Use of zeolites and alumina in adsorption processes

• US 5,779,767 A
• Filed: 03/07/1997
• Issued: 07/14/1998
• Est. Priority Date: 03/07/1997
• Status: Expired due to Term

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Golden, Timothy Christopher, Allam, Rodney John, Taylor, Fred William, Kalbassi, Mohammed Ali
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US08/814,749
• Time in Patent Office: 494 Days
• Field of Search: 95/96-106, 95/117-126, 95/139, 95/141, 95/145, 95/902, 96/108, 96/121, 96/130
• US Class Current: 95/96
• CPC Class Codes: B01D 2253/104 Alumina
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/1085 characterized by a silicon-aluminium ratio
• CPC Class Codes: B01D 2253/30 Physical properties of adsorbents
• CPC Class Codes: B01D 2257/404 Nitrogen oxides other than dinitrogen oxide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2257/7022 Aliphatic hydrocarbons
• CPC Class Codes: B01D 2257/80 Water
• CPC Class Codes: B01D 2259/416 involving cryogenic temperature treatment
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/0462 Temperature swing adsorption
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: B01J 20/08 comprising aluminium oxide or hydroxide; comprising bauxite
• CPC Class Codes: B01J 20/183 Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
• CPC Class Codes: B01J 2220/42 Materials comprising a mixture of inorganic materials materials coated or impregnated on a carrier B01J20/32
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y10S 95/902 Molecular sieve

Abstract

A process for the adsorption of at least carbon dioxide, water and oxides of nitrogen and preferably acetylene from a feed gas, comprises contacting the feed gas with an adsorbent mixture of a zeolite and an alumina. The process may be operated as a swing adsorption process comprising contacting the gas with the adsorbent at a first temperature and pressure to adsorb at least carbon dioxide, water and oxides of nitrogen therefrom and periodically regenerating the adsorbent by reducing the pressure and or increasing the temperature to which the adsorbent is exposed.

Claims

1. A process for the adsorption of at least carbon dioxide and water from a feed gas, comprising contacting the feed gas with a composite adsorbent comprising a fixture of a zeolite and an alumina.

2. A process as claimed in claim 1, in which acetylene is also adsorbed from said feed gas by said adsorbent.

3. A process as claimed in claim 1, in which nitrogen oxides are also adsorbed from said feed gas by said adsorbent.

4. A process as claimed in claim 1, wherein said feed gas is air.

5. A process as claimed in claim 1, wherein the adsorbent contains from 10 to 90% by weight zeolite and from 90 to 10% by weight alumina.

6. A process as claimed in claim 5, wherein the adsorbent contains from 20 to 80% zeolite and from 80 to 20% by weight alumina.

7. A process as claimed in claim 6, wherein the adsorbent contains from 30 to 50% by weight zeolite and from 70 to 50% by weight alumina.

8. A process as claimed in claim 1, wherein the zeolite has a Si/Al ratio of at least 1.0.

9. A process as claimed in claim 8, wherein the zeolite has a Si/Al ratio of at least 2.0.

10. A process as claimed in claim 9, wherein said zeolite is Na Y zeolite.

11. A process as claimed in claim 1, wherein said alumina is a modified alumina obtainable by impregnating a starting alumina with a basic solution having a pH of 9 or more.

12. A process as claimed in claim 11, wherein the pH of the impregnating solution is at least 10.

13. A process as claimed in claim 11, wherein the pH of the impregnating solution is from 10 to 12.

14. A process as claimed in claim 11, wherein the pH of the impregnating solution is about 11.

15. A process as claimed in claim 11, wherein the pH of the impregnating solution is related to the zero point charge of the alumina according to the formula:

space="preserve" listing-type="equation">pH≧

zpc-1.4

16.

16. A process as claimed in claim 15, wherein the pH of the impregnating solution is related to the zero point charge of the alumina by the formula:

space="preserve" listing-type="equation">zpc+2≧

pH≧

zpc-1.4.

17. A process as claimed in claim 15, wherein the pH of the impregnating solution is related to the zero point charge of the alumina by the formula:

space="preserve" listing-type="equation">zpc+1≧

pH≧

zpc-1.

18. A process as claimed in claim 11, wherein said basic solution is a solution of an alkali metal or ammonium compound.

19. A process as claimed in claim 11, wherein said basic solution is selected for the group consisting of alkali metal or ammonium hydroxides, carbonates, bicarbonates, phosphates, and organic acid salts.

20. A process as claimed in claim 1, which is a swing adsorption process comprising contacting said gas with said adsorbent at a first temperature and pressure to adsorb at least carbon dioxide, water and oxides of nitrogen therefrom and periodically regenerating said adsorbent by reducing the pressure and or increasing the temperature to which the adsorbent is exposed.

21. A process as claimed in claim 20, which is a pressure swing adsorption process, conducted according to the following parameters:

Feed pressure;

15 to 450 psig (305-3130 kPa)

Feed temperature;

5°

to 50°

C.

Cycle time;

10 to 80 minutes

Regeneration Temp.;

10°

to 60°

C.

Purge pressure;

-7 to 100 psig (152-910 kPa)

Feed CO₂ content;

1 to 1000 ppm.

22. A process as claimed in claim 20, which is a pressure swing adsorption process, conducted according to the following parameters:

Feed pressure;

15 to 200 psig (305-1615 kPa)

Feed temperature;

10°

to 40°

C.

Cycle time;

10 to 80 minutes

Regeneration Temp.;

20°

to 50°

C.

Purge pressure;

0 to 30 psig (202-408 kPa)

Feed CO₂ content;

200 to 600 ppm.

23. A process as claimed in claim 20, which is a temperature swing adsorption process, conducted according to the following parameters:

Feed pressure;

15 to 450 psig (305-3130 kPa)

Feed temperature;

5°

to 50°

C.

Cycle time;

60 to 900 minutes

Regeneration Temp.;

30°

to 250°

C.

Purge pressure;

-7 to 100 psig (152-910 kPa)

Feed CO₂ content;

1 to 1000 ppm.

24. A process as claimed in claim 20, which is a temperature swing adsorption process, conducted according to the following parameters:

Feed pressure;

15 to 200 psig (305-1615 kPa)

Feed temperature;

10°

to 40°

C.

Cycle time;

120 to 300 minutes

Regeneration Temp.;

50°

to 150°

C.

Purge pressure;

0 to 30 psig (202-408 kPa)

Feed CO₂ content;

200 to 600 ppm.

25. A process as claimed in claim 20, which is a hybrid pressure and temperature swing adsorption process, conducted according to the following parameters:

Feed pressure;

15 to 450 psig (305-3130 kPa)

Feed temperature;

5°

to 60°

C.

Cycle time 40 to 600 minutes

Regeneration Temp.;

20°

to 120°

C.

Purge pressure;

-7 to 100 psig (152-910 kPa)

Feed CO₂ content;

1 to 1000 ppm.

26. A process as claimed in claim 20, which is a hybrid pressure and temperature swing adsorption process, conducted according to the following parameters:

Feed pressure;

15 to 200 psig (305-1615 kPa)

Feed temperature;

10°

to 50°

C.

Cycle time 60 to 200 minutes

Regeneration Temp.;

30°

to 100°

C.

Purge pressure;

0 to 30 psig (202-408 kPa)

Feed CO₂ content;

200 to 600 ppm.

27. An adsorbent comprising a zeolite and a modified alumina comprising an activated alumina impregnated with a basic impregnant material.

28. An adsorbent as claimed in claim 27, wherein said-modified alumina is obtainable by impregnating a starting alumina with a basic solution having a pH of 9 or more.

29. An adsorbent as claimed in claim 27 which has not been heated to temperatures sufficient to decompose the impregnant.

30. An adsorbent as claimed in claim 27, wherein the modified alumina comprises activated alumina and a basic material selected from the group consisting of alkali metal or ammonium hydroxides, carbonates, bicarbonates, phosphates and organic acid salts.