Latent image printing process and apparatus and substrate therefor

• US 5,774,160 A
• Filed: 03/31/1997
• Issued: 06/30/1998
• Est. Priority Date: 04/15/1991
• Status: Expired due to Fees

• Current Assignee: Nocopi Technologies, Inc.
• Original Assignee: Nocopi Technologies, Inc.
• Inventors: Gundjian, Arshavir
• Primary Examiner(s): TRAN, HUAN HUU
• Application Number:
  US08/829,264
• Time in Patent Office: 456 Days
• Field of Search: 347/171, 347/221, 503/201, 503/206, 503/226
• US Class Current: 347/171
• CPC Class Codes: B41M 3/142 using chemical colour-formers or chemical reactions, e.g. leuco-dye/acid, photochromes
• CPC Class Codes: B41M 5/124 using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
• CPC Class Codes: B41M 5/165 characterised by the use of microcapsules; Special solvents for incorporating the ingredients
• CPC Class Codes: B41M 5/24 Ablative recording, e.g. by burning marks; Spark recording marking by high energetic means, e.g. by laser otherwise than burning or ablative removal B41M5/26; materials or methods for recording or reproduction by optical means G11B7/00
• CPC Class Codes: B41M 5/26 Thermography B41M5/20, B41M5/24 take precedence; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used B23K takes precedence; thermographic or photothermographic systems using noble metal compounds G03C1/494
• CPC Class Codes: B41M 5/30 using chemical colour formers B41M5/34 takes precedence
• CPC Class Codes: B41M 5/36 using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties B41C1/10 takes precedence
• CPC Class Codes: B41M 5/48 combined with other image registration layers or compositions; Special originals for reproduction by thermography

Abstract

A latent image printing method and apparatus uses a substrate with one main surface having a covering comprising one of a first pair of a color developer and color former dye defining a background color in conjunction with the one main surface, wherein the color developer and the color former dye react when mixed to produce a first spectral response which is visible relative to the background color and a continuous coating over the covering which is non-porous with respect to the other of the pair and solvent-resistant to the other of the pair. The coating above selected portions of the covering corresponding to a desired latent image is removed.

Claims

1. A latent image printing substrate comprising:

one main surface having one of a pair of a color developer and color former dye applied thereto and defining a background color in conjunction with the one main surface, wherein the color developer and the color former dye react when mixed to produce a first spectral response which is visible relative to the background color; and

a covering over said one of the pair which is non-porous with respect to the other of the pair and solvent-resistant to the other of the pair, wherein the covering has a melting point of from 50°

to 200°

C.

2. A latent image printing substrate comprising:

one main surface having one of a pair of a color developer and color former dye applied thereto and defining a background color in conjunction with the one main surface, wherein the color developer and the color former dye react when mixed to produce a first spectral response which is visible relative to the background color; and

a covering over said one of the pair which is non-porous with respect to the other of the pair and solvent-resistant to the other of the pair, wherein the covering has a thickness on the order of 0.1 to 10 microns.

3. A latent image printing substrate comprising:

one main surface having one of a pair of a color developer and color former dye applied thereto and defining a background color in conjunction with the one main surface, wherein the color developer and the color former dye react when mixed to produce a first spectral response which is visible relative to the background color; and

a covering over said one of the pair which is non-porous with respect to the other of the pair and solvent-resistant to the other of the pair, further comprising a layer of sensitizer on the covering.

4. A latent image printing substrate comprising:

one main surface having one of a pair of a color developer and color former dye applied thereto and defining a background color in conjunction with the one main surface, wherein the color developer and the color former dye react when mixed to produce a first spectral response which is visible relative to the background color; and

a covering over said one of the pair which is non-porous with respect to the other of the pair and solvent-resistant to the other of the pair, wherein the covering includes a sensitizer.

5. A latent image printing substrate comprising:

one main surface having one of a pair of a color developer and color former dye applied thereto and defining a background color in conjunction with the one main surface, wherein the color developer and the color former dye react when mixed to produce a first spectral response which is visible relative to the background color; and

a covering over said one of the pair which is non-porous with respect to the other of the pair and solvent-resistant to the other of the pair, wherein the covering comprises microcapsules encapsulating the one of the pair and which are non-porous with respect to the other of the pair and have a melting point of between 50° and

200°

C.

6. A latent image printing process comprising the steps of:

providing a substrate with one main surface having one of a pair of a color developer and color former dye applied thereto and defining a background color in conjunction with the one main surface, wherein the color developer and the color former dye react when mixed to produce a first spectral response which is visible relative to the background color and a covering over said one of the pair which is non-porous with respect to the other of the first pair and solvent-resistant to the other of the pair; and

removing selected portions of the covering corresponding to a desired latent image.

7. The process according to claim 6, further comprising the step of activating the latent image by applying the other of said pair on the covering to react with the one of said pair where the coating has been removed.

8. The process according to claim 6, wherein the covering has a melting point of from 50°

to 200°

C.

9. The process according to claim 8, wherein the step of removing comprises locally heating the covering to above its melting point.

10. The process according to claim 6, wherein the covering has a thickness of from 0.1 to 10 microns.

11. The process according to claim 10, wherein the step of removing comprises locally applying pressure to the covering.

12. A latent image printing process comprising the steps of:

providing a first substrate with one main surface having one of a pair of a color developer and color former dye applied thereto and defining a background color in conjunction with the one main surface, wherein the color developer and the color former dye react when mixed to produce a first spectral response which is visible relative to the background color and a covering over said one of the pair which is non-porous with respect to the other of the first pair and solvent-resistant to the other of the pair;

superposing a second substrate with one main surface onto the one main surface of the first substrate; and

causing selected portions of the covering corresponding to a desired latent image to be transferred to the one main surface of the second substrate.

13. The process according to claim 12, further comprising causing selected portions of the covering and said one of said pair to be transferred to the one main surface of the second substrate.

14. The process according to claim 13, wherein the step of causing a transfer comprises locally heating the covering and said one of said pair through one of the first and second substrate.

15. The process according to claim 13, wherein the step of causing a transfer comprises locally applying pressure to the covering and said one of said pair through one of the first and second substrate.

16. The process according to claim 13, further comprising the step of activating the latent image by applying the other of said pair on the one main surface of the second substrate to react with the one of said pair where the covering and said one of said pair have been transferred.

17. The process according to claim 12, wherein the covering has a thickness of from 0.1 to 10 microns.

18. The process according to claim 12, wherein the step of causing a transfer comprises locally heating the covering through one of the first and second substrate.

19. The process according to claim 12, wherein the step of causing a transfer comprises locally applying pressure to the covering through one of the first and second substrate.

20. The process according to claim 12, further comprising the step of activating the latent image by applying the other of said pair on the one main surface of the first substrate to react with the one of said pair where the covering has been transferred.