Non-fouling flow through capacitor system

• US 5,779,891 A
• Filed: 04/15/1997
• Issued: 07/14/1998
• Est. Priority Date: 04/23/1990
• Status: Expired due to Term

• Current Assignee: Biosource, Incorporated
• Original Assignee: Marc D. Andelman
• Inventors: Andelman, Marc D.
• Primary Examiner(s): Therkorn, Ernest G.
• Application Number:
  US08/834,259
• Time in Patent Office: 455 Days
• Field of Search: 204/600, 204/645, 204/647, 204/671, 210/635, 210/656, 210/747, 210/198.2, 210/243, 210/541
• US Class Current: 210/198.2
• CPC Class Codes: B01D 15/00 Separating processes involving the treatment of liquids with solid sorbents using liquid sorbents B01D11/00; ion exchange processes or materials, sorbent materials in general B01J, e.g. sorbents for chromatography B01J20/281; for investigating or analysing materials G01N30/00; Apparatus therefor
• CPC Class Codes: B01D 15/36 involving ionic interaction
• CPC Class Codes: B01J 47/08 subjected to a direct electric current
• CPC Class Codes: C02F 1/4691 Capacitive deionisation
• CPC Class Codes: C02F 2301/024 Turbulent
• CPC Class Codes: G01N 2030/0035 electrical field
• CPC Class Codes: G01N 2030/027 Liquid chromatography
• CPC Class Codes: G01N 2030/965 suppressor columns
• CPC Class Codes: G01N 30/02 Column chromatography
• CPC Class Codes: G01N 30/461 with serial coupling of separation columns
• CPC Class Codes: G01N 30/466 with separation columns in parallel
• CPC Class Codes: G01N 30/50 Conditioning of the sorbent material or stationary liquid
• CPC Class Codes: G01N 30/60 Construction of the column
• CPC Class Codes: G01N 30/6043 in parallel
• CPC Class Codes: G01N 30/6069 with compartments or bed substructure
• CPC Class Codes: G01N 30/6095 Micromachined or nanomachined, e.g. micro- or nanosize
• CPC Class Codes: G01N 30/96 using ion-exchange G01N30/02, G01N30/90 take precedence

Abstract

A foul-resistant, flow-through capacitor, a system employing the capacitor and a method of separation is disclosed wherein the capacitor has at least one anode and cathode electrode pair. The electrodes are formed of high surface area, electrically conductive material and have an open, preferably straight, fluid flow-through path. Typically, the flow path is formed by a plurality of straight, parallel, spaced apart electrodes with the flow path not greater than one of the X-Y-Z distance components of the capacitor. The flow-through capacitor avoids fouling in use and may be employed with saturated waste or other streams.

Claims

1. A flow-through capacitor-cartridge system for use in the electrical treatment of fluids which tend to foul the capacitor of the system, which system comprises:

a) one or more foul-resistant, flow-through capacitors, each capacitor having at least one anode and cathode pair for use in the electrical purification, concentration, separation, recovery, or electrochemical breakdown of solutes or fluids, which capacitor comprises one or more monolithic, spaced apart pairs of cathode-anode electrodes incorporating a high surface area material and having a non-conductive spacer between the anode and cathode electrodes characterized by an open flow path between the electrodes to permit the unobstructed flow of the fluid across the electrode surface and of sufficient width to prevent the fouling of the capacitor, and wherein the open flow path has at least one dimension open to an exterior of the capacitor; and

b) cartridge means to seal the capacitor therein, the cartridge means having a fluid flow feed inlet and a fluid flow product outlet.

2. The system of claim 1 wherein the cartridge means has a liquid dead volume and which system includes means to displace liquid from the dead volume by pressurized gas.

3. The system of claim 1 which includes a feed source of saturated waste in communication with the feed inlet and for processing by the capacitor and means to recycle the saturated waste and to recover from the product outlet the waste as a solid precipitate.

4. The system of claim 3 which includes a decantation tank, provided with means to trigger precipitation from a super-saturated solution.

5. The system of claim 1 which includes a control means to control the system by integrating current versus time to calculate a set amount of charge which triggers a regeneration cycle of the capacitor.

6. The system of claim 1 which includes a single capacitor and a hold-up tank to average the flow of the fluid being processed through the cartridge means to provide a continuous product stream.

7. The system of claim 1 which includes three or more simultaneously regenerating capacitors in the system and wherein multiple capacitors are electrically connected in series and used to recharge a lesser number of capacitors in the system.

8. The system of claim 1 wherein the flow of the fluid into the flow inlet through the capacitor is reversed every charge or discharge cycle or wherein polarity of the electrodes is reversed every charge or discharge cycle.

9. The system of claim 1 wherein the open flow path is relatively short and is no longer in length than the length or height of the electrode.

10. The system of claim 1 wherein the open flow path is straight.

11. The system of claim 1 wherein the flow path comprises multiple parallel flow paths.

12. The system of claim 1 wherein the flow path comprises multiple serpentine flow paths.

13. The system of claim 1 wherein the flow passages include baffle means within the flow path of the fluid to create flow turbulence for cleaning purposes.

14. The system of claim 1 wherein the open flow paths comprise a plurality of generally parallel, straight flow paths comprising at least as many flow paths as there are spaces between the electrodes.

15. The system of claim 1 wherein the width of the flow path is less than about 50 mils.

16. The system of claim 1 wherein the space between the electrodes forms an open flow path following the contours of the electrodes along the shortest, straightest route to the exterior surface of the capacitor.

17. The system of claim 1 wherein the spacer material comprises integral pieces of material in washer or netting form.

18. The system of claim 1 wherein the spacer material comprises multiple shims, protrusions, rods or threads.

19. The system of claim 1 wherein the spacer material is manufactured directly attached to the high surface area electrode material in the form of ridges, multiple individual protrusions or ribs.

20. The system of claim 1 wherein the monolithic high surface area material is selected from the group consisting of:

bonded or sintered activated carbon particles;

aerogel particles;

conductive ceramics;

activated carbon fiber cloth;

fibrous metal coated with platinum;

or transition metal oxides, borides and nitrides, and combinations thereof.

21. The system of claim 1 wherein the monolithic high surface area material comprises activated carbon sintered together with a binder and doped with a metal.

22. The system of claim 1 which includes a conductive backing electrically secured to the high surface area material.

23. The system of claim 1 wherein the conductive backing comprises integral metal or graphite foil sheet material.

24. The system of claim 1 wherein the capacitor electrodes are in spiral wound form, and the spacer material is in the form of an open net or mesh.

25. The system of claim 1 wherein the capacitor electrodes are in crescent pleat form about a central tube, and the spacer material is in the form of an open net or mesh material.

26. The system of claim 1 wherein the capacitor electrodes are in flat, polygonal form, and the capacitor is placed within a flat, polygonal or circular box-shape cartridge.

27. The system of claim 1 whereby the capacitor electrodes are in the form of multiple rods or tubes.

28. The system of claim 1 whereby the capacitor electrodes are formed of a composite high surface area conductive material and include a conductive backing or fibrous network formed together as a single, integral material.

29. The system of claim 1 wherein the width spacing between the electrodes is between about 5 and 20 mils, and the length of the open flow path is less than about 12 inches.

30. The system of claim 1 wherein the spacer comprises biplanar netting material.

31. The system of claim 1 wherein the electrode includes a conductive backing layer.

32. The system of claim 1 wherein the internal electrical resistance of the capacitor is less than about four ohms.

33. The system of claim 1 wherein the electrodes comprise a non-conductive high surface area material in contact with a conductive backing material.

34. The system of claim 1 wherein the spacer is characterized by screen printed microprotrusions.

35. The system of claim 1 wherein the open flow path comprises straight multiple parallel flow paths of less than 50 mils and the lesser dimension of the X-Y-Z dimensions of the electrode.