Method for making an optical film

• US 5,783,120 A
• Filed: 02/29/1996
• Issued: 07/21/1998
• Est. Priority Date: 02/29/1996
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Inventors: Weber, Michael F., Ouderkirk, Andrew J., Nevitt, Timothy J., Stover, Carl A., Allen, Richard C., Majumdar, Biswaroop, Carlson, Lockwood W., Kotz, Arthur L.
• Primary Examiner(s): Vargot, Mathieu D.
• Application Number:
  US08/610,109
• Time in Patent Office: 873 Days
• Field of Search: 264/1.34, 264/1.7, 264/108, 264/1.9, 264/2.7, 264/288.4, 264/290.2
• US Class Current: 264/1.34
• CPC Class Codes: G02B 1/04 made of organic materials, e.g. plastics G02B1/08 takes precedence
• CPC Class Codes: G02B 5/3008 comprising dielectric particles, e.g. birefringent crystals embedded in a matrix
• CPC Class Codes: G02B 5/3083 Birefringent or phase retarding elements G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001

Abstract

An optical film is provided which includes a disperse phase of polymeric particles disposed within a continuous birefringent matrix. The film is oriented, typically by stretching, in one or more directions. The size and shape of the disperse phase particles, the volume fraction of the disperse phase, the film thickness, and the amount of orientation are chosen to attain a desired degree of diffuse reflection and total transmission of electromagnetic radiation of a desired wavelength in the resulting film.

Claims

1. A method for producing an optical body, comprising the steps of:

providing a composition comprising a continuous phase having a birefringence of at least about 0.05 and a disperse phase, wherein the index of refraction of at least one of the continuous and disperse phases is adjustable by orientation; and

orienting the composition until the diffuse reflectivity of the composition along at least one axis for at least one polarization of electromagnetic radiation is greater than about 30% and the indices of refraction of the first and second phases differ by more than about 0.05 along a first of three mutually orthogonal axes but differ by less than about 0.05 along a second of three mutually orthogonal axes.

2. The method of claim 1, wherein the birefringence of the continuous phase is at least about 0.1.

3. The method of claim 1, wherein the birefringence of the continuous phase is at least about 0.15.

4. The method of claim 1, wherein the birefringence of the continuous phase is at least about 0.2.

5. The method of claim 1, wherein the composition is oriented until the indices of refraction of the first and second phases differ by more than about 0.1 along the first of three mutually orthogonal axes.

6. The method of claim 1, wherein the composition is oriented until the indices of refraction of the first and second phases differ by more than about 0.15 along the first of three mutually orthogonal axes.

7. The method of claim 1, wherein the composition is oriented until the indices of refraction of the first and second phases differ by more than about 0.2 along the first of three mutually orthogonal axes.

8. The method of claim 1, wherein the composition is oriented until the indices of refraction of the first and second phases differ by less than about 0.03 along the second of three mutually orthogonal axes.

9. The method of claim 1, wherein the composition is oriented until the indices of refraction of the first and second phases differ by less than about 0.01 along the second of three mutually orthogonal axes.

10. The method of claim 1, wherein the composition is oriented until the diffuse reflectivity of the composition is greater than about 50%.

33. The method of claim 1, wherein the composition is extruded into a film before it is oriented.

34. The method of claim 1, wherein the composition is extruded into a film before it is oriented.

11. A method for producing an optical body, comprising the steps of:

providing a first resin whose index of refraction is adjustable along a first of three mutually orthogonal axes;

providing a second resin;

incorporating the second resin as a disperse phase within a matrix of the first resin; and

orienting the first resin along the first axis until the indices of refraction of the first and second resins are substantially mismatched along the first axis, but are substantially matched along a second of the three mutually orthogonal axes, and the diffuse reflectivity for said matrix and said disperse phase taken together along at least one axis for at least one polarization of electromagnetic radiation is at least about 30%.

12. The method of claim 11, wherein the optical body is a film, and wherein the second of three mutually orthogonal axes is perpendicular to the plane of the film.

13. The method of claim 11, wherein the second resin is incorporated into the matrix before it is oriented.

14. The method of claim 11, wherein the first resin is uniaxially oriented.

15. The method of claim 11, wherein the first resin is biaxially oriented.

16. The method of claim 11, wherein the first resin is stretched to a stretch ratio of at least about 2.

17. The method of claim 11, wherein the first resin is stretched to a stretch ratio of at least about 4.

18. The method of claim 11, wherein the first resin is stretched to a stretch ratio of at least about 6.

19. The method of claim 11, wherein the first and second resins are thermoplastic polymers.

20. The method of claim 11, wherein at least one of the first and second resins comprise a polymer selected from the group consisting of polyethylene naphthalate, polymethylmethacrylate, syndiotactic polystyrene, and the alkyl derivatives of these polymers.

21. The method of claim 11, wherein the dispersed phase is randomly dispersed throughout the matrix, and wherein the matrix is oriented in at least one direction.

22. The method of claim 11, wherein the dispersed phase comprises a plurality of essentially rod-like masses after orientation.

23. The method of claim 11, wherein the dispersed phase comprises a plurality of particles which are essentially rod-like in shape prior to orientation.

32. The method of claim 11, wherein the optical body is a film.

24. A method for producing an optical body, comprising the steps of:

providing a first resin whose index of refraction is adjustable along a first of three mutually orthogonal axes;

providing a second resin;

incorporating the second resin as a disperse phase within a matrix of the first resin; and

orienting the first resin along the first axis until (i) the absolute value of the difference in index of refraction of said first and second resins is Δ

n₁ along a first axis and Δ

n₂ along a second axis orthogonal to said first axis, (ii) the absolute value of the difference between Δ

n₁ and Δ

n₂ is at least about 0.05, and (iii) the diffuse reflectivity of said first and second resins taken together along at least one axis for at least one polarization of electromagnetic radiation is at least about 30%.

25. The method of claim 24, wherein wherein the absolute value of the difference between Δ

n₁ and Δ

n₂ is at least about 0.1.

26. The method of claim 24, wherein said matrix has a larger birefringence than said disperse phase.

27. The method of claim 26, wherein the birefringence of said matrix is at least 0.02 greater than the birefringence of said disperse phase.

28. The method of claim 26, wherein the birefringence of said matrix is at least 0.05 greater than the birefringence of said disperse phase.

31. The method of claim 24, wherein the optical body is a film.

35. The method of claim 24, wherein the first resin is extruded into a film before it is oriented.

40. The method of claim 24, wherein the first resin is oriented until the diffuse reflectivity of the first and second resins taken together is greater than about 30% for at least one polarization of visible light.

29. A method for producing an optical body, comprising the steps of:

providing a first phase having a birefringence of at least about 0.05 whose index of refraction is adjustable along a first of three mutually orthogonal axes;

providing a second phase which is discontinuous along at least two of any three mutually orthogonal axes;

incorporating the second phase into the first phase; and

orienting the first phase along the first axis until (i) the absolute value of the difference in index of refraction of said first and second phases is Δ

n₁ along a first axis and Δ

n₂ along a second axis orthogonal to said first axis, (ii) the absolute value of the difference between Δ

n₁ and Δ

n₂ is at least about 0.05, and (iii) the diffuse reflectivity of said first and second phases taken together along at least one axis for at least one polarization of electromagnetic radiation is at least about 30%.

30. The method of claim 29, wherein the optical body is a film.

41. The method of claim 29, wherein the first phase is oriented until the diffuse reflectivity of the first and second phases taken together is greater than about 30% for at least one polarization of visible light.

36. A method for producing an optical body, comprising the steps of:

providing a composition comprising a continuous phase having a birefringence of at least about 0.05, and a disperse phase which is randomly aligned within the continuous phase, wherein the index of refraction of at least one of the continuous and disperse phases is adjustable by orientation; and

orienting the composition until the indices of refraction of the first and second phases differ by more than about 0.05 along a first of three mutually orthogonal axes but differ by less than about 0.05 along a second of three mutually orthogonal axes, and the diffuse reflectivity of the composition along at least one axis for at least one polarization of electromagnetic radiation is greater than about 30%.

37. The method of claim 36, wherein the composition is oriented until the diffuse reflectivity of the composition is greater than about 30% for at least one polarization of visible light.

38. A method for producing an optical body, comprising the steps of:

providing a composition comprising (i) a first resin whose index of refraction is adjustable along a first of three mutually orthogonal axes, and (ii) a second resin which is randomly oriented within the first resin; and

orienting the first resin along the first axis until (i) the absolute value of the difference in index of refraction of said first and second resins is Δ

n₁ along a first axis and Δ

n₂ along a second axis orthogonal to said first axis, (ii) the absolute value of the difference between Δ

n₁ and Δ

n₂ is at least about 0.05, and (iii) the diffuse reflectivity of said first and second phases taken together along at least one axis for at least one polarization of electromagnetic radiation is at least about 30%.

39. The method of claim 38, wherein the diffuse reflectivity of said first and second resins taken together along at least one axis for at least one polarization of visible light is at least about 30%.

42. A method for producing an optical body which diffusely reflects electromagnetic radiation of wavelength λ

having a first polarization and which specularly transmits electromagnetic radiation of wavelength λ

having a second polarization, comprising the steps of;

providing a composition comprising a continuous phase of strain-induced birefringent material and a disperse phase disposed within the continuous phase, wherein the disperse phase comprises a plurality of particles that are larger than about 2 λ

in a first dimension and are larger than about λ

/30 but smaller than about λ

in a second and third dimension; and

orienting the composition until the indices of refraction of the continuous and disperse phases differ by more than about 0.05 for electromagnetic radiation of wavelength λ

polarized along a first of three mutually orthogonal axes but differ by less than about 0.05 for electromagnetic radiation of wavelegnth λ

polarized along a second of three mutually orthogonal axes, and the diffuse reflectivity of the composition along at least one axis for at least one polarization of electromagnetic radiation of wavelegnth λ

is at least about 30%.

43. The method of claim 42, wherein the composition is oriented until the diffuse reflectivity of the composition toward the first polarization electromagnetic radiation of wavelength λ

is greater than about 50%.

44. The method of claim 42, wherein the plurality of particles are larger than about 4 λ

in the first dimension.

45. The method of claim 42, wherein the plurality of particles are smaller than about 0.5 λ

in at least one of the second and third dimensions.

46. The method of claim 42, wherein the plurality of particles are smaller than about 0.5 λ

in both of the second and third dimensions.

47. The method of claim 42, wherein λ

is in the visible region of the spectrum.

48. The method of claim 42, wherein the continuous phase and the disperse phase are diverse thermoplastic polymers.