Dual-cure latex compositions

• US 5,780,117 A
• Filed: 02/25/1997
• Issued: 07/14/1998
• Est. Priority Date: 02/26/1996
• Status: Expired due to Term

• Current Assignee: Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Rohm and Haas Company (Dow, Inc.)
• Inventors: Wood, Kurt Arthur, Swartz, Andrew Joseph
• Primary Examiner(s): GULAKOWSKI, RANDY P
• Application Number:
  US08/806,893
• Time in Patent Office: 504 Days
• Field of Search: 523/406, 430/905, 430/910, 430/927, 522/110, 522/113, 525/107, 525/529, 525/530, 525/531, 525/532, 427/493
• US Class Current: 427/493
• CPC Class Codes: C08G 59/18 Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
• CPC Class Codes: C08J 3/243 Two or more independent types of crosslinking for one or more polymers
• CPC Class Codes: C08J 3/28 Treatment by wave energy or particle radiation
• CPC Class Codes: Y10S 430/106 Binder containing
• CPC Class Codes: Y10S 430/111 Polymer of unsaturated acid or ester
• CPC Class Codes: Y10S 430/128 Radiation-activated cross-linking agent containing

Abstract

Radiation-curable latex compositions having a secondary curing mechanism are disclosed. In these compositions, an anionically stabilized, water-borne dispersion of one or more radiation-curable resins is combined with a low molecular weight compound having at least two reactive functional groups, wherein one reactive functional group comprises an epoxy and the other reactive functional group comprises either an epoxy or a functionality capable of self-condensation after film formation. Also disclosed is a method for providing a cross-linked protective coating on a substrate, wherein a coating of the composition of the present invention is applied to the substrate, the coated substrate is exposed to actinic radiation to effect curing, and then the unexposed or underexposed portions of the coated substrate are allowed to cure at room temperature or greater.

Claims

1. A radiation-cured latex composition having a secondary curing mechanism, comprising:

an anionically stabilized, water-borne dispersion of one or more radiation-curable resins; and

a low molecular weight compound having at least two reactive functional groups, wherein one reactive functional group comprises an epoxy and the other reactive functional group comprises either an epoxy or a functionality, which is cured via self-condensation after film formation.

2. The latex composition of claim 1, wherein the low molecular weight compound having at least two reactive functional groups is selected from the group consisting of:

aliphatic or cycloaliphatic di- and tri-epoxies, and epoxysilanes.

3. The latex composition of claim 2, wherein the low molecular weight compound having at least two reactive functional groups is selected from the group consisting of:

3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, bis-(3,4-epoxycyclohexyl) adipate, 3-glycidoxypropyltrimethyoxy silane, and other glycidoxyalkyl trialkoxysilanes.

4. The latex composition of claim 1, wherein the molecular weight of the low molecular weight compound is less than 1000.

5. The latex composition of claim 4, wherein the molecular weight of the low molecular weight compound is between 100-500.

6. The latex composition of claim 1, wherein the composition has a pot life of at least 2 weeks.

7. A method for providing a cross-linked protective coating on a substrate, comprising the steps of:

applying a coating of the composition of claim 1 to the substrate;

exposing the coated substrate to actinic radiation to effect curing; and

allowing the unexposed or underexposed portions of the coated substrate to cure at room temperature or greater.

8. A method for providing a secondary curing mechanism to a radiation-cured latex composition, comprising the addition of a low molecular weight compound having at least two reactive functional groups, wherein one reactive functional group comprises an epoxy and the other reactive functional group comprises either an epoxy or a functionality, which is cured via self-condensation after film formation.

9. The method of claim 8, wherein the low molecular weight compound having at least two reactive functional groups is selected from the group consisting of:

aliphatic or cycloaliphatic di- and tri-epoxies, and epoxysilanes.

10. The method of claim 9, wherein the low molecular weight compound having at least two reactive functional groups is selected from the group consisting of:

3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, bis-(3,4-epoxycyclohexyl) adipate, 3-glycidoxypropyltrimethyoxysilane, and other glycidoxyalkyl trialkoxysilanes.