Use of polyaspartic acid in detergents and cleaners

• US 5,770,553 A
• Filed: 05/20/1996
• Issued: 06/23/1998
• Est. Priority Date: 12/11/1993
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Kroner, Matthias, Baur, Richard, Schwendemann, Volker, Schornick, Gunnar, Kud, Alexander
• Primary Examiner(s): Shah, Mukund J.
• Assistant Examiner(s): TRUONG, TAMTHOM NGO
• Application Number:
  US08/646,263
• Time in Patent Office: 764 Days
• Field of Search: 510/501, 510/360, 510/476, 510/490, 510/533, 525/418, 525/419, 252/175, 252/180
• US Class Current: 510/360
• CPC Class Codes: C08G 69/10 Alpha-amino-carboxylic acids polysuccinimides C08G73/1092
• CPC Class Codes: C08G 73/1092 Polysuccinimides
• CPC Class Codes: C11D 3/3719 Polyamides or polyimides

Abstract

The use of polyaspartic acid prepared by polycondensation of aspartic acid in the presence of phosphoric acid in a molar ratio of from 1:0.05 to 1:10 at temperatures of at least 120° C. to give polysuccinimide, and subsequent hydrolysis of the polysuccinimide with bases to give at least partially neutralized polyaspartic acid, as additive to detergents and cleaners in amounts of from 0.1 to 10% by weight, and detergents and cleaners which contain polyaspartic acids prepared in the presence of phosphoric acid.

Claims

1. A method of preparing a detergent or cleaner, comprising polycondensing aspartic acid in the presence of phosphoric acid in a molar ratio of from 1:

0.05 to 1;

10 at temperatures of at least 120°

C. to give polysuccinimide, and subsequently hydrolyzing the polysuccinimide with bases to give at least partially neutralized polyaspartic acid, and adding said partially neutralized polyaspartic acid to detergents or cleaners in amounts of from 0.1 to 10% by weight based on the detergents and cleaners.

2. The method as claimed in claim 1, wherein the polycondensation of aspartic acid is carried out in the presence of phosphoric acid in a molar ratio of from 1:

1 to 1;

3 at from 140°

to 250°

C.

3. The method as claimed in claim 1, wherein the detergents or cleaners contain from 1 to less than 5% by weight of the at least partially neutralized polyaspartic acid.

4. A detergent or cleaner which contains at least one surfactant and polyaspartic acid with or without other conventional ingredients, which contains from 0.1 to 10% by weight of a polyaspartic acid which has been prepared by polycondensation of aspartic acid in the presence of phosphoric acid in a molar ratio of from 1:

0.05 to 1;

10 at temperatures of at least 120°

C. to give polysuccinimide, and subsequent hydrolysis of the polysuccinimide with bases to give at least partially neutralized polyaspartic acid.

5. A detergent or cleaner as claimed in claim 4, which contains from 1 to less than 5% by weight of polyaspartic acid.