Composition for the detection of electrophilic gases and methods of use thereof

• US 5,783,110 A
• Filed: 04/17/1997
• Issued: 07/21/1998
• Est. Priority Date: 04/17/1997
• Status: Expired due to Fees

• Current Assignee: R-Fax Technologies Incorporated
• Original Assignee: R-TECT, Inc.
• Inventors: Walsh, Shawn, Verdicchio, Robert J., Kaiser, Stewart R.
• Primary Examiner(s): Anthony, Joseph D.
• Application Number:
  US08/837,355
• Time in Patent Office: 460 Days
• Field of Search: 252/68, 252/194, 252/184, 252/189, 252/192, 252/315.1, 252/315.2, 252/315.3, 252/960, 252/961, 252/963, 252/964, 62/125, 73/40, 73/40.7
• US Class Current: 516/102
• CPC Class Codes: B01J 13/0052 Preparation of gels
• CPC Class Codes: G01M 3/042 by using materials which expand, contract, disintegrate, or decompose in contact with a fluid G01M3/12 takes precedence
• CPC Class Codes: G01M 3/146 for containers, e.g. radiators
• CPC Class Codes: G01M 3/148 for radiators
• CPC Class Codes: Y10S 252/964 Leak detection

Abstract

There is provided a composition for the detection of an electrophilic gas, such as chlorodifluoromethane or carbon dioxide, which comprises a Lewis base capable of removing a proton from the gas or reacting therewith in a similar electrophilic manner; a dye capable of visibly indicating a color change on protonation or deprotonation; a solvent for the dye, the base and the gas; and a rheology modifier capable of producing a non-newtonian gel of all of these components which is sufficiently translucent to permit visual detection of change of color of the dye and of sufficient pseudoplasticity/thixotropy to provide adhesion to vertical and horizontal surfaces.

Claims

1. A gel composition for the detection of an electrophilic gas consisting essentially of

a) a Lewis base capable of electrophilic reaction with said gas,

b) a dye capable of visibly indicating a color change on protonation or deprotonation,

c) a solvent for said dye, said base and said gas, selected from the group consisting of alkanols, arylalkanols, alkyl halides, alkyl ketones, alkylamines, aralkylamines, alkyl esters of alkanoic acids and dimethylsulfoxide,

d) a rheology modifier capable of producing a non-newtonian gel of components (a)+(b)+(c)+(d) which is sufficiently translucent to permit visual detection of change of color of (b) and of sufficient pseudoplasticity/thixotropy to provide adhesion to vertical and horizontal surfaces.

2. The composition of claim 1 wherein the Lewis base is present in sufficient amount to bring the pH of the gel to between 6.9 and 14.

3. The composition of claim 1 wherein the Lewis base is selected from the group consisting of alkali- and alkaline earth- metal hydroxides, alkoxides and carbonates;

amines;

quaternary ammonium hydroxides, alkoxyamines, and hydroxylalkylamines.

4. The composition of claim 1 wherein the alkyl moieties are selected from the group consisting of straight chain-, branch chain- and cyclic- moieties.

5. The composition of claim 1 wherein the alkanols and alkylamines are selected from the group consisting of primary, secondary and tertiary alkanols and alkylamines.

6. The composition of claim 1 wherein the solvent is selected from the group consisting of dimethylsulfoxide, water, tetrahydrofuran, acetone, ethyl acetate and methanol.

7. The composition of claim 1 wherein the solvent is utilized in a range relative to the sum of (a) and (b) of between 1 and 99 parts by volume per part by weight of (a)+(b).

8. The composition of claim 1 wherein the rheology modifier is selected from the group consisting of hydroxyalkylcellulose, cellulosic semisynthetic polymers, polyvinyl alcohols, carbopols, alginates, natural gums, polyvinylpyrrolidone , alkyd resins and polyacrylates.

9. The composition of claim 1 wherein the solvent is dimethylsulfoxide.

10. The composition of claim 1 wherein the Lewis base is sodium hydroxide.

11. The composition of claim 1 wherein the rheology modifier is hydroxy ethyl cellulose, polyvinylalcohol or sodium alginate.

12. A coating of a composition of claim 1 when located on a conduit for said gas.

13. The coating of claim 12 additionally comprising a sprayable, film forming topcoat composition settable at between about 0°

-about 30°

C. wherein the film is sufficiently translucent to permit visual detection of change of color of (b).

14. A gel composition for the detection of an electrophilic gas consisting essentially of sodium hydroxide, dimethyl sulfoxide, and a member selected from the group consisting of hydroxyethyl cellulose, polyvinylalcohol and sodium alginate, and a dye capable of visibly indicating a color change on protonation or deprotonation.

15. By A coating of a composition of claim 14 when located on a conduit for said gas.

16. The coating of claim 15 additionally comprising a sprayable film forming topcoat composition settable at between about 0°

and 30°

C. wherein the film is sufficiently translucent to permit visual detection of a color change of said dye.