Autoignition propellant containing superfine iron oxide

• US 5,763,821 A
• Filed: 10/30/1996
• Issued: 06/09/1998
• Est. Priority Date: 05/17/1996
• Status: Expired due to Term

• Current Assignee: Arc Automotive Incorporated (The Jordan Co. LP)
• Original Assignee: Atlantic Research Corporation (L3Harris Technologies, Inc.)
• Inventors: Wheatley, Brian K.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US08/740,531
• Time in Patent Office: 587 Days
• Field of Search: 149/19.5, 149/83, 149/86, 280/741
• US Class Current: 149/19.5
• CPC Class Codes: B60R 2021/26064 characterised by auto-ignition means
• CPC Class Codes: C06B 29/06 the component being a cyanide; the component being an oxide of iron, chromium or manganese
• CPC Class Codes: C06B 33/00 Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
• CPC Class Codes: C06C 9/00 Chemical contact igniters; Chemical lighters
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

An autoignition propellant (AIP) is disclosed for use in conjunction with gas generative compositions for air bags to reduce the autoignition temperature of said propellant without adversely affecting the AIP'"'"'s storage thermal stability. Said AIP consists essentially of A) a mixture of a) about 60 to 80% by weight KClO₃, b) about 15 to about 30% by weight lactose and c) about 1 to about 10% by weight of an aliphatic polycarbonate and B) an autoignition lowering effective amount of superfine iron in an amount up to 10% by weight based upon the combined weight of A) and B). A method of using the AIP to lower autoignition temperatures and an air bag inflator containing the AIP are also disclosed.

Claims

1. An autoignition propellant (AIP) for use with a gas generative composition for inflating an inflatable device, the AIP exhibiting a lower autoignition temperature while retaining its effectiveness after a 17-day storage at 107°

C., said autoignition propellant consisting essentially of

A) a mixture containing the following components;

a) about 60 to about 80% by weight KClO₃ ;

b) about 15 to about 30% by weight lactose; and

c) about 1 to about 10% by weight of an aliphatic polycarbonate; and

B) superfine iron oxide in an autoignition temperature lowering effective amount up to about 10% by weight based upon the combined weight of A) and B).

2. The autoignition propellant according to claim 1 wherein B) the superfine iron oxide is present in an autoignition lowering effective amount of about 1% by weight based upon the combined weight of A) and B).

3. The autoignition propellant according to claim 1 wherein the autoignition temperature is reduced from approximately 195°

C. without said B) superfine iron oxide to about 160°

C. with said B) superfine iron oxide.

4. The autoignition propellant according to claim 1 wherein the components of

A) are present in the following amounts:

a) about 70% by weight KClO₃ ;

b) about 25% by weight lactose; and

c) about 5% by weight of an aliphatic polycarbonate;

with

B) superfine iron oxide in an autoignition temperature lowering effective amount up to about 10% by weight based upon the combined weight of A) and B).

5. The autoignition propellant according to claim 4, wherein B) the superfine iron oxide is present in an autoignition temperature lowering effective amount of about 1% by weight based upon the combined weight of A) and B).

6. The autoignition propellant according to claim 1 in which the AIP is in the form of a pressed charge having a weight up to about 0.3 g.

7. In an inflator for an inflatable device, which inflator includes an ignition composition, the improvement wherein as said ignition composition, there is provided

A) a mixture containing the following components:

a) about 60 to about 80% by weight KClO₃ ;

b) about 15 to about 30% by weight lactose; and

c) about 1 to about 10% by weight of an aliphatic polycarbonate;

in combination with

B) superfine iron oxide in an autoignition temperature lowering effective amount up to about 10% by weight based upon the combined weight of A) and B).

8. The inflator according to claim 7, wherein the inflator includes a supply of pressurized gas.

9. The inflator according to claim 7, wherein inflation gases are provided solely by a gas-generative composition.

10. The inflator according to claim 7, wherein said inflation device comprises an automotive air bag.

11. The inflator according to claim 7, wherein said ignition composition is in the form of a pressed charge having a weight up to 0.3 g.