Tin oxide based conductive powders and coatings

• US 5,776,373 A
• Filed: 03/06/1996
• Issued: 07/07/1998
• Est. Priority Date: 08/18/1994
• Status: Expired due to Term

• Current Assignee: Milliken & Company
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Feist, Thomas Paul, Hormadaly, Jacob, Bergmann, Oswald Robert, Jacobson, Howard Wayne
• Primary Examiner(s): McGinty, Douglas J.
• Assistant Examiner(s): Delcotto, Gregory R.
• Application Number:
  US08/611,894
• Time in Patent Office: 853 Days
• Field of Search: 252/518, 106/443, 423/593
• US Class Current: 252/518.1
• CPC Class Codes: C01G 19/02 Oxides
• CPC Class Codes: C09D 5/24 Electrically-conducting paints conductive materials H01B1/00
• CPC Class Codes: H01B 1/08 oxides
• CPC Class Codes: H01B 1/20 Conductive material dispersed in non-conductive organic material organic macromolecular compounds or compositions C08

Abstract

A product and process are disclosed that relate to electroconductive powders based on tantalum, niobium, or phosphorus or any combination thereof doped tin oxide and coatings containing such powders. These powders can be used for making transparent coated films that are conductive and have desirable properties for a number of end uses. Some important end uses are in static dissipative fiber and films, coatings for recyclable containers, materials involved in packaging, where the presence of certain heavy metals is undesirable, transparent conductive coatings, among other uses.

Claims

1. A method for making an electroconductive powder by a process comprising:

(1) preparing a first solution comprising an aqueous solution containing a source of tin, and a second solution comprising a source of phosphorus,

(2) combining the first and second solutions,

(3) adding the combined solution to water while stirring and maintaining pH at about 0 to about 7 by adding a basic solution, thereby precipitating a hydrous tin oxide; and

,

(4) heating the hydrous tin oxide to a temperature sufficient to obtain the electroconductive powder.

2. The method of claim 1 wherein the hydrous tin oxide is calcined in a substantailly inert atmosphere.

3. The method of claim 1 wherein the source of tin comprises at least one of tetravalent tin salts selected from the group of a chloride, sulfate, nitrate, an oxalate, and acetate.

4. The method of claim 1 wherein the source of phosphorus comprises at least one member from the group consisting of phosphorus pentoxide, phosphorus oxychloride and phosphoric acid.