Continuous processing of powder coating compositions

• US 5,766,522 A
• Filed: 07/19/1996
• Issued: 06/16/1998
• Est. Priority Date: 07/19/1996
• Status: Expired due to Fees

• Current Assignee: Morton International Incorporated (Autoliv Incorporated)
• Original Assignee: Morton International Incorporated (Autoliv Incorporated)
• Inventors: Decker, Owen H., Daly, Andrew T., Wursthorn, Karl R., Houda, Frank R.
• Primary Examiner(s): THEISEN, MARY LYNN F
• Application Number:
  US08/684,112
• Time in Patent Office: 697 Days
• Field of Search: 264/5, 264/12, 264/13
• US Class Current: 264/13
• CPC Class Codes: B01J 2/006 Coating of the granules without description of the process or the device by which the granules are obtained to prevent the granules sticking together B01J2/30
• CPC Class Codes: B01J 2/20 by expressing the material, e.g. through sieves and fragmenting the extruded length
• CPC Class Codes: B05D 1/025 using gas close to its critical state
• CPC Class Codes: B05D 2401/32 applied as powders
• CPC Class Codes: B05D 2401/90 at least one component of the composition being in supercritical state or close to supercritical state
• CPC Class Codes: B29B 9/06 in the form of filamentary material, e.g. combined with extrusion
• CPC Class Codes: B29C 48/00 Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor extrusion blow-moulding B29C49/04
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/288 in solid form, e.g. powder or granules
• CPC Class Codes: B29C 48/29 in liquid form
• CPC Class Codes: B29K 2027/18 PTFE, i.e. polytetrafluorethene , e.g. ePTFE, i.e. expanded polytetrafluorethene
• CPC Class Codes: B29K 2081/00 Use of polymers having sulfur, with or without nitrogen, oxygen or carbon only, in the main chain, as moulding material
• CPC Class Codes: B29K 2105/0005 containing compounding ingredients releasing, lubricating or separating agents B29C33/56, fibers B29K2105/08, B29K2105/12; fillers B29K2105/16, recycled material B29K2105/26
• CPC Class Codes: C09D 5/03 Powdery paints

Abstract

Systems, apparatus combinations and methods for producing a powder coating are provided wherein a stream of a powder coating precursor including at least one resin and at least one additional powder coating ingredient is contacted with a process fluid effective to reduce the viscosity of the powder coating precursor to allow processing of the powder coating precursor at a lower temperature.

Claims

1. In a method for producing a powder coating, the step of:

contacting a powder coating precursor stream comprising powder coating ingredients including at least one resin and at least one additional powder coating ingredient in a continuous extruder with a process media fluid effective to reduce the viscosity of the powder coating precursor stream to allow continuous extrusion of the powder coating precursor stream at a lower temperature, said process media fluid comprising a process media material in the form of a fluid selected from the group consisting of supercritical fluids and liquified gases.

2. The method of claim 1 wherein said powder coating precursor stream is processed in a continuous extruder at a temperature no greater than the softening temperature of the resin.

3. The method of claim 2 wherein said powder coating precursor stream is processed at a temperature of at least about 10°

-20°

F. below the softening temperature of the resin.

4. The method of claim 2 wherein said powder coating precursor stream is processed at a temperature of at least about 20°

-40°

F. below the softening temperature of the resin.

5. The method of claim 1 wherein said process media fluid comprises a supercritical fluid.

6. The method of claim 1 wherein said process media fluid comprises a liquified gas.

7. The method of claim 1 wherein said process media fluid comprises carbon dioxide.

8. The method of claim 1 wherein said contacting comprises the steps of:

adding the process media material to the powder coating precursor stream in a continuous extruder, and

extruding the powder coating ingredients with the process media material.

9. The method of claim 1 wherein the powder coating precursor stream comprises the extrudate of a continuous extruder.

10. The method of claim 1 wherein the powder coating precursor stream comprises the feed to a continuous extruder.

11. The method of claim 1 comprising:

adding the process media material to the powder coating precursor stream in a continuous extruder,

extruding the powder coating ingredients with the added process media material, and

contacting the extrudate of the continuous extruder with additional process media fluid.

12. The method of claim 1 additionally comprising the step of contacting at least one of the powder coating precursor stream and the powder coating precursor stream subsequent to said contacting with a co-solvent.

13. The method of claim 1 wherein the at least one resin of the powder coating ingredients is a thermoplastic resin.

14. The method of claim 13 wherein the thermoplastic resin is selected from the group consisting of polyphenylsulfones and PTFE.

15. The method of claim 1 wherein the at least one resin of the powder coating ingredients is a thermosettable resin.

16. The method of claim 1 wherein subsequent to said contacting step, the so contacted powder coating precursor stream is spray dried to form powder coating particles.

17. The method of claim 16 wherein the powder coating particles are spherical in shape.

18. The method of claim 17 wherein the spherically shaped powder coating particles range in size from less than 2 to about 40 microns.

19. The method of claim 1 wherein said powder coating precursor stream is processed in a continuous extruder to form a foam mass, said method additionally comprising the step of:

grinding the foam mass to form powder coating particles.

20. In a method for producing a powder coating wherein powder coating raw materials including at least one resin and at least one additional powder coating ingredient are fed to and processed in a continuous extruder to disperse the at least one additional ingredient with the at least one resin to form an extrudate product, the step of:

adding a process media fluid comprising a process media material in the form of a fluid selected from the group consisting of supercritical fluids and liquified gases to a process stream of at least one of the following;

a.) the raw materials fed to the continuous extruder;

b.) the raw materials processed in the continuous extruder; and

c.) the extrudate product of the continuous extruder,

said addition being effective to reduce the viscosity of the selected process stream to allow processing of the process stream at a lower temperature.

21. The method of claim 20 wherein said powder coating precursor stream is processed in the continuous extruder at a temperature no greater than the softening temperature of the resin.

22. The method of claim 21 wherein said powder coating precursor stream is processed in the continuous extruder at a temperature of at least about 10°

-20°

F. below the softening temperature of the resin.

23. The method of claim 21 wherein said powder coating precursor stream is processed in the continuous extruder at a temperature of at least about 20°

-40°

F. below the softening temperature of the resin.

24. The method of claim 20 additionally comprising the step of adding a co-solvent to a process stream comprising at least one of the following:

a.) the raw materials fed to the continuous extruder;

b.) the raw materials processed in the continuous extruder; and

c.) the extrudate product of the continuous extruder.

25. The method of claim 20 wherein said process media fluid comprises carbon dioxide.

32. The method of claim 20 additionally comprising the step of statically mixing the extrudate product of the continuous extruder.

26. A method for producing a powder coating, said method comprising the steps of:

extruding a premixed blend of powder coating raw materials including at least one thermosettable resin and at least one curing agent for the at least one thermosettable resin to form an extrudate product;

feeding a stream of the extrudate product through a melt pump to form a stream of extrudate product at increased pressure; and

spray drying the stream of extrudate product at increased pressure to form the powder coating,

wherein at least one of the blend of powder coating raw materials undergoing extrusion and the stream of extrudate product at increased pressure is contacted with a process media fluid selected from the group consisting of supercritical fluids and liquified gases, the process media being effective to reduce the viscosity of the materials of the selected process stream to allow processing at a lower temperature.

27. The method of claim 26 wherein said powder coating precursor stream is processed in a continuous extruder at a temperature no greater than the softening temperature of the resin.

28. The method of claim 26 wherein said powder coating precursor stream is processed in a continuous extruder at a temperature of at least about 10°

-20°

F. below the softening temperature of the resin.

29. The method of claim 26 wherein said powder coating precursor stream is processed in a continuous extruder at a temperature of at least about 20°

-40°

F. below the softening temperature of the resin.

30. The method of claim 26 wherein said process media fluid comprises carbon dioxide.

31. The method of claim 26 additionally comprising the step of applying an additional quantity of the process media fluid to seals in said melt pump to keep such seals free of the powder coating materials being processed.

33. The method of claim 26 additionally comprising the step of statically mixing the process media fluid with the stream of extruded product at increased pressure.