Spectroscopic sample holder

• US 5,764,355 A
• Filed: 01/12/1996
• Issued: 06/09/1998
• Est. Priority Date: 01/12/1996
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Aysta, James E., Pieper, Richard M., Gagnon, David R.
• Primary Examiner(s): Pham, Hoa Q.
• Application Number:
  US08/587,316
• Time in Patent Office: 879 Days
• Field of Search: 356/244, 356/440, 356/319, 356/326, 356/246, 250/339.07, 250/343, 250/576, 436/164, 436/172, 422/99, 422/102, 422/104, 422/57, 435/805
• US Class Current: 356/244
• CPC Class Codes: G01N 21/01 Arrangements or apparatus for facilitating the optical investigation

Abstract

A device for holding a sample to be spectroscopically analyzed in which the sample is retained within a defined area. The device includes a receiving medium on which the sample is held. When this receiving medium is mounted in a frame (an optional feature), it extends across an aperture in the frame. In/on the receiving medium is a sample confining region that keeps any sample placed on the receiving medium from migrating outside a defined area. By keeping the sample within a defined area, quantitative measurements of the sample can be obtained.

Claims

1. A device for holding a sample to be spectroscopically analyzed, said device comprising:

a porous medium for receiving said sample,

said porous medium comprising a nonporous region for confining said sample within a predetermined portion of said porous medium, said nonporous region defining said predetermined portion.

2. The device of claim 1 wherein said porous medium is a screen comprising a plurality of unobstructed openings, the cross-sectional area of each of said openings being such that said sample is retained on said screen by the surface tension of said sample.

3. The device of claim 1 wherein said porous medium is a microporous sheet.

4. The device of claim 3 wherein said microporous sheet has a void volume of at least 20%.

5. The device of claim 3 wherein said microporous sheet comprises a polymer.

6. The device of claim 5 wherein said polymer is polyethylene, polypropylene, copoly(ethylene-propylene), polytetrafluoroethylene, poly(vinyl chloride), polycarbonate, poly(vinylidene fluoride), cellulose acetate, cellulose nitrate, poly(chlorotrifluoroethylene), polyester, or nylon.

7. The device of claim 3 wherein said nonporous region is an embossed compression in said microporous sheet.

8. The device of claim 1 wherein the area of said predetermined portion is between about 1 and about 6 cm².

9. The device of claim 1 wherein said porous medium comprises two or more of said predetermined portions.

10. The device of claim 1 further comprising a frame, said frame comprising an upper surface, a lower surface, and at least one aperture extending from said upper surface through said lower surface, said porous medium being held within said frame and extending across said aperture.

11. The device of claim 10 wherein said frame holds said porous medium substantially flat across said aperture.

12. The device of claim 10 wherein said porous medium is a screen comprising a plurality of unobstructed openings, the cross-sectional area of each of said openings being such that said sample is retained on said screen by the surface tension of said sample.

13. The device of claim 10 wherein said porous medium is a microporous sheet.

14. The device of claim 13 wherein said microporous sheet has a void volume of at least 20%.

15. The device of claim 13 wherein said microporous sheet comprises a polymer.

16. The device of claim 15 wherein said polymer is polyethylene, polypropylene, copoly(ethylene-propylene), polytetrafluoroethylene, poly(vinyl chloride), polycarbonate, poly(vinylidene fluoride), cellulose acetate, cellulose nitrate, poly(chlorotrifluoroethylene), polyester, or nylon.

17. The device of claim 13 wherein said nonporous region is an embossed compression in said microporous sheet.

18. The device of claim 10 wherein the area of said predetermined portion is between about 1 and about 6 cm².

19. The device of claim 10 comprising two or more apertures, each aperture having a porous medium for receiving a sample extending thereacross.

20. A method of spectroscopically analyzing a sample comprising the steps:

a) transmitting infrared radiation through a sample that has been applied to the predetermined portion of a device for holding a sample to be spectroscopically analyzed, said device comprising

a porous medium for receiving said sample, and

a nonporous region for confining said sample within a predetermined portion of said porous medium, said nonporous region defining said predetermined portion; and

b) analyzing the radiation transmitted through said sample and said porous medium.

21. The method of claim 20 further comprising the step of determining the baseline transmittance of said device prior to applying said sample thereto.

22. The method of claim 20 wherein said sample is applied to said device by filtering a stream containing said sample through said predetermined portion of said porous medium.

23. The method of claim 20 wherein said porous medium is a microporous sheet.

24. A method of spectroscopically analyzing a sample comprising the steps:

a) transmitting infrared radiation through a sample that has been applied to the predetermined portion of a device for holding a sample to be spectroscopically analyzed, said device comprising

a porous medium for receiving said sample, and

a nonporous region for confining said sample within a predetermined portion of said porous medium, said nonporous region defining said predetermined portion, and

a frame comprising an upper surface, a lower surface, and at least one aperture extending from said upper surface through said lower surface,

said porous medium being held within said frame and extending across said aperture; and

b) analyzing the radiation transmitted through said sample and said porous medium.

25. The method of claim 24 further comprising the step of determining the baseline transmittance of said device prior to applying said sample thereto.

26. The method of claim 24 wherein said sample is applied to said device by filtering a stream containing said sample through said predetermined portion of said porous medium.

27. The method of claim 24 wherein said porous medium is a microporous sheet.