Thin-film fiber optic hydrogen and temperature sensor system

• US 5,783,152 A
• Filed: 03/24/1997
• Issued: 07/21/1998
• Est. Priority Date: 03/24/1997
• Status: Expired due to Fees

• Current Assignee: Westinghouse Savannah River Company
• Original Assignee: United States Department of Energy (Government of the United States of America)
• Inventors: Nave, Stanley E.
• Primary Examiner(s): SNAY, JEFFREY R
• Application Number:
  US08/824,063
• Time in Patent Office: 484 Days
• Field of Search: 422/82.05, 422/82.06, 422/82.09, 422/82.12, 436/144, 436/164
• US Class Current: 422/82.06
• CPC Class Codes: G01N 2021/7773 Reflection
• CPC Class Codes: G01N 21/783 for analysing gases
• CPC Class Codes: G02F 2202/34 Metal hydrides materials
• CPC Class Codes: Y10T 436/22 Hydrogen, per se

Abstract

The invention discloses a sensor probe device for monitoring of hydrogen gas concentrations and temperatures by the same sensor probe. The sensor probe is constructed using thin-film deposition methods for the placement of a multitude of layers of materials sensitive to hydrogen concentrations and temperature on the end of a light transparent lens located within the sensor probe. The end of the lens within the sensor probe contains a lens containing a layer of hydrogen permeable material which excludes other reactive gases, a layer of reflective metal material that forms a metal hydride upon absorbing hydrogen, and a layer of semi-conducting solid that is transparent above a temperature dependent minimum wavelength for temperature detection. The three layers of materials are located at the distal end of the lens located within the sensor probe. The lens focuses light generated by broad-band light generator and connected by fiber-optics to the sensor probe, onto a reflective metal material layer, which passes through the semi-conducting solid layer, onto two optical fibers located at the base of the sensor probe. The reflected light is transmitted over fiberoptic cables to a spectrometer and system controller. The absence of electrical signals and electrical wires in the sensor probe provides for an elimination of the potential for spark sources when monitoring in hydrogen rich environments, and provides a sensor free from electrical interferences.

Claims

1. A sensor system capable of measuring hydrogen concentrations and temperatures comprising:

a sensor probe having a rigid housing with one distal open end;

a light transparent lens inside said sensor probe with one end oriented toward the distal open end of the sensor probe and the other end of said lens oriented toward the proximal closed end of the sensor probe;

a sem-conducting solid that is transparent above a temperature dependent minimum wavelength, forming a layer on the distal end of said lens inside said sensor probe;

a reflective metal material that forms a metal hydride upon absorbing hydrogen, forming a layer on top of and contiguous with said semi-conducting solid layer inside said sensor probe;

a coating of hydrogen permeable material on top of, distal, and contiguous with said reflective metal material layer within said sensor probe;

a rigid connector at the proximal end of said sensor probe;

first and second optical fibers positioned at a focal point of the lens inside said sensor probe by a fiber-optic terminator and connector at the proximal end of said sensor probe;

a means for generating light comprising a broad-band light source;

a fiber-optic cable comprising said first and second optical fibers, said first optical fiber connecting the sensor probe to said source of broad-band light;

a controlling processor;

a means for analysis of light information from said sensor probe comprising a spectrometer; and

a means for transmission of light from said reflective metal material layer and said semi-conducting solid layer to said means for analysis.

2. The sensor system capable of measuring hydrogen concentrations and temperatures as described in claim 1, wherein said sensor probe is constructed of a swagelock connector with one distal end open and the other proximal end closed with a female connector.

3. The sensor system capable of measuring hydrogen concentrations and temperatures as described in claim 1, wherein said lens is composed of quartz.

4. The sensor system capable of measuring hydrogen concentrations and temperatures as described in claim 1, wherein said pair of optical fibers extend close to and in alignment with said lens inside said sensor probe.

5. The sensor system capable of measuring hydrogen concentrations and temperatures as described in claim 1, wherein said semi-conducting solid that is transparent above a temperature dependent minimum wavelength comprises a zinc selenide temperature sensor layer on the distal end of said light transparent lens, said temperature sensor layer being transparent to broad-based light above a minimum wavelength.

6. The sensor system capable of measuring hydrogen concentrations and temperatures as described in claim 1, wherein said coating is selected from the group consisting of sol-gel glass and teflon, said coating being located on top of and contiguous with said reflective metal material layer inside the distal end of said sensor probe.

7. The sensor system capable of measuring hydrogen concentrations and temperatures as described in claim 1, said rigid connector comprising a female connector of a swagelock reducer which connects to said fiber-optic terminator and connector at the proximal end of said sensor probe.

8. The sensor system capable of measuring hydrogen concentrations and temperatures as described in claim 1, said means for generating light comprising a quartz-halogen light source.

9. The sensor system capable of measuring hydrogen concentrations and temperatures as described in claim 1, said controlling processor including an analog-to-digital converter.

10. The sensor system capable of measuring hydrogen concentrations and temperatures as described in claim 1, said means for generating light comprising a tungsten-halogen light source, said light source being connected by said first optical fiber to said sensor probe.

11. The sensor system capable of measuring hydrogen concentrations and temperatures as described in claim 1, wherein said reflective metal material that forms a metal hydride upon absorbing hydrogen comprises a palladium alloy film layer on top of and contiguous with said semi-conducting solid layer inside the distal end of said sensor probe.

12. The sensor system as described in claim 11, wherein said palladium alloy layer is reflective to light passing through said lens and through said semi-conducting solid layer inside said sensor probe.

13. A sensor device for use in measuring hydrogen concentrations and temperatures comprising:

a sensor probe having a rigid housing with one distal open end;

a light transparent lens inside said sensor probe with one end oriented toward the distal open end of the sensor probe and the other end of said lens oriented toward the proximal closed end of the sensor probe;

a semi-conducting solid that is transparent above a temperature dependent minimum wavelength, forming a layer on the distal end of said lens inside said sensor probe;

a reflective metal material that forms a metal hydride upon absorbing hydrogen, forming a layer on top of and contiguous with said semi-conducting solid layer inside said sensor probe;

a coating of hydrogen permeable material on top of, distal, and contiguous with said reflective metal material layer within said sensor probe;

a rigid connector at the proximal end of said sensor probe; and

a pair of optical fibers positioned at a focal point of the lens inside said sensor probe by a fiber-optic terminator and connector at the proximal end of said sensor probe.