Silicone compositions and uses thereof

• US 5,777,059 A
• Filed: 04/19/1996
• Issued: 07/07/1998
• Est. Priority Date: 04/19/1996
• Status: Expired due to Term

• Current Assignee: Dow Corning Corporation (Dow, Inc.)
• Original Assignee: Dow Corning Corporation (Dow, Inc.)
• Inventors: Fey, Kenneth Christopher, Datz-Siegel, Teresa Lynn
• Primary Examiner(s): MOORE, MARGARET G
• Application Number:
  US08/635,043
• Time in Patent Office: 809 Days
• Field of Search: 524/863, 524/731, 524/588, 524/506, 252/321, 252/358, 528/25, 528/22, 528/12, 528/14, 528/21, 528/23
• US Class Current: 528/14
• CPC Class Codes: B01D 19/0404 characterised by the nature of the chemical substance
• CPC Class Codes: B01D 19/0409 compounds containing Si-atoms
• CPC Class Codes: C08G 77/02 Polysilicates
• CPC Class Codes: C08G 77/16 to hydroxyl groups
• CPC Class Codes: C08G 77/18 to alkoxy or aryloxy groups
• CPC Class Codes: C08G 77/24 halogen-containing groups
• CPC Class Codes: C08G 77/44 containing only polysiloxane sequences
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/44 Silicon-containing compounds
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: C11D 3/0026 Low foaming or foam regulating compositions
• CPC Class Codes: C11D 3/373 containing silicones
• CPC Class Codes: D21C 3/28 Prevention of foam
• CPC Class Codes: D21H 21/12 Defoamers

Abstract

The present invention relates to a silicone composition prepared by reacting a mixture of (i) a polyisobutylene compound, (ii) a polyorganosiloxane, (iii) a silicon compound, and (iv) a catalytic amount of a catalyst. The compositions of this invention are resistant to phase separation and are useful as foam control compositions in foam producing systems.

Claims

1. A silicone composition prepared by reacting at a temperature of 25°

C. to 300°

C. a mixture comprising;

(i) 1 to 100 parts by weight of a polyisobutylene compound;

(ii) 5 to 100 parts by weight of a polyorganosiloxane having a viscosity of 200 to about 100 million mm² /s at 25°

C. expressed by the general formula R¹_a (R² O)_b SiO.sub.(4-a-b)/2 in which R¹ a monovalent hydrocarbon or halogenated hydrocarbon group having 1 to 10 carbon atoms, R² is hydrogen or a monovalent hydrocarbon group having 1 to 10 carbon atoms, a has an average value of 1.9 to 2.2 and b has a sufficiently large value to give at least one --OR² group in each molecule, at least one such --OR² group being present at the end of the molecular chain;

(iii) 0.5 to 20 parts by weight of at least one silicon compound selected from

(a) an organosilicon compound of the general formula R³_c SiX_4-c in which R³ is a monovalent hydrocarbon group having 1 to 5 carbon atoms, X is selected from a halogen atom or a hydrolyzable group and c has an average value of one or less,

(b) a partially hydrolyzed condensate of said compound (a),

(c) a siloxane resin comprising (CH₃)₃ SiO_1/2 units and SiO₄ /₂ units wherein the ratio of (CH₃)₃ SiO_1/2 units to SiO_4/2 units is 0.4;

1 to 1.2;

1, or

(d) a condensate of said compound (c) with said compound (a) or (b); and

(iv) a catalytic amount of a catalyst selected from the group consisting of alkali metal hydroxides, alkali metal silanolates, alkali metal alkoxides, guatemary ammonium hydroxides, quatemary ammonium silanolates, quatemnar phosphonium hydroxides, quatemmry phosphonium silanolates, mineral acids, acetic acid, organosulfonic acids, ammonium carbonate, and ammonium hydroxide.

2. A composition according to claim 1, wherein one end group of said polyisobutylene is a saturated group and another end group is selected from a saturated group or an unsaturated group and said polyisobutylene has a number average molecular weight of about 200 to about 400.

3. A composition according to claim 2, wherein the saturated endgroup is independently selected from --C(CH₃)₃ or --CH₂ C(CH₃)₂ H and the unsaturated endgroup is independently selected from --CH═

C(CH₃)₂ or --CH═

CH₂.

4. A composition according to claim 1, wherein polyorganosiloxane (ii) is a hydroxyl-terminated polydimethylsiloxane having a viscosity of about 1,000 to 50,000 mm² /s at 25°

C.

5. A composition according to claim 1, wherein silicon compound (iii) is selected from ethyl polysilicate or a siloxane resin copolymer comprising (CH₃)₃ SiO_1/2 units and SiO₂ units in a molar ratio of approximately 0.4:

1 to 1.2;

1, respectively.

6. A composition according to claim 1, wherein the catalyst (iv) is selected from the group consisting of alkali metal hydroxides, alkali metal silanolates, alkali metal alkoxides, quaternary ammonium hydroxides, and quaternary ammonium silanolates.

7. A composition according to claim 1, wherein the mixture further comprises up to 30 parts by weight of:

(v) at least one finely divided filler.

8. A composition according to claim 7, wherein the finely divided filler (v) is a hydrophobic silica having a surface area of about 50 to 300 m² /g.

9. A composition according to claim 1, wherein the mixture further comprises up to 20 parts by weight of:

(vi) a polyorganosiloxane having a viscosity of 5 to 200 mm² /s at 25°

C. and being expressed by the general formula R⁷_d (R⁸ O)_e SiO.sub.(4-d-e)/2 wherein R⁷ is a monovalent hydrocarbon or halogenated hydrocarbon group having one to ten carbon atoms, R⁸ is hydrogen or a monovalent hydrocarbon group having one to ten carbon atoms, d is has a value of 1.9 and 2.2 and e has a value so as to provide at least two --OR⁸ groups in each molecule.

10. A composition according to claim 7, wherein the mixture further comprises up to 20 parts by weight of:

(vi) a polyorganosiloxane having a viscosity of 5 to 200 mm² /s at 25°

C. and being expressed by the general formula R⁷_d (R⁸ O)_e SiO.sub.(4-d-e)/2 wherein R⁷ is a monovalent hydrocarbon or halogenated hydrocarbon group having one to ten carbon atoms, R⁸ is hydrogen or a monovalent hydrocarbon group having one to ten carbon atoms, d is has a value of 1.9 and 2.2 and e has a value so as to provide at least two --OR⁸ groups in each molecule.

11. A composition according to claim 9, wherein said polyorganosiloxane (vi) is a hydroxyl-terminated polydimethylsiloxane having a viscosity of about 10 to 100 mm² /s at 25°

C.

12. A composition according to claim 10, wherein said polyorganosiloxane (vi) is a hydroxyl-terminated polydimethylsiloxane having a viscosity of about 10 to 100 mm² /s at 25°

C.

13. A method for controlling foam in a foam producing system comprising adding to the foam producing system the composition of claim 1.

14. A method for controlling foam in a foam producing system comprising adding to the foam producing system the composition of claim 2.

15. A method for controlling foam in a foam producing system comprising adding to the foam producing system the composition of claim 6.

16. A method for controlling foam in a foam producing system comprising adding to the foam producing system the composition of claim 7.

17. A method for controlling foam in a foam producing system comprising adding to the foam producing system the composition of claim 9.

18. A method for controlling foam in a foam producing system comprising adding to the foam producing system the composition of claim 10.

19. A method according to claim 13, wherein the foam producing system is selected from inks, coatings, paints, detergents, pulp manufacture, paper manufacture, textile dyes, or hydrocarbon containing fluids.

20. A method according to claim 16, wherein the foam producing system is selected from inks, coatings, paints, detergents, pulp manufacture, paper manufacture, textile dyes, or hydrocarbon containing fluids.