Fabric softening compositions with dye transfer inhibitors for improved fabric appearance

• US 5,767,062 A
• Filed: 06/12/1997
• Issued: 06/16/1998
• Est. Priority Date: 11/16/1992
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Trinh, Toan, Tordil, Helen Bernardo, Wendland, Paul Arthur, Sung, Stephanie Lin-Lin
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US08/873,487
• Time in Patent Office: 369 Days
• Field of Search: 510/519, 510/520, 510/517, 510/516, 510/518
• US Class Current: 510/516
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 17/041 Compositions releasably affixed on a substrate or incorporated into a dispensing means
• CPC Class Codes: C11D 3/001 Softening compositions
• CPC Class Codes: C11D 3/0015 liquid
• CPC Class Codes: C11D 3/0021 Dye-stain or dye-transfer inhibiting compositions
• CPC Class Codes: C11D 3/222 Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
• CPC Class Codes: C11D 3/3769 (Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
• CPC Class Codes: C11D 3/3773 in liquid compositions
• CPC Class Codes: C11D 3/3776 Heterocyclic compounds, e.g. lactam
• CPC Class Codes: C11D 3/3792 Amine oxide containing polymers
• CPC Class Codes: C11D 3/505 encapsulated or adsorbed on a carrier, e.g. zeolite or clay
• CPC Class Codes: D06P 1/5242 Polymers of unsaturated N-containing compounds
• CPC Class Codes: D06P 5/08 macromolecular

Abstract

The present invention relates to compositions and processes which incorporate water-soluble polymers, other than enzymes, containing ═N--C(═O)-- (including PVP) and/or N-oxide groups into the wash, rinse, and/or drying cycle of a laundering process (e.g., via fabric softening compositions) for dye transfer inhibition in the subsequent wash cycle. Multiple wash cycles optimize the dye transfer inhibitor performance of these polymers, remove unwanted dye discoloration caused by dye transfer, and provide soil antiredeposition benefits.

Claims

1. A dryer added fabric softening composition comprising:

I. from about 50% to about 99% by weight of the composition of fabric softening agent consisting essentially of;

cationic fabric softener;

nonionic fabric softener selected from the group consisting of sorbitan esters, C₁₂ -C₂₆ fatty alcohols, fatty amines, and mixtures thereof;

carboxylic acid salt of tertiary amines; and

mixtures thereof; and

II. from about 0.2% to about 50% by weight of the composition of water-soluble polymeric dye transfer inhibitor, selected from the group consisting of;

(A) polymers, which are not enzymes, with one or more monomeric units containing at least one ═

N--C(═

O)-- group having an average molecular weight of from about 500 to about 100,000;

(B) polymers with one or more monomeric units containing at least one N-oxide group having an average molecular weight of from about 500 to about 1,000,000;

(C) polymers containing both ═

N--C(═

O)-- and N-oxide groups of (A) and (B);

(D) mixtures thereof; and

wherein the composition is essentially free of bleach;

sachets containing an active ingredient;

anionic surfactant; and

, additionally, essentially free of polymer-coated soil release polymers; and

III. optionally, a dispensing means which provides for release of an effective amount of the composition to fabrics in an automatic laundry dryer to impart dye transfer inhibition benefits to said fabrics during subsequent wash cycles, plus softening effects, antistatic effects, or combination of softening and antistatic effects to said fabrics.

2. The dryer-added composition according to claim 1 wherein the fabric softening agent is from about 70% to about 99% by weight of the composition and said dye transfer inhibitor is from about 1% to about 30% by weight of the composition.

3. The dryer-added composition according to claim 1 wherein said dye transfer inhibitor has a particle size of about 0.5 mm or smaller.

4. The dryer-added composition according to claim 3 wherein said dye transfer inhibitor has a particle size of about 0.2 mm or smaller.

5. The dryer-added composition according to claim 1 wherein said dye transfer inhibitor is (A) having an average molecular weight of from about 500 to about 40,000.

6. The dryer-added composition according to claim 5 wherein said dye transfer inhibitor has an average molecular weight of from about 1,000 to about 30,000.

7. The dryer-added composition according to claim 1 wherein said dye transfer inhibitor is polyvinylpyrrolidone.

8. The dryer-added composition according to claim 1 wherein said dye transfer inhibitor is (B) having an average molecular weight of from about 1,000 to about 100,000.

9. The dryer-added composition according to claim 8 wherein said dye transfer inhibitor has an average molecular weight of from about 2,000 to about 100,000.

10. The dryer-added composition according to claim 1 wherein said dye transfer inhibitor is poly(4-vinylpyridine N-oxide).

11. The dryer-added composition according to claim 1 which additionally comprises from about 5% to about 40% perfume/cyclodextrin complex.

12. The dryer-added composition according to claim 1 additionally containing polymeric soil release agent at a level of from about 10% to about 40%.