Amphoteric agents as modifiers of lamellar phases of detergents or liquid or pasty cosmetic compositions

• US 5,783,533 A
• Filed: 03/22/1996
• Issued: 07/21/1998
• Est. Priority Date: 03/23/1995
• Status: Expired due to Fees

• Current Assignee: Coatex SAS (Arkema)
• Original Assignee: Coatex S.A.
• Inventors: Suau, Jean-Marc, Kensicher, Yves
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): Douyon, Lorna M.
• Application Number:
  US08/620,360
• Time in Patent Office: 851 Days
• Field of Search: 510/475, 510/476, 510/119, 510/123, 510/108, 510/124, 510/405, 424/70.1, 514/844
• US Class Current: 510/119
• CPC Class Codes: A61K 2800/5428 amphoteric or zwitterionic
• CPC Class Codes: A61K 8/0295 Liquid crystals
• CPC Class Codes: A61K 8/042 Gels
• CPC Class Codes: A61K 8/8152 Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/8158 Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
• CPC Class Codes: A61K 8/8182 Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair
• CPC Class Codes: C11D 17/0026 Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
• CPC Class Codes: C11D 3/3796 Amphoteric polymers or zwitterionic polymers

Abstract

Amphoteric copolymers of general formula:

(X).sub.a --(Y).sub.b --(Z).sub.c

in which

X represents a monomer type with anionic charge;

Y represents a monomer type with nonionic character;

Z represents a monomer type with cationic charge;

a is the weight % based on the total weight of monomers of X, and is between 95 and 15;

b is the weight % based on the total weight of monomers of Y, and is between 0 and 65;

c is the weight % based on the total weight of monomers of Z, and is between 5 and 60

as rheological modifiers of lamellar phases of detergent or cosmetic (liquid or pasty) compositions are disclosed. Liquid washing detergent and liquid shampoos containing the amphoteric copolymers are also disclosed.

Claims

1. A method for modifying the rheological properties of a detergent or cosmetic composition containing a lamellar phase, said method comprising adding to said composition an amphoteric copolymer comprising at least a first type of monomeric unit being derived from one or more ethylenically unsaturated monomers having an anionic charge, said second type of monomeric unit being derived from one or more ethylenically unsaturated monomers having a cationic charge, with one at least of said cationic charged monomers having a surface-active structure, and optionally comprising a third type of monomeric unit derived from one or more ethylenically unsaturated nonionic monomers, and

wherein said copolymer has the formula (I):

##STR10## in which;

R₁ is H or COOH,

R₂ is H or CH₃,

R₃ is a group having at least an acidic function which may be totally or partially neutralized, and

a is a number such that the weight percentage of the anionic monomeric unit, based on the total weight of all monomers is, limits included, between 95 and 15;

R₄ is ##STR11## in which R₄ '"'"' is an alkyl or alkoxy radical having 1 to 4 carbon atoms,

R₄ " is H or alkyl radical having 1 to 4 carbon atoms,

R₄ '"'"'" is an alkyl radical having 1 to 4 carbon atoms,

R₅ is H or CH₃, and

b is a number such that the weight percentage of the nonionic monomeric unit, based on the total weight of all monomers is, limits included, between 0 and 65;

A is a monomeric unit derived from a polymerizable unsaturated radical selected from the group consisting of acrylic, methacrylic, maleic, itaconic, crotonic, and vinylphthalic esters, maleic, itaconic, vinylphthalic hemiesters, acrylurethane, methacrylurethane, α

,α

-dimethyl-m-isopropenyl benzylurethane, allylurethane, allylic ethers, substituted or unsubstituted acrylamides, substituted or unsubstituted methacrylamides, and vinyl groups;

R₆ is H or CH₃,

n=2 to 30,

R₇ is an alkyl group having 1 to 4 carbon atoms,

Z is N or S,

X is a sulfate or halogen counter-ion and when Z is N;

R₈ is an alkyl chain having 8 to 22 carbon atoms or a linking group to another polymeric chain of formula (I) having the following formula;

##STR12## with n=2 to 30, where A has the same meaning as above and the two bonds from A are connected to two monomer units in another polymer chain of formula (I), and

R₉ is an alkyl chain having 8 to 22 carbon atoms and when Z is S;

R₈ does not exist

R₉ is an alkyl chain having 8 to 22 carbon atoms, and c'"'"' is a number such that the weight percentage, based on the total weight of all monomers, of the cationic charged monomer having a surface-active structure, is, limits included, between 5 and 60 with c'"'"'+c"=c;

c representing the weight percentage of all cationic monomers and varying between 5 and 60, limits included; and

B is a cationic monomeric unit,

c" is a number such that the weight percentage, based on the total weight of all monomers, of the cationic monomer which does not contain a surface-active structure is, limits included, between 0 and 55.

2. The method of claim 1 wherein said detergent or cosmetic compositions are liquid or pasty.

3. The method of claim 1 wherein said lamellar phase of said cosmetic or detergent composition is an anionic lamellar phase, a cationic lamellar phase, or a mixture of an anionic lamellar phase and a cationic lamellar phase.

4. The method of claim 1, wherein said rheological modification is a fluidification of a detergent or cosmetic composition

wherein a is, limits included, between 80 and 25;

b is, limits included, between 20 and 50;

B is selected from the group consisting of trimethylaminoethyl acrylate chloride, trimethylaminoethyl methacrylate chloride, trimethylaminoethyl acrylate sulfate, trimethylaminoethyl methacrylate sulfate, trimethylaminopropyl acrylamide chloride, trimethylaminopropyl methacrylamide chloride, trimethylaminopropyl acrylamide sulfate, and trimethylaminopropyl methacrylamide sulfate, and said copolymer has a specific viscosity between 0.3 and 3.0.

5. The method of claim 4, wherein said specific viscosity is between 0.4 and 2.0.

6. The method of claim 4, wherein c'"'"' is, limits included, between 10 and 35, and c is, limits included, between 10 and 35.

7. The method of claim 4, wherein C" is, limits included, between 1 and 55.

8. The method of claim 1, wherein said rheological modification is a thickening of a detergent or cosmetic composition and wherein

B is a cationic monomeric unit derived from a monomer selected from the group consisting of trimethylaminoethyl acrylate chloride, trimethylaminoethyl methacrylate chloride, trimethylaminoethyl acrylate sulfate, trimethylaminoethyl methacrylate sulfate, trimethylaminopropyl acrylamide chloride, trimethylaminopropyl methacrylamide chloride, trimethylaminopropyl acrylamide sulfate, and trimethylaminopropyl methacrylamide sulfate, and said copolymer has a specific viscosity greater than 3.0.

9. The method of claim 8, wherein said specific viscosity is greater than 10.

10. The method of claim 8, wherein c'"'"' is, limits included, between 10 and 35, and c is, limits included, between 10 and 35.

11. The method of claim 8, wherein C" is, limits included, between 1 and 55.

12. The method of claim 1, wherein said rheological modification is an improvement of compatibility of a detergent or cosmetic composition containing a mixture of anionic and cationic lamellar phases and wherein

B is a cationic monomeric unit derived from a monomer selected from the group consisting of trimethylaminoethyl acrylate chloride, trimethylaminoethyl methacrylate chloride, trimethylaminoethyl acrylate sulfate, trimethylaminoethyl methacrylate sulfate, trimethylaminopropyl acrylamide chloride, trimethylaminopropyl methacrylamide chloride, trimethylaminopropyl acrylamide sulfate, and trimethylaminopropyl methacrylamide sulfate.

13. The method of claim 12, wherein c'"'"' is, limits included, between 10 and 35, and c is, limits included, between 10 and 35.

14. The method of claim 12, wherein C" is, limits included, between 1 and 55.

15. The method of claim 1, wherein at least 0.25 dry weight % of said copolymer based on the total weight of said detergent or cosmetic composition is added.

16. A liquid detergent composition, comprising at least 0.2 dry wt. %, based on the total weight of the composition, a rheological modifier, which is an amphoteric copolymer comprising at least a first and a second type of monomeric units with said first type of monomeric unit being derived from one or more ethylenically unsaturated monomers having an anionic charge, said second type of monomeric unit being derived from one or more ethylenically unsaturated monomers having a cationic charge, with one at least of said cationic charged monomers having a surface-active structure, and optionally comprising a third type of monomeric unit derived from one or more ethylenically unsaturated nonionic monomers, and wherein said copolymer has the formula (I):

##STR13## in which;

R₁ is H or COOH,

R₂ is H or CH₃,

R₃ is a group having at least an acidic function which may be totally or partially neutralized, and

a is a number such that the weight percentage of the anionic monomeric unit, based on the total weight of all monomers is, limits included, between 95 and 15;

R₄ is ##STR14## in which R₄ '"'"' is an alkyl or alkoxy radical having 1 to 4 carbon atoms,

R₄ " is H or alkyl radical having 1 to 4 carbon atom,

R₄ '"'"'" is an alkyl radical having 1 to 4 carbon atoms,

R₅ is H or CH₃, and

b is a number such that the weight percentage of the nonionic monomeric unit, based on the total weight of all monomers is, limits included, between 0 and 65;

A is a monomeric unit derived from a polymerizable unsaturated radical selected from the group consisting of acrylic, methacrylic, maleic, itaconic, crotonic, and vinylphthalic esters, maleic, itaconic, vinylphthalic hemiesters, acrylurethane, methacrylurethane, α

, α

-dimethyl-m-isopropenyl benzylurethane, allylurethane, allylic ethers, substituted or unsubstituted acrylamides, substituted or unsubstituted methacrylamides, and vinyl groups;

R₆ is H or CH₃,

n=2 to 30,

R₇ is an alkyl group having 1 to 4 carbon atoms,

Z is N or S,

X is a sulfate or halogen counter-ion and when Z is N;

R₈ is an alkyl chain having 8 to 22 carbon atoms or a linking group to another polymeric chain of formula (I) having the following formula;

##STR15## with n=2 to 30, where A has the same meaning as above and the two bonds from A are connected to two monomer units in another polymeric chain of formula (I), and

R₉ is an alkyl chain having 8 to 22 carbon atoms and when Z is S;

R₈ does not exist

R₉ is an alkyl chain having 8 to 22 carbon atoms, and

c'"'"' is a number such that the weight percentage, based on the total weight of all monomers, of the cationic charged monomer having a surface-active structure is, limits included, between 5 and 60, with c'"'"'+c"=c;

c representing the weight percentage of all cationic monomers and varying between 5 and 60, limits included; and

B is a cationic monomeric unit,

c" is a number such that the weight percentage, based on the total weight of all monomers, of the cationic monomer which does not contain a surface-active structure is, limits included, between 0 and 55.

17. The liquid detergent of claim 16, which is a liquid washing detergent.

18. A liquid or pasty cosmetic composition, comprising at least 0.2 dry wt. %, based on the total weight of the composition, a rheological modifier, which is an amphoteric copolymer comprising at least a first and a second type of monomeric units with said first type of monomeric unit being derived from one or more ethylenically unsaturated monomers having an anionic charge, said second type of monomeric unit being derived from one or more ethylenically unsaturated monomers having a cationic charge, with one at least of said cationic charged monomers having a surface-active structure, and optionally comprising a third type of monomeric unit derived from one or more ethylenically unsaturated nonionic monomers, and wherein said copolymer has the formula (I):

##STR16## in which;

R₁ is H or COOH,

R₂ is H or CH₃,

R₃ is a group having at least an acidic function which may be totally or partially neutralized, and

a is a number such that the weight percentage of the anionic monomeric unit, based on the total weight of all monomers is, limits included, between 95 and 15;

R₄ is ##STR17## in which R₄ '"'"' is an alkyl or alkoxy radical having 1 to 4 carbon atoms,

R₄ " is H or alkyl radical having 1 to 4 carbon atoms,

R₄ '"'"'" is an alkyl radical having 1 to 4 carbon atoms,

R₅ is H or CH₃, and

b is a number such that the weight percentage of the nonionic monomeric unit, based on the total weight of all monomers is, limits included, between 0 and 65;

A is a monomeric unit derived from a polymerizable unsaturated radical selected from the group consisting of acrylic, methacrylic, maleic, itaconic, crotonic, and vinylphthalic esters, maleic, itaconic, vinylphthalic hemiesters, acrylurethane, methacrylurethane, α

, α

-dimethyl-m-isopropenyl benzylurethane, allylurethane, allylic ethers, substituted or unsubstituted acrylamides, substituted or unsubstituted methacrylamides, and vinyl groups;

R₆ is H or CH₃,

n=2 to 30,

R₇ is an alkyl group having 1 to 4 carbon atoms,

Z is N or S,

X is a sulfate or halogen counter-ion and when Z is N;

R₈ is an alkyl chain having 8 to 22 carbon atoms or a linking group to another polymeric chain of formula (I) having the following formula;

##STR18## with n=2 to 30, where A has the same meaning as above and the two bonds from A are connected to two monomer units in another polymeric chain of formula (I), and

R₉ is an alkyl chain having 8 to 22 carbon atoms and when Z is S;

R₈ does not exist

R₉ is an alkyl chain having 8 to 22 carbon atoms, and

c'"'"' is a number such that the weight percentage, based on the total weight of all monomers, of the cationic charged monomer having a surface-active structure is, limits included, between 5 and 60, with c'"'"'+c"=c;

c representing the weight percentage of all cationic monomers and varying between 5 and 60, limits included; and

B is a cationic monomeric unit,

c" is a number such that the weight percentage, based on the total weight of all monomers, of the cationic monomer which does not contain a surface-active structure is, limits included, between 0 and 55.

19. The cosmetic composition of claim 18, which is a shampoo.