Panel composed of synthetic resins and coated with an antifogging layer and a method of making the panel

• US 5,766,739 A
• Filed: 07/13/1995
• Issued: 06/16/1998
• Est. Priority Date: 07/13/1995
• Status: Expired due to Fees

• Current Assignee: Nippon Arc Co., Ltd., Nippon Sheet Glass Company Limited, Tsutsunaka Plastic Industry Co., Ltd. (Sumitomo Bakelite Company Limited)
• Original Assignee: Nippin Sheet Glass Co., Ltd., Nippon Arc Co., Ltd., Tsutsunaka Plastic Industry Co., Ltd. (Sumitomo Bakelite Company Limited)
• Inventors: Funaki, Masaaki, Nanri, Hiroyoshi
• Primary Examiner(s): YAMNITZKY, MARIE ROSE
• Application Number:
  US08/502,424
• Time in Patent Office: 1,069 Days
• Field of Search: 428/201, 428/203, 428/204, 428/323, 428/328, 428/447, 428/451, 428/480, 428/522, 252/70, 252/500, 252/511, 252/512, 252/518, 219/203, 52/171.2, 106/13, 523/169, 427/163.1, 427/164, 427/258, 427/372.2, 427/379, 427/380, 427/387, 427/393.5, 427/412.1
• US Class Current: 428/201
• CPC Class Codes: H05B 2203/002 Heaters using a particular layout for the resistive material or resistive elements
• CPC Class Codes: H05B 3/84 Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields
• CPC Class Codes: Y10T 428/24851 Intermediate layer is discontinuous or differential
• CPC Class Codes: Y10T 428/24868 Translucent outer layer
• CPC Class Codes: Y10T 428/24876 Intermediate layer contains particulate material [e.g., pigment, etc.]
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/256 Heavy metal or aluminum or compound thereof
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane
• CPC Class Codes: Y10T 428/31667 Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

A panel is composed of synthetic resins and coated with an antifogging layer, the panel having a plastics substrate formed as a board or film or molded into any desired shape. The panel further has a heat generating pattern as the antifogging layer formed on the substrate and composed of a conductive paste, and a hard coat covering the layer and mainly composed of a silicone resin. The conductive paste is composed of a resinous binder, a conductive agent and a solvent, and the binder is selected from a group consisting of (i) a saturated polyester, (ii) a mixture of the polyester and a polyvinyl chloride, (iii) a mixture of the polyester and a copolymer of vinyl chloride and vinyl acetate, and (iv) a mixture of the polyester, the polyvinyl chloride and the copolymer. The heat generating pattern layer protects the resin panel from fogging, and the hard coat enhances scratch resistance and weather resistance to the panel.

Claims

1. A panel composed of synthetic resins and coated with a layer, the panel comprising:

a plastics substrate formed as a board or a film or molded into any desired shape;

a heat generating pattern layer as the layer coated on the substrate and formed from an electrically conductive paste; and

a coat formed of a silicone-based composition containing a silicone resin which covers the heat generating pattern layer,

where the electrically conductive paste is composed of a resinous binder, a conductive agent and a solvent, with the resinous binder being selected from the group consisting of (i) a mixture of a saturated polyester and a polyvinyl chloride, (ii) a mixture of a saturated polyester and a copolymer of vinyl chloride and vinyl acetate, and (iii) a mixture of a saturated polyester, a polyvinyl chloride and a copolymer of vinyl chloride and vinyl acetate, where the amount of polyvinyl chloride and/or copolymer of vinyl chloride and vinyl acetate in the resinous binder is up to 40% by weight, and with the resinous binder and the conductive agent being 35-75% by weight of the electrically conductive paste.

2. The panel as defined in claim 1, wherein a periphery of the heat generating pattern layer is surrounded by a colored translucent area.

3. The panel as defined in claim 1, wherein the heat generating pattern comprises a pair of electrode portions and a plurality of heat generating lines extending between the electrode portions.

4. The panel as defined in claim 1, 2 or 3, wherein the silicone-based composition for forming the coat comprises an organopolysiloxane that consists essentially of a condensation oligomer of RSi(OH)₃ and an aqueous or alcoholic dispersion of colloidal silica or any colloidal metal oxide, wherein `R` is selected from the group consisting of an alkyl group having one to three carbon atoms, a vinyl group, 3,3,3-trifluoropropyl, γ

-aminopropyl, γ

-methacryloxypropyl and γ

-glycidoxypropyl.

5. A method of making a panel composed of synthetic resins and coated with a heat generating layer, the method comprising the steps of:

preparing a plastics substrate formed as a board or a film or molded into any desired shape;

then applying an electrically conductive paste to the plastics substrate;

next, curing the paste to form thereon the heat generating pattern layer;

subsequently applying to the heat generating pattern layer a silicone-based composition containing a silicone resin; and

finally curing the silicone-base composition to form a coat covering the heat generating pattern layer,

wherein the electrically conductive paste is composed of a resinous binder, a conductive agent and a solvent, with the resinous binder being selected from the group consisting of (i) a mixture of a saturated polyester and a polyvinyl chloride, (ii) a mixture of a saturated polyester and a copolymer of vinyl chloride and vinyl acetate, and (iii) a mixture of a saturated polyester, a polyvinyl chloride and a copolymer of vinyl chloride and vinyl acetate, where the amount of polyvinyl chloride and/or copolymer of vinyl chloride and vinyl acetate in the resinous binder is up to 40% by weight, and with the resinous binder and the conductive agent being 35-75% of the electrically conductive paste.