Method for preserving precision edges using diamond-like nanocomposite film coatings

• US 5,795,648 A
• Filed: 10/03/1995
• Issued: 08/18/1998
• Est. Priority Date: 10/03/1995
• Status: Expired due to Fees

• Current Assignee: NV Bekaert SA
• Original Assignee: Advanced Refractory Technologies, Inc.
• Inventors: Bray, Donald J., Goel, Arvind
• Primary Examiner(s): TURNER, ARCHENE A
• Application Number:
  US08/538,731
• Time in Patent Office: 1,050 Days
• Field of Search: 428/408, 428/446, 428/336, 428/457, 428/697, 30/346.53, 30/346.54, 30/346.55, 427/249, 427/255.3, 427/574, 427/578
• US Class Current: 428/336
• CPC Class Codes: B26B 21/60 by the coating material
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C23C 16/30 Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
• CPC Class Codes: C23C 16/44 characterised by the method of coating C23C16/04 takes precedence
• CPC Class Codes: C23C 16/4483 using a porous body
• CPC Class Codes: C23C 16/503 using dc or ac discharges
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

A method for preserving the precision-edges of a precision-edged substrate by applying to a the substrate a corrosion resistant coating comprising a diamond-like solid state material having interpenetrating atomic scale networks comprising a first diamond-like carbon network stabilized by hydrogen, a silicon network stabilized by oxygen, and optionally at least one network made from dopant elements or dopant compounds containing elements from Groups 1-7b and 8 of the periodic table.

Claims

1. A method for preserving a precision edge of a precision-edged substrate comprising:

providing a precision-edged substrate, wherein the precision-edged substrate is a cutting apparatus; and

applying to said substrate a coating made from a diamond-like solid state material formed from interpenetrating networks comprising a diamond-like carbon network stabilized by hydrogen, a silicon network stabilized by oxygen, and optionally at least one network made from dopant elements or dopant compounds containing elements from Groups 1-7b and 8 of the periodic table.

2. The method according to claim 1, wherein the carbon, hydrogen, silicon and oxygen are obtained from the decomposition of an organosiloxane having from about 1 to about 10 silicon atoms.

3. The method according to claim 2, wherein the organosiloxane is polyphenylmethylsiloxane.

4. The method according to claim 1, wherein the carbon content of the coating is from about 40 wt. % to about 98 wt. %.

5. The method according to claim 1, wherein the carbon content of the coating is from about 50 wt.% to about 98 wt.%.

6. The method according to claim 1, wherein the carbon to silicon weight ratio of the coating is from about 2:

1 to about 8;

1.

7. The method according to claim 1, wherein the silicon to oxygen weight ratio of the coating is from about 0.5:

1 to about 3;

1.

8. The method according to claim 1, wherein the coating is deposited on a metal substrate.

9. The method according to claim 1, wherein the coating is deposited on a non-metal substrate.

10. The method according to claim 1, wherein the dopant elements are selected from the group consisting of B, Si, Ge, Te, O, Mo, W, Ta, Nb, Pd, Ir, Pt, V, Fe, Co, Mg, Mn, Ni, Ti, Zr, Cr, Re, Hf, Cu, Al, N, Ag, and Au.

11. The method according to claim 1, wherein the coating is deposited on the substrate to a thickness of from about 5 nm to about 12 micrometers.

12. The method according to claim 1, wherein the coating is deposited on the substrate to a thickness of from about 5 nm to about 150 nm.

13. The method according to claim 1, wherein the carbon content of the diamond-like solid state material is greater than about 40 atomic % of the DLN, the hydrogen content is up to about 40 atomic % of the carbon, and the sum of the silicon, oxygen and dopants together is greater than about 2 atomic % of the DLN.

14. A cutting apparatus comprising a precision-edged substrate coated with a precision-edge preserving coating, said coating comprising a diamond-like solid state material formed from interpenetrating networks comprising a first diamond-like carbon network stabilized by hydrogen, a second silicon network stabilized by oxygen and, optionally, at least one network of dopant elements, or dopant compounds containing elements from Groups 1-7b and 8 of the periodic table.

15. The apparatus according to claim 14, wherein the carbon, hydrogen, silicon and oxygen are obtained from the decomposition of an organosiloxane having from about 1 to about 10 silicon atoms.

16. The apparatus according to claim 15, wherein the organosiloxane is polyphenylmethylsiloxane.

17. The apparatus according to claim 14, wherein the carbon content of the coating is from about 40 wt. % to about 98 wt. %.

18. The apparatus according to claim 14, wherein the carbon content of the coating is from about 50 wt. % to about 98 wt. %.

19. The apparatus according to claim 14, wherein the carbon to silicon weight ratio of the coating is from about 2:

1 to about 8;

1.

20. The apparatus according to claim 14, wherein the silicon to oxygen weight ratio of the coating is from about 0.5:

1 to about 3;

1.

21. The apparatus according to claim 14, wherein the substrate comprises a metal.

22. The apparatus according to claim 14, wherein the substrate comprises a non-metal.

23. The apparatus according to claim 14, wherein the dopant elements are selected from the group consisting of B, Si, Ge, Te, O, Mo, W, Ta, Nb, Pd, Ir, Pt, V, Fe, Co, Mg, Mn, Ni, Ti, Zr, Cr, Re, Hf, Cu, Al, N, Ag, and Au.

24. The apparatus according to claim 14, wherein the carbon content of the solid state material is at least 40 atomic % of the coating, the hydrogen content is up to about 40 atomic % of the carbon, and the sum of the silicon, oxygen and dopants together is greater than about 2 atomic % of the coating.

25. The apparatus according to claim 14, wherein the coating is deposited on the substrate to a thickness of from about 5 nm to about 12 micrometers.

26. The apparatus according to claim 14, wherein the coating is deposited on the substrate to a thickness of from about 5 nm to about 150 nm.

27. The apparatus according to claim 14, wherein the apparatus is selected from the group consisting of industrial tools, surgical instruments, knives and razors.

28. The apparatus according to claim 14, wherein the apparatus is a razor blade.