Process for producing cement from a flue gas desulfurization process waste product

• US 5,766,339 A
• Filed: 05/07/1997
• Issued: 06/16/1998
• Est. Priority Date: 05/07/1997
• Status: Expired due to Fees

• Current Assignee: Dravo Lime, Inc.
• Original Assignee: Dravo Lime, Inc.
• Inventors: Forsythe, Russell C., College, John W., Babu, Manyam
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US08/852,798
• Time in Patent Office: 405 Days
• Field of Search: 106/745, 106/752, 106/757, 106/761, 106/763, 106/765, 106/769, 423/522, 423/530, 423/541.1
• US Class Current: 106/745
• CPC Class Codes: C01B 17/0491 with hydrogen or hydrogen-containing mixtures, e.g. synthesis gas
• CPC Class Codes: C01B 17/506 of calcium sulfates
• CPC Class Codes: C04B 7/04 using raw materials containing gypsum , i.e. processes of the Mueller-Kuehne type
• CPC Class Codes: C04B 7/24 Cements from oil shales, residues or waste other than slag
• CPC Class Codes: Y02P 20/129 Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
• CPC Class Codes: Y02P 40/10 Production of cement, e.g. improving or optimising the production methods; Cement grinding

Abstract

Cement is produced by forming a moist mixture of a flue gas desulfurization process waste product containing 80-95 percent by weight calcium sulfite hemihydrate and 5-20 percent by weight calcium sulfate hemihydrate, aluminum, iron, silica and carbon, agglomerating the moist mixture while drying the same to form a feedstock, and calcining the dry agglomerated feedstock in a rotary kiln. Sulfur dioxide released from the calcium sulfite hemihydrate and calcium sulfate hemihydrate during calcination may be used to produce sulfuric acid, while heat recovered in the process is used to dry the agglomerating feedstock.

Claims

1. A process for producing cement from a flue gas desulfurization process waste product, comprising:

providing a moist flue gas desulfurization process waste product containing 80-95 percent by weight of solids of calcium sulfite hemihydrate and 5-20 percent by weight of solids of calcium sulfate hemihydrate;

adding a source of aluminum, iron, carbon, and a siliceous material to said flue gas desulfurization process waste product to form a moist mixture thereof;

agglomerating said moist mixture while removing water therefrom, by contact with hot air, to provide a dry agglomerated kiln feedstock containing about 6 percent or less water;

calcining said dry agglomerated kiln feedstock in a rotary kiln to produce a cement clinker; and

pulverizing said cement clinker to produce cement.

2. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 1 wherein said source of aluminum and iron comprises fly ash.

3. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 1 wherein said waste product results from a flue gas desulfurization process using a magnesium-enhanced lime slurry for reaction with sulfur dioxide in a gas stream.

4. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 1 wherein said waste product results from a flue gas desulfurization process using lime for reaction with sulfur dioxide in a gas stream.

5. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 1 wherein said waste product results from a flue gas desulfurization process using limestone for reaction with sulfur dioxide in a gas stream.

6. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 1 wherein said moist mixture contains between about 5 to 20 weight percent of water.

7. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 1 wherein said dry agglomerated kiln feedstock has a solid content comprising, by weight, 82.77 percent flue gas desulfurization process waste product, 5.80 percent fly ash, 6.43 percent sand, and 5.0 percent coke.

8. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 1 wherein sulfur dioxide is produced from calcining of said agglomerated kiln feedstock in said rotary kiln and said sulfur dioxide is discharged from said rotary kiln to an indirect heat exchanger to heat air and air heated in said heat exchanger is used to remove water from said moist mixture during agglomeration.

9. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 8 wherein said sulfur dioxide, after heating air in said heat exchanger is passed to a sulfuric acid producing plant and used for production of sulfuric acid.

10. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 9 wherein hot gases produced in said sulfuric acid producing plant are used to preheat air and said preheated air is used to remove water from said moist mixture during agglomeration.

11. A process for producing cement from a flue gas desulfurization process waste product, comprising:

providing a moist flue gas desulfurization process waste product containing 80-95 percent by weight of solids of calcium sulfite hemihydrate and 5-20 percent by weight of solids of calcium sulfate hemihydrate;

adding a source of aluminum, iron, carbon, and a siliceous material to said flue gas desulfurization process waste product to form a moist mixture thereof;

agglomerating said moist mixture while removing water therefrom, by contact with hot air, to provide a dry agglomerated kiln feedstock containing about 6 percent or less water;

calcining said dry agglomerated kiln feedstock in a rotary kiln to produce a cement clinker and sulfur dioxide;

removing said cement clinker from the rotary kiln and pulverizing the same to produce cement;

discharging said sulfur dioxide from the rotary kiln;

passing said discharged sulfur dioxide to an indirect heat exchanger to heat air; and

using the heated air so produced to remove water from said moist mixture during said agglomerating.

12. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 11 wherein said sulfur dioxide, after heating air in said heat exchanger is passed to a sulfuric acid producing plant and used for production of sulfuric acid.

13. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 12 wherein hot gases produced in said sulfuric acid producing plant are used to preheat air and said preheated air is used to remove water from said moist mixture during agglomeration.

14. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 11 wherein said source of siliceous material, aluminum and iron comprises fly ash.

15. The process for producing cement from a flue gas desulfurization process waste product as defined in claim 11 wherein said dry agglomerated kiln feedstock has a solid content comprising, by weight 82.77 percent flue gas desulfurization process waste product, 5.80 percent fly ash, 6.43 percent sand, and 5.0 percent coke.

16. A process for producing cement from a flue gas desulfurization process waste product, comprising:

providing a moist flue gas desulfurization process waste product containing 80-95 percent by weight of solids of calcium sulfite hemihydrate and 5-20 percent by weight of solids of calcium sulfate hemihydrate resulting from a flue gas desulfurization process using a magnesium-enhanced lime slurry for reaction with sulfur dioxide in a gas stream;

adding fly ash containing aluminum and iron, carbon, and sand to said flue gas desulfurization process waste product to form a moist mixture thereof;

agglomerating said moist mixture while removing water therefrom, by contact with hot air, to provide a dry agglomerated kiln feedstock containing about 6 percent or less water;

calcining said dry agglomerated kiln feedstock in a rotary kiln to produce a cement clinker and sulfur dioxide;

discharging said sulfur dioxide from the rotary kiln to an indirect heat exchanger and heating air in said heat exchanger therewith;

using said heated air to remove water from said moist mixture during agglomeration; and

pulverizing said cement clinker to produce cement.