Treatments to reduce friction and wear on metal alloy components

• US 5,780,119 A
• Filed: 03/20/1996
• Issued: 07/14/1998
• Est. Priority Date: 03/20/1996
• Status: Expired due to Term

• Current Assignee: Southwest Research Institute
• Original Assignee: Southwest Research Institute
• Inventors: Dearnaley, Geoffrey, Lankford, James Jr.
• Primary Examiner(s): King, Roy V.
• Application Number:
  US08/618,568
• Time in Patent Office: 846 Days
• Field of Search: 427/530, 427/528, 427/249, 427/527, 427/122, 427/402, 427/2.26, 427/525, 623/18, 623/19, 623/20
• US Class Current: 427/528
• CPC Class Codes: C23C 16/029 Graded interfaces
• CPC Class Codes: C23C 16/26 Deposition of carbon only
• CPC Class Codes: C23C 16/486 using ion beam radiation

Abstract

The present invention provides a method for strongly adhering a diamond-like carbon coating to a metal alloy substrate using ion beam assisted deposition of silicon and/or germanium followed by ion beam assisted deposition of diamond-like carbon.

Claims

1. A method for coating an outer surface of a metal alloy substrate with diamond-like carbon comprising:

exposing said metal alloy substrate to a vacuum of at least about 10^-5 torr;

heating said substrate to a first temperature of about 300°

C. (149°

F.) or, if said metal alloy is temperature sensitive, to a highest temperature acceptable for said metal alloy;

depositing an intermediate material selected from the group consisting of silicon and germanium onto said substrate in an amount sufficient to form an intermetallic bonding layer at said outer surface of said substrate cohesively bonded to an outer interlayer of said intermediate material;

substantially simultaneously bombarding said intermediate material with a first energetic beam of ions at a first energy, a first ion arrival ratio, and for a first amount of time sufficient to form said intermetallic bonding layer cohesively bonded to said interlayer;

condensing a diamond-like carbon precursor onto said interlayer at a second temperature and for a second amount of time sufficient to form a film of precursor molecules on said interlayer;

substantially simultaneously bombarding said diamond-like carbon precursor with a second energetic beam of ions at a second energy, a second ion arrival ratio, and for a third amount of time sufficient to form a carbide bonding layer cohesively bonded to a coating of diamond-like carbon.

3. The method of claim 1 wherein said first and second beam of ions comprise ions selected from the group consisting of nitrogen, argon, silicon, methane, helium, neon, and combinations thereof.

4. The method of claim 1 wherein said second beam of ions comprises nitrogen ions.

6. The method of claim 1 wherein said first energy and said second energy are between about 10-30 keV.

8. The method of claim 1 wherein said second temperature is about 80°

C. (26°

F.).

10. The method of claim 4 wherein said second temperature is about 80°

C. (26°

F.).

11. The method of claim 1 wherein said intermediate material is deposited onto said substrate to a thickness of between about 100-200 nm.

13. The method of claim 3 wherein said intermediate material is deposited onto said substrate to a thickness of between about 100-200 nm.

2. A method for coating an outer surface of a metal alloy substrate with diamond-like carbon comprising:

providing a substrate comprised of a metal alloy selected from the group consisting of cobalt, nickel, titanium, zirconium, chromium, molybdenum, tungsten, platinum, palladium, and combinations thereof;

exposing said substrate to a vacuum of at least about 10^-5 torr;

heating said substrate to a first temperature of about 300°

C. (149°

F.) or, if said metal alloy is temperature sensitive, to a highest temperature acceptable for said metal alloy;

depositing an intermediate material selected from the group consisting of silicon and germanium onto said substrate in an amount sufficient to form an intermetallic bonding layer at said outer surface of said substrate cohesively bonded to an outer interlayer of said intermediate material;

substantially simultaneously bombarding said intermediate material with a first energetic beam of ions at a first energy, a first ion arrival ratio, and for a first amount of time sufficient to form said intermetallic bonding layer cohesively bonded to said interlayer;

condensing a diamond-like carbon precursor onto said interlayer at a second temperature and for a second amount of time sufficient to form a film of precursor molecules on said interlayer;

substantially simultaneously bombarding said diamond-like carbon precursor with a second energetic beam of ions at a second energy, a second ion arrival ratio, and for a third amount of time sufficient to form a carbide bonding layer cohesively bonded to a coating of diamond-like carbon.

5. The method of claim 2 wherein said second beam of ions comprises nitrogen ions.

7. The method of claim 2 wherein said first energy and said second energy are between about 10-30 keV.

9. The method of claim 2 wherein said second temperature is about 80°

C. (26°

F.).

12. The method of claim 2 wherein said intermediate material is deposited onto said substrate to a thickness of between about 100-200 nm.

14. A method for making an orthopaedic implant comprising an outer surface of a metal alloy substrate in frictional contact with an ultra-high molecular weight polyethylene component, said method comprising the steps of:

providing an orthopaedic component comprising a metal alloy substrate selected from the group consisting of cobalt, nickel, titanium, zirconium, chromium, molybdenum, tungsten, platinum, palladium, and combinations thereof;

exposing said substrate to a vacuum of at least about 10^-5 torr;

heating said substrate to a first temperature of about 300°

C. (149°

F.) or, if said metal alloy is temperature sensitive, to a highest temperature acceptable for said metal alloy;

depositing an intermediate material selected from the group consisting of silicon and germanium onto said substrate in an amount sufficient to form an intermetallic bonding layer at said outer surface of said substrate cohesively bonded to an outer interlayer of said intermediate material;

substantially simultaneously bombarding said intermediate material with a first energetic beam of ions at a first energy, a first ion arrival ratio, and for a first amount of time sufficient to form said intermetallic bonding layer cohesively bonded to said interlayer;

condensing a diamond-like carbon precursor onto said interlayer at a second temperature and for a second amount of time sufficient to form a film of precursor molecules on said interlayer;

substantially simultaneously bombarding said diamond-like carbon precursor with a second energetic beam of ions at a second energy, a second ion arrival ratio, and for a third amount of time sufficient to form a carbide bonding layer cohesively bonded to a coating of diamond-like carbon.