• Issued: 06/09/1998
• Est. Priority Date: 08/10/1994
• Status: Expired due to Term

• Current Assignee: Sanyo Chemical Industries Limited
• Original Assignee: Sanyo Chemical Industries Limited
• Inventors: Ohta, Yoshihisa, Sakai, Kouzou, Matsuya, Hidehiko
• Primary Examiner(s): Johnson, Jerry D.
• Application Number:
  US08/513,562
• Time in Patent Office: 1,034 Days
• Field of Search: 508/469
• US Class Current: 508/469
• CPC Class Codes: C10M 145/14 Acrylate; Methacrylate
• CPC Class Codes: C10M 169/04 Mixtures of base-materials and additives
• CPC Class Codes: C10M 2203/1025 used as base material
• CPC Class Codes: C10M 2209/084 Acrylate; Methacrylate
• CPC Class Codes: C10M 2219/068 Thiocarbamate metal salts
• CPC Class Codes: C10M 2223/045 Metal containing thio derivatives
• CPC Class Codes: C10N 2010/12 Groups 6 or 16
• CPC Class Codes: C10N 2020/02 Viscosity; Viscosity index
• CPC Class Codes: C10N 2020/04 Molecular weight; Molecular weight distribution
• CPC Class Codes: C10N 2030/08 Resistance to extreme temperature
• CPC Class Codes: C10N 2030/68 Shear stability
• CPC Class Codes: C10N 2040/04 Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
• CPC Class Codes: C10N 2040/042 for automatic transmissions
• CPC Class Codes: C10N 2040/044 for manual transmissions
• CPC Class Codes: C10N 2040/046 for traction drives
• CPC Class Codes: C10N 2040/08 Hydraulic fluids, e.g. brake-fluids
• CPC Class Codes: C10N 2040/25 Internal-combustion engines
• CPC Class Codes: C10N 2040/252 Diesel engines
• CPC Class Codes: C10N 2040/255 Gasoline engines
• CPC Class Codes: C10N 2040/30 Refrigerators lubricants or compressors lubricants
• CPC Class Codes: C10N 2070/02 : Concentrating of additives

Abstract

A viscosity index improver, comprising an oil-soluble copolymer (A) having 20-70% by weight of alkyl acrylate units and 30-80% by weight of alkyl methacrylate units, and a viscosity index improver, comprising 20-80% by weight of an oil-soluble alkyl acrylate (co)polymer (A1) and 20-80% by weight of an oil-soluble methacrylate (co)polymer (A2), are capable of reducing high-temperature high-shear viscosity, particularly isoparaffin-containing high viscosity index oil, and provide luburicating oils useful as engine oil, gear lubricant and so on.

Claims

1. A lubricating oil composition, which comprises:

a minor portion, as a viscosity index improver, of an oil-soluble copolymer (A) having 20-70% by weight of at least one alkyl acrylate unit (a1) containing 5-22 carbon atoms in the alkyl group and 30-80% by weight of at least one alkyl methacrylate unit (a2) containing 1-22 carbon atoms in the alkyl group, and a major portion of an isoparaffin-containing high viscosity index oil (B) having a viscosity index of at least 110.

2. The composition of claim 1, wherein said unit (a2) comprises an alkyl methacrylate unit containing at least 10 carbon atoms in the alkyl group.

3. The composition of claim 1, wherein said unit (a2) comprises an alkyl methacrylate unit (a2-1) containing 10-18 carbon atoms in the alkyl group.

4. The composition of claim 1, wherein said unit (a2) comprises an alkyl methacrylate unit (a2-1) containing 10-18 carbon atoms in the alkyl group and an alkyl methacrylate unit (a2-2) containing 1-4 carbon atoms in the alkyl group.

5. The composition of claim 4, wherein said unit (a2) comprises 60-95% by weight of said unit (a2-1) and 5-40% by weight of said unit (a2-2).

6. The composition of claim 1, wherein said oil (B) has a viscosity index of 120-160.

7. The composition of claim 1, wherein said oil (B) is selected from the group consisting of isoparaffin-containing isomerized mineral oils formed by hydrogenolysis of n-paraffins, and isoparaffin-containing oils formed by hydrogenation and ring-opening reaction of polycyclic aromatics or naphthenes.

8. The composition of claim 1, which comprises 0.3-30% by weight of said copolymer (A).

9. The composition of claim 1, which further comprises a molybdenum-containing antiwear agent (C) in an amount of 0.05-5% by weight.

10. The composition of claim 1, which further comprises a pour point depressant (D) in an amount of up to 30% by weight based on the total weight of said (A) and said (D).

11. A method for improving low temperature flow characteristics and oxidative stability at high temperature in a automobile assembly, which comprises operating the automobile assembly with an engine oil, gear lubricant or brake fluid, containing the composition of claim 1.

12. The composition of claim 1, wherein at least a portion of the monomer units which comprise alkyacrylate unit (a1) is an alkylacrylate monomer in which the alkyl group has not more than 10 carbon atoms.

13. A lubricating oil composition, which comprises:

a minor portion, as a viscosity index improver, of an oil-soluble copolymer (A) comprising 20-70% by weight of alkylacrylate unit (a1) whose alkyl group has 1-22 carbon atoms comprising an alkylacrylate monomer (a1-1) whose alkyl group has 5-10 carbon atoms and an alkylacrylate monomer (a1-2) whose alkyl group has 1-4 carbon atoms and 30-80% by weight of at least one alkylmethacrylate unit (a2) containing 1-22 carbon atoms in the alkyl group, and a major portion of an isoparaffin-containing high viscosity index oil (B) having a viscosity index of at least 110.

14. The composition of claim 13, wherein said unit (a1) comprises 60-90% by weight of said unit (a1-1) and 10-40% by weight of said unit (a1-2).

15. A lubricating oil composition, which comprises:

a minor portion, as a viscosity index improver, of an oil-soluble copolymer (A) having 20-70% by weight of at least one alkyl acrylate unit (a1) containing 5-10 carbon atoms in the alkyl group and 30-80% by weight of at least one alkyl methacrylate unit (a2) containing 1-22 carbon atoms in the alkyl group, and a major portion of an isoparaffin containing high viscosity index oil (B) having a viscosity index of at least 110.

16. A lubricating oil composition, which comprises:

a minor portion, as a viscosity index improver, of an oil-soluble copolymer (A) having 20-70% by weight of at least one alkylacrylate unit (a1) containing 1-22 carbon atoms in the alkyl group and 30-80% by weight of at least alkylmethacrylate unit (a2) containing 1-22 carbon atoms in the alkyl group, and a major portion of an isoparaffin-containing high viscosity index oil (B) having a viscosity index of at least 110;

wherein said unit (a1) comprises at least 60% by weight of the alkylacrylate unit (a1-1) containing 5-10 carbon atoms in the alkyl group.