Thermally processable imaging element

• US 5,783,380 A
• Filed: 09/24/1996
• Issued: 07/21/1998
• Est. Priority Date: 09/24/1996
• Status: Expired due to Fees

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Melpolder, Sharon Marilyn, Smith, Dennis Edward, Muehlbauer, John Leonard
• Primary Examiner(s): Chea, Thorl
• Application Number:
  US08/719,105
• Time in Patent Office: 665 Days
• Field of Search: 430/617, 430/619, 430/523, 430/545, 430/950, 430/517, 430/519, 430/521
• US Class Current: 430/619
• CPC Class Codes: B41M 2205/40 Cover layers; Layers separated from substrate by imaging layer; Protective layers; Layers applied before imaging protective layers applied after imaging B41M7/00
• CPC Class Codes: B41M 5/42 Intermediate, backcoat, or covering layers B41M5/405 takes precedence; multilayer thermal transfer systems in general B41M5/38214
• CPC Class Codes: B41M 5/423 characterised by non-macromolecular compounds, e.g. waxes
• CPC Class Codes: B41M 5/426 characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
• CPC Class Codes: B41M 5/44 characterised by the macromolecular compounds
• CPC Class Codes: G03C 1/49872 Aspects relating to non-photosensitive layers, e.g. intermediate protective layers
• CPC Class Codes: Y10S 430/151 Matting or other surface reflectivity altering material

Abstract

A thermally processable imaging element is comprised of:

(1) a support;

(2) a thermographic or photothermographic imaging layer on one side of the support;

(3) a transparent protective layer comprising:

(A) a film forming binder;

(B) a dye in said protective layer in an amount sufficient to impart a pre-selected color thereto; and

(C) matte particles, the color of which substantially matches the color of the protective layer.

Claims

1. A thermally processable imaging element comprising:

(1) a support;

(2) a thermographic or photothermographic imaging layer on one side of the support;

(3) a protective layer overlying the image-forming layer;

said protective layer comprising;

(A) a film forming binder;

(B) a dye dispersed throughout said protective layer in an amount sufficient to impart a pre-selected color thereto; and

(C) matte particles, the color of which substantially matches the color of the protective layer.

2. A thermally processable imaging element according to claim 1, wherein the film forming binder comprises crosslinked polyvinyl alcohol, gelatin, or poly(silicic acid).

3. A thermally processable imaging element according to claim 1, wherein the dye dispersed in the protective layer is Victoria Pure Blue BO, Victoria Brilliant Blue G, Seiva Blue WS, Aniline Blue, Page Blue G-90 or Methylene Blue.

4. A thermally processable imaging element according to claim 1, wherein the amount of dye dispersed in the protective layer is about 1 to about 100 mg/m².

5. A thermally processable imaging element according to claim 1, wherein the matte particles comprise a hydrophobic polymer containing a hydrophobic dye.

6. A thermally processable imaging element according to claim 5, wherein the hydrophobic polymer is selected from polymeric esters of acrylic and methacrylic acid.

7. A thermally processable imaging element according to claim 5, wherein the hydrophobic dye is selected from the following dye classes:

anthraquinone, formazan, metal-complexed formazans, azo, metal-complexed azo, phthalocyanine, metalophthalocyanine, merocyanine, oxonol, cyanine, hemicyanine, indigo, metal dithiolene, squarylium, methine, azamethine, azacyanine, diazacyanine, oxazine, phenazine, thioxazine, rhodamine, fluoran, pyryllium, thiapyryllium, selenapyryllium, telluropyryllium, benzoquinone, anthrapyridone, stilbene, triphenylmethane, oxoindolizine, indolizine, prophyrazine, thioindigo, croconate, styryl, azastyryl and perlene.

8. A thermally processable imaging element according to claim 5, wherein the dye is present in the matte particles in an amount of about 0.01 to about 20% by weight, based on the weight of the polymer.

9. A thermally processable imaging element according to claim 1, wherein the protective layer is an overcoat layer overlying the imaging layer.

10. A thermally processable imaging element according to claim 1, wherein the protective layer is a backing layer.

11. A thermally processable imaging element comprising:

(1) a support;

(2) a thermographic or photothermographic imaging layer on one side of the support;

(3) a protective layer;

said protective layer comprising;

(A) a hydrophilic film forming binder;

(B) a water-soluble dye dispersed throughout said protective layer in an amount sufficient to impart a pre-selected color thereto; and

(C) hydrophobic matte particles comprising a dye in an amount sufficient that the color of the matte particles substantially matches the color of the protective layer.

12. A thermally processable imaging element according to claim 11, wherein the film forming binder comprises crosslinked polyvinyl alcohol, gelatin, or poly(silicic acid).

13. A thermally processable imaging element according to claim 11, wherein the dye dispersed in the protective layer is Victoria Pure Blue BO, Victoria Brilliant Blue G, Serva Blue WS, Aniline Blue, Page Blue G-90 or Methylene Blue.

14. A thermally processable imaging element according to claim 11, wherein the amount of dye dispersed in the protective layer is about 1 to about 100 mg/m².

15. A thermally processable imaging element according to claim 11, wherein the hydrophobic polymer is selected from polymeric esters of acrylic and methacrylic acid.

16. A thermally processable imaging element according to claim 11, wherein the hydrophobic dye is selected from the following dye classes:

anthraquinone, formazan, metal-complexed formazans, azo, metal-complexed azo, phthalocyanine, metalophthalocyanine, merocyanine, oxonol, cyanine, hemicyanine, indigo, metal dithiolene, squarylium, methine, azamethine, azacyanine, diazacyanine, oxazine, phenazine, thioxazine, rhodamine, fluoran, pyryllium, thiapyryllium, selenapyryllium, telluropyryllium, benzoquinone, anthrapyridone, stilbene, triphenylmethane, oxoindolizine, indolizine, prophyrazine, thioindigo, croconate, styryl, azastyryl and perlene.

17. A thermally processable imaging element according to claim 11, wherein the dye is present in the matte particles in an amount of about 0.01 to about 20% by weight, based on the weight of the polymer.

18. A thermally processable imaging element according to claim 11, wherein the protective layer is an overcoat layer overlying the imaging layer.

19. A thermally processable imaging element according to claim 11, wherein the protective layer is a backing layer.