Detection of thermal damage in composite materials using low field nuclear magnetc resonance testing

• US 5,786,691 A
• Filed: 01/30/1997
• Issued: 07/28/1998
• Est. Priority Date: 01/30/1997
• Status: Expired due to Term

• Current Assignee: Mcdonnell Douglas Corporation (The Boeing Co.)
• Original Assignee: Mcdonnell Douglas Corporation (The Boeing Co.)
• Inventors: Stoddard, Ronald D., Conradi, Mark S., Palmer, Donald D. Jr.
• Primary Examiner(s): Arana, Louis M.
• Application Number:
  US08/791,812
• Time in Patent Office: 544 Days
• Field of Search: 324/300, 324/303, 324/307, 324/309, 324/306
• US Class Current: 324/300
• CPC Class Codes: G01R 33/44 using nuclear magnetic resonance [NMR] G01R33/24, G01R33/62 take precedence

Abstract

Thermal damage in resin-matrix composite materials is detected using a low field NMR nondestructive testing technique. The technique involves subjecting the resin-matrix composite material to an NMR measurement of the spin-lattice relaxation (T₁) at a low magnetic field strength and/or the spin-lattice relaxation of local field order (T_1D) at any field strength. Thermal damage is evident as an increase in T₁ and T_1D.

Claims

1. A nondestructive method for detecting thermal damage in a specimen which is already manufactured, comprising subjecting the specimen to an NMR evaluation to obtain at least one of a spin-lattice relaxation value and a spin-lattice relaxation of local field order value, and comparing the thus obtained value or values to data indicative of a relationship between a magnitude of the obtained value or values and thermal damage of the specimen.

2. A method as claimed in claim 1, wherein the specimen is a resin-matrix composite material.

3. A method as claimed in claim 2, wherein the NMR evaluation includes measuring a spin-lattice relaxation value at a low magnetic field strength.

4. A method as claimed in claim 3, wherein the low magnetic field strength is in a range of 0.1 to 2.0 Tesla.

5. A method as claimed in claim 2, wherein the NMR evaluation includes measuring the spin-lattice relaxation of local field order.

6. A method for preparing comparison data for use in the nondestructive detection of thermal damage in a specimen which is already manufactured, comprising subjecting each of a plurality of like test specimens to a respective plurality of different elevated temperatures extending over a given temperature range, the temperature range including temperatures at which the specimen would suffer thermal damage, and, after cooling of each test specimen, subjecting each test specimen to an NMR evaluation to obtain at least one of a spin-lattice relaxation value and a spin-lattice relaxation of local field order value for each specimen, wherein the obtained value or values for each specimen is correlated with the elevated temperature of the specimen to form the comparison data, and wherein an increase in the value or values with an increase in temperature is indicative of thermal damage.

7. A method as claimed in claim 6, wherein each specimen is a resin-matrix composite material.

8. A method as claimed in claim 7, wherein the NMR evaluation includes measuring a spin-lattice relaxation value at a low magnetic field strength.

9. A method as claimed in claim 8, wherein the low magnetic field strength is in a range of 0.1 to 2.0 Tesla.

10. A method as claimed in claim 7, wherein the NMR evaluation includes measuring the spin-lattice relaxation of local field order.

11. A method for detecting thermal damage in an already-manufactured specimen made of a composite material, including the steps of:

using an NMR measurement device positioned completely external to the specimen to obtain NMR data about the specimen; and

,

using the NMR data to detect thermal damage in the specimen.

12. The method as set forth in claim 11, wherein the specimen comprises an aircraft part.

13. The method as set forth in claim 11, wherein the composite material comprises a resin-matrix composite material.

14. The method as set forth in claim 11, wherein the step of using an NMR measurement device is performed using a low magnetic field strength.

15. The method as set forth in claim 14, wherein the low magnetic field strength is in a range of 0.1 to 2.0 Tesla.

16. The method as set forth in claim 11, wherein the NMR data includes at least one of a spin-lattice relaxation value and a spin-lattice relaxation of local field order value of the composite material.