Device for converting invisible and visible radiation to visible light and/or UV radiation

• US 5,786,102 A
• Filed: 01/16/1996
• Issued: 07/28/1998
• Est. Priority Date: 01/25/1994
• Status: Expired due to Fees

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Chwalek, James M., Paz-Pujalt, Gustavo R., Chatterjee, Dilip K., Hung, Liang-Sun, Hrycin, Anna L.
• Primary Examiner(s): Speer, Timothy M.
• Application Number:
  US08/585,657
• Time in Patent Office: 924 Days
• Field of Search: 428/688, 428/689, 428/690, 428/691, 428/696, 428/697, 428/432, 252/301.4 F, 252/301.4 H, 252/301.4 R, 250/483.1, 250/484.4, 250/486.1, 250/581, 385/129, 385/130, 385/131, 385/141, 385/142, 359/326, 359/328, 359/332, 427/585
• US Class Current: 428/689
• CPC Class Codes: C09K 11/7772 Halogenides C09K11/7767 takes precedence
• CPC Class Codes: C09K 11/7773 with alkali or alkaline earth metal
• CPC Class Codes: C23C 14/0694 Halides
• CPC Class Codes: F21K 2/005 excited by infrared radiation using up-conversion
• CPC Class Codes: Y10S 430/145 Infrared
• CPC Class Codes: Y10S 430/146 Laser beam

Abstract

An amorphous upconversion phosphor comprising barium fluoride a combination of rare-earth fluorides including yttrium and lanthanum and dopants, and a waveguide thereof on a substrate selected to have a refractive index lower than a thin film of the phosphor material or any other substrate with an appropriate buffer layer of lower refractive index that the film wherein infrared radiation and visible light are converted to ultraviolet and visible light. The amorphous upconversion phosphor is deposited at temperatures low enough to permit integration into semiconductor materials.

Claims

1. An article comprising:

a substrate and a thin amorphous glassy phosphor film consisting essentially of an alkaline earth and a mixture of rare-earth fluorides on the substrate and having an index of refraction greater than the substrate.

2. An article as claimed in claim 1, wherein said glassy phosphor film has a thickness of about 2 μ

m or less.

5. The device of claim 2 further including a buffer layer having an index of refraction selected to be less than the index of refraction of the film.

6. The device of claim 5 wherein the substrate is selected the group consisting of fused silica, barium fluoride, magnesium fluoride, calcium fluoride, strontium fluoride, and lithium fluoride.

7. The device of claim 5 wherein the substrate is a III-V compound semiconductor of elements such as aluminum, gallium, indium, nitrogen, phosphorus, or arsenic or combinations thereof.

3. A device for converting invisible light to visible light, comprising:

a substrate and thin amorphous glassy phosphor film consisting essentially of an alkaline earth fluoride and a mixture of rare-earth fluoride on the substrate and having an index of refraction greater than the substrate and which is selected to convert infrared radiation or visible radiation into ultraviolet and visible radiation.

4. The device of claim 3 wherein the alkaline earth fluoride is barium fluoride and the mixture of rare-earth earth fluorides is selected from the group consisting of yttrium fluoride, ytterbium fluoride, erbium fluoride, thulium fluoride, holmium fluoride, and combinations thereof.

8. A device as claimed in claim 3, wherein said glassy phosphor film has a thickness of about 2 μ

m or less.

9. A device for converting IR or red light into red, green, blue, and/or ultraviolet light comprising:

a) a source of radiation having a wavelength near 645-665 nm or 675-685 nm a substrate and a thin amorphous glassy phosphor film selected so that it can be deposited at less than 240°

C., such film consisting essentially of an alkaline earth fluoride and/or a mixture of rare-earth fluorides on the substrate and having an index of refraction greater than the substrate and which is selected to convert visible radiation into ultraviolet and visible radiation wherein the wavelength of the UV is 350-370 nm, blue light is 450-480 nm, the green light is 500-550 nm, and the red light 630-680; and

b) a source of radiation having a wavelength near 800 to 1100 nm a substrate and a thin amorphous glassy phosphor film consisting essentially of an alkaline earth fluoride, and a mixture of rare-earth fluorides on the substrate and having an index of refraction greater than the substrate and which is selected to convert infrared radiation into ultraviolet and visible radiation wherein the wavelength of the ultraviolet radiation is 350-370 nm, blue light is 450-480 nm, the green light is 500-550 nm and the red light 630-680 nm.

10. The device of claim 9 wherein the alkaline earth fluoride is barium fluoride and the mixture of rare-earth earth fluorides is selected from the group consisting of yttrium fluoride, ytterbium fluoride, erbium fluoride, thulium fluoride, holmium fluoride, and combinations thereof.

11. A device as claimed in claim 9, wherein said glassy phosphor film has a thickness of about 2 μ

m or less.

12. A method of making a device for converting IR or red light into red, green, blue, and ultraviolet light comprising:

providing a substrate and forming by electron beam deposition or thermal evaporation thin amorphous phosphor film at a temperature of less than 240°

C., such film being formed of an alkaline earth fluoride, and a mixture of rare-earth fluorides on the substrate, of a thickness of about 2 μ

m or less, and having an index of refraction greater than the substrate and which is selected to convert invisible IR radiation into visible light into ultraviolet, blue, green and red visible light wherein the wavelength of the ultraviolet is 350-370 nm, blue light is 440-490 nm, the green light is 500-560 nm and the red light 630-680 nm.

13. A device for converting IR or red light into red, green, blue, and/or ultraviolet light comprising:

a source of radiation having a wavelength near 800 to 1100 nm a substrate and a thin amorphous glassy phosphor film including an alkaline earth fluoride, and a mixture of rare-earth fluorides on the substrate and having an index of refraction greater than the substrate and which is selected to convert infrared radiation into ultraviolet and visible radiation wherein the wavelength of the ultraviolet radiation is 350-370 nm, blue light is 450-480 nm, the green light is 500-550 nm and the red light 630-680 nm.

14. A device as claimed in claim 13, wherein said glassy phosphor film has a thickness of about 2 μ

m or less.