Use of oligourethanes as formulating agents for aqueous pigment preparations

• US 5,770,651 A
• Filed: 10/13/1993
• Issued: 06/23/1998
• Est. Priority Date: 04/16/1991
• Status: Expired due to Fees

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Muller, Hans-Werner, Traubel, Harro, Novotny, Fritz
• Primary Examiner(s): NILAND, PATRICK DENNIS
• Application Number:
  US08/136,439
• Time in Patent Office: 1,714 Days
• Field of Search: 524/591, 524/839, 524/840
• US Class Current: 524/591
• CPC Class Codes: C08G 18/0823 containing carboxylate salt groups or groups forming them
• CPC Class Codes: C08G 18/12 using two or more compounds having active hydrogen in the first polymerisation step
• CPC Class Codes: C08G 18/282 Alkanols, cycloalkanols or arylalkanols including terpenealcohols
• CPC Class Codes: C08G 18/3278 containing at least three hydroxy groups
• CPC Class Codes: C09B 67/0066 Aqueous dispersions of pigments containing only dispersing agents
• CPC Class Codes: C09D 17/001 in aqueous medium C09D17/003, C09D17/004 take precedence
• CPC Class Codes: C14C 11/006 using polymeric products of isocyanates (or isothiocyanates) with compounds having active hydrogen

Abstract

Oligourethanes containing both anionic and cationic groups may be used as formulating agents for superior aqueous pigment preparations.

Claims

1. An aqueous pigment preparation comprising

(a) a formulating agent comprising an oligourethane having a number average molecular weight range of from 5000 to 50,000 and containing

(1) no primary or secondary amino groups,

(2) 5 to 25% by weight, based on the oligourethane, of incorporated ethoxy groups, and

(3) anionic and cationic groups, wherein the quantity of anionic groups is from 0.2 to 0.8 mol per 1000 g of the oligourethane and the molar ratio of anionic to cationic groups is from 0.8 to 4,

wherein said oligourethane comprises a reaction product of a polyisocyanate, hydroxyl compounds, wherein at least one such hydroxyl compound is a dihydroxyl compound containing ionic groups;

and an amino alcohol having tertiary nitrogen atoms;

(b) from 2 to 20 ml, per 100 gram of pigment preparation, of a pigment having a density of from 0.8 to 7 g/ml; and

(c) an aqueous phase containing up to 30% by weight of organic solvent.

2. An aqueous pigment preparation according to claim 1 wherein the dihydroxyl compound containing ionic groups comprises a dihydroxysulfonic acid corresponding to the formula ##STR3## wherein R is C₁ -C₄ alkyl.

3. An aqueous pigment preparation according to claim 1 wherein the dihydroxyl compound containing ionic groups comprises a dihydroxysulfonic acid corresponding to the formula ##STR4## wherein A and B are, independently of one another, divalent aliphatic hydrocarbon groups having 1 to 6 carbon atoms,

R is hydrogen, an aliphatic hydrocarbon groups having 1 to 4 carbon atoms, or a phenyl group,

X⁺ is an alkali metal cation or an optionally substituted ammonium group,

n and m are independently zero or numbers from 1 to 30,

o and p are independently zero or 1, and

q is zero, 1, or 2.

4. An aqueous pigment preparation according to claim 1 wherein the formulating agent contains 0.25 to 0.7 mol of anionic groups per 1000 g of the oligourethane.

5. An aqueous pigment preparation according to claim 1 wherein the molar ratio of anionic to cationic groups in the formulating agent is from 0.9 to 3.6.

6. A process for coloring a dressing agent for leather or a coating composition for textiles comprising mixing an aqueous pigment preparation according to claim 1 with said dressing agent for leather or coating composition for textiles.