Barrier film having high colorless transparency and method

• US 5,792,550 A
• Filed: 04/28/1995
• Issued: 08/11/1998
• Est. Priority Date: 10/24/1989
• Status: Expired due to Term

• Current Assignee: Viavi Solutions, Inc. (Lumentum Holdings Inc.)
• Original Assignee: Flex Products Incorporated (Sicpa Holding SA)
• Inventors: Todd, David W., Phillips, Roger W., Tan-Johnson, Myra, Wendt, Lauren R.
• Primary Examiner(s): Speer, Timothy M.
• Application Number:
  US08/430,250
• Time in Patent Office: 1,201 Days
• Field of Search: 428/34.4, 428/34.6, 428/34.8, 428/35.2, 428/35.4, 428/35.7, 428/213, 428/220, 428/336, 428/339, 428/347, 428/480, 428/483, 428/446, 428/701, 428/702, 428/448
• US Class Current: 428/336
• CPC Class Codes: B32B 27/06 as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to a layer of a particular substance B32B9/045; next to a bituminous or tarry layer B32B11/046; next to a water setting substance layer B32B13/12; next to a metal layer B32B15/08; next to a glass layer B32B17/10; next to a layer formed of natural mineral fibres or particles B32B19/045; next to a wood layer B32B21/08; next to a cellulosic plastic layer B32B23/08; next to a natural or synthetic rubber layer B32B25/08
• CPC Class Codes: C23C 14/08 Oxides C23C14/10 takes precedence
• CPC Class Codes: C23C 14/081 of aluminium, magnesium or beryllium
• CPC Class Codes: Y10T 428/2495 Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/269 including synthetic resin or polymer layer or component
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers

Abstract

Barrier film with a high colorless transparency comprising a flexible plastic substrate. A barrier layer is formed on the surface and has a thickness ranging from approximately 50 to 100 Angstroms and is formed of a material selected from the group of aluminum oxide, tin oxide and yttrium oxide. An additional barrier layer formed of silicon dioxide may also be formed on the barrier layer.

Claims

1. A barrier film consisting of a flexible transparent substrate having a thickness ranging from approximately 1/2 mil to 4 mils and having a surface and a thin film vacuum-deposited barrier coating formed on said surface, said barrier coating being formed as a single layer of a single material having a thickness ranging from approximately 50 to less than 200 Å

and being formed of a dielectric material selected from the group consisting of aluminum oxide, yttrium oxide and a mixed oxide alloy consisting of 65% SiO₂ and 35% MgO, said barrier coating in combination with said flexible transparent substrate forming a film having a water white high colorless transparency and being impermeable to water and oxygen.

2. A barrier film as in claim 1 wherein said barrier coating is formed of aluminum oxide.

3. A barrier film as in claim 1 wherein said aluminum oxide has a purity of 99% or better.

4. A barrier film as in claim 1 wherein said substrate is formed essentially of polypropylene.

5. A barrier film as in claim 4 together with an additional substrate formed of a polypropylene having a barrier coating deposited on the surface, a laminating adhesive adhering the barrier coating of the first named substrate to the barrier coating of the additional substrate.

6. A barrier film as in claim 1 wherein the substrate is provided with an additional surface together with a heat seal layer disposed on the additional surface.

7. A barrier film as in claim 1 together with a laminated heat seal layer disposed on the barrier coating.

8. A barrier film consisting of a flexible transparent substrate having a thickness ranging from approximately 1/2 mil to 4 mils and having a surface and a thin film vacuum-deposited barrier coating formed on said surface, said barrier coating being formed as a single layer of a single material having a thickness ranging from approximately 50 to less than 200 Å

and being formed of a dielectric material selected from the group consisting of aluminum oxide, yttrium oxide and a mixed oxide alloy consisting of 65% SiO₂ and 35% MgO, said barrier coating in combination with said flexible transparent substrate forming a film having a water white high colorless transparency and being impermeable to water and oxygen, said substrate being provided with an additional surface opposite the first named surface and a barrier coating formed on the additional surface, said barrier coating on said additional surface being formed as a single layer of a single material having a thickness ranging from approximately 50 to less than 200 Angstroms and being formed of a material selected from the group consisting of aluminum oxide, yttrium oxide and a mixed alloy consisting of 65% SiO₂ and 35% MgO.

9. A barrier film as in claim 8 together with a heat seal layer formed on at least one of said barrier coatings.

10. A barrier film as in claim 9 together with a heat seal layer formed on each of the barrier coatings.

11. A barrier film consisting of a flexible plastic substrate having a thickness ranging from approximately 1/2 mil to 4 mils and having a surface and a thin film vacuum-deposited barrier coating formed on said surface, said barrier coating being formed of a combination of at least two layers of at least two different materials having an overall thickness ranging from 300 to 600 Å

with one of said at least two layers being a nucleation layer formed of a material selected from the group consisting of aluminum oxide, tin oxide, yttrium oxide and a mixed oxide alloy consisting of 65% SiO₂ and 35% MgO, the other of said at least two layers being formed of a material selected from silicon dioxide and a mixed oxide alloy consisting of 65% SiO₂ and 35% MgO, said barrier coating in combination with said flexible plastic substrate forming a barrier film having a water white high colorless transparency in the visible region and being impermeable to water and oxygen.

12. A barrier film as in claim 11 wherein said nucleation layer is formed of aluminum oxide.

13. A barrier film as in claim 11 wherein the nucleation layer is formed of a material having a purity of 99% or better.

14. A barrier film as in claim 11 wherein said plastic substrate is formed essentially of a polyester.

15. A barrier film as in claim 11 wherein said substrate is formed essentially of a polypropylene.

16. A barrier film as in claim 15 wherein the substrate is provided with an additional surface together with a propylene heat seal layer disposed on the additional surface.

17. A barrier film as in claim 11 together with a heat seal layer disposed on the barrier coating.

18. A barrier film as in claim 11 wherein the substrate is provided with an additional surface opposite the first named surface and a vacuum deposited barrier coating formed on said additional surface and being formed of a combination of at least two layers of at least two different materials having an overall thickness ranging from 300 to 600 Angstroms with one of said at least two layers being a nucleation layer formed of a material selected from the group consisting of aluminum oxide, tin oxide, yttrium oxide and a mixed oxide alloy consisting of 65% SiO₂ and 35% MgO, the other of said at least two layers being formed of a material selected from silicon dioxide and a mixed oxide alloy consisting of 65% SiO₂ and 35% MgO.

19. A barrier film as in claim 18 together with a heat seal layer carried by the substrate on one of said first named and additional surfaces.

20. A barrier film as in claim 18 wherein the nucleation layer of the at least two layers on the additional surface has a thickness ranging from 50 to 180 Angstroms and wherein the other layer of the at least two layers of silicon dioxide on the additional surface has a thickness ranging from 100 to 500 Angstroms.

21. A barrier film as in claim 11 together with a laminating sheet formed essentially of polypropylene and a laminating adhesive adhering the laminating sheet to the thin film barrier coating.

22. A barrier film as in claim 11 together with a heat seal coating deposited on the thin film barrier coating.

23. A barrier film as in claim 22 together with a heat seal coating on the substrate on the opposite side on which the thin film barrier coating is provided.

24. A barrier film as in claim 22 together with an additional substrate formed essentially of polypropylene having a barrier coating deposited on the surface and a laminating adhesive adhering the thin film barrier coating of the first named substrate to the barrier coating of the additional substrate surface.