Phenolic polymers made by aralkylation reactions

• US 5,773,552 A
• Filed: 01/03/1997
• Issued: 06/30/1998
• Est. Priority Date: 07/12/1995
• Status: Expired due to Fees

• Current Assignee: Georgia-Pacific Resins, Inc. (KOCH Industries Incorporated)
• Original Assignee: Georgia-Pacific Resins, Inc. (KOCH Industries Incorporated)
• Inventors: Hutchings, David A., Mills, Jeffrey L., Bourlier, Kenneth
• Primary Examiner(s): Truong, Duc
• Application Number:
  US08/775,377
• Time in Patent Office: 543 Days
• Field of Search: 528/205, 528/97, 568/717, 568/731, 568/734, 568/744
• US Class Current: 528/97
• CPC Class Codes: C08G 61/02 Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes

Abstract

The present invention is directed to the formation of phenol alkylation polymers which release negligible phenol and formaldehyde emissions. The phenol aralkylation polymers of the present invention are derived from a phenolic monomer, at least one styrene derivative and an aryl diolefin. In addition to the phenolic monomer, styrene derivative and aryl diolefin, other reactants may be introduced to produce a product with particular properties.

Claims

1. A phenol aralkylation polymer formed by reacting 1 mole of bisphenol A with from about 0.3 to 0.8 moles of an aryl diolefin to obtain a bisphenol A/aryl diolefin polymer and then aralkylating the polymer with at least one styrene derivative selected from the group consisting of p-t butyl styrene, t-butyl styrene, vinyl toluene, α

-methyl styrene, and styrene wherein from 20 to 100 percent of the open reactive sites of the polymer are occupied by styrene derived moieties.

2. The phenol aralkylation polymer of claim 1 wherein some of the styrene derivatives are reacted with the bisphenol A prior to reacting with the aryl diolefin.

3. The phenol aralkylation polymer of claim 1, wherein a portion of the bisphenol A is replaced with t-butyl phenol.

8. The phenol aralkylation polymer of claim 1 wherein the degree of styrenation is in the range of 40 to 95%.

4. A phenol aralkylation polymer formed by aralkylating bisphenol A with at least one styrene derivative selected from the group consisting of p-t butyl styrene, t-butyl styrene, vinyl toluene, α

-methyl styrene, and styrene and then reacting the aralkylated bisphenol A with an aryl diolefin to obtain the phenol aralkylation polymer wherein from about 0.3 to 0.8 mole of said aryl diolefin is reacted per mole of bisphenol A and wherein from 20 to 100 percent of the open reactive sites of the polymer are occupied by styrene derived moieties.

5. The phenol aralkylation polymer of claim 4 wherein a portion of the bisphenol A is replaced with t-butyl phenol.

9. The phenol aralkylation polymer of claim 4 wherein the degree of styrenation is in the range of 40 to 95%.

6. A phenol aralkylation polymer formed by coreacting bisphenol A with at least one styrene derivative selected from the group consisting of p-t butyl styrene, t-butyl styrene, vinyl toluene, α

-methyl styrene, and styrene and with an aryl diolefin to obtain the phenol aralkylation polymer wherein from about 0.3 to 0.8 mole of said aryl diolefin is reacted per mole of bisphenol A and wherein from 20 to 100 percent of the open reactive sites of the polymer are occupied by styrene derived moieties.

7. The phenol aralkylation polymer of claim 6 wherein a portion of the bisphenol A is replaced with t-butyl phenol.

10. The phenol aralkylation polymer of claim 6 wherein the degree of styrenation is in the range of 40 to 95%.