Method of manufacturing a switchable cholesteric filter as well as a luminaire having such a filter

• US 5,798,057 A
• Filed: 12/18/1996
• Issued: 08/25/1998
• Est. Priority Date: 12/21/1995
• Status: Expired due to Fees

• Current Assignee: US Philips Corporation (Koninklijke Philips N.V.)
• Original Assignee: US Philips Corporation (Koninklijke Philips N.V.)
• Inventors: Hikmet, Rifat A. M.
• Primary Examiner(s): Wo, Shean C.
• Application Number:
  US08/768,476
• Time in Patent Office: 615 Days
• Field of Search: 252/299.01, 252/299.5, 428/1, 349/183, 349/185, 349/104, 349/106, 438/30
• US Class Current: 252/299.5
• CPC Class Codes: C09K 19/38 Polymers
• CPC Class Codes: C09K 19/542 Macromolecular compounds
• CPC Class Codes: C09K 2323/057 Ester polymer, e.g. polycarbonate, polyacrylate or polyester
• CPC Class Codes: F21V 9/14 for producing polarised light
• CPC Class Codes: G02F 1/13345 Network or three-dimensional gels
• CPC Class Codes: G02F 1/13718 based on a change of the texture state of a cholesteric liquid crystal

Abstract

The invention provides a simple method of manufacturing a broadband, switchable cholesteric filter. To this end, a mixture of polymerizable, liquid-crystalline molecules is provided between two, substantially parallel substrates, which are each provided with an electrode. This mixture is subsequently polymerized with UV light to form an optically active layer of cholesteric order comprising a three-dimensional polymeric network. If the mixture also contains a quantity of a photo-stabilizing compound, a broadband, cholesteric filter is obtained. The mixture preferably comprises, in addition to maximally 5 wt. % of the photo-stabilizing compound, maximally 2 wt. % of monomers having at least two polymerizable groups, maximally 90 wt. % of liquid-crystalline monomers having one polymerizable group, as well as a mixture of chiral and/or achiral liquid-crystalline molecules without a polymerizable group. Switchable cholesteric filters having a bandwidth of 200 nm and more can be obtained in this manner.

Claims

1. A method of manufacturing a switchable cholesteric filter comprising an optically active layer, in which a mixture of polymerizable, liquid-crystalline molecules is provided between two, substantially parallel substrates, which are each provided with an electrode for applying an electric field, said mixture subsequently being polymerized by means of UV light to form an optically active layer of cholesteric order comprising a three-dimensional network, characterized in that a quantity of a photo-stabilizing compound is added to the mixture, said quantity being not greater than about 5 wt. % of the overall volume of the mixture.

2. A method as claimed in claim 1, characterized in that a compound of the "excited state quencher" type is added as the photo-stabilizing compound.

3. A method as claimed in claim 2, characterized in that for the photo-stabilizing compound use is made of a compound whose composition corresponds to the formula ##STR3## where X, Y and Z are moieties selected from the group consisting of H, OH, CH₃ and C(CH₃)₃.

4. A method as claimed in claim 2, characterized in that for the photo-stabilizing compound use is made of a compound whose composition corresponds to the formula ##STR4## where X and Y are moieties selected from the groups consisting of H and an electron-accepting group such as CN or NO₂, and where R and R'"'"' are moieties from the groups consisting of H, an electron-accepting group such as CN or NO₂, an aliphatic group and an aromatic group.

5. A method as claimed in claim 1, characterized in that the mixture contains maximally 2 wt. % of monomers having at least two polymerizable groups, maximally 90 wt. % of liquid-crystalline monomers having one polymerizable group as well as a mixture of chiral and/or achiral liquid-crystalline molecules without a polymerizable group.

6. A method as claimed in claim 5, characterized in that the monomers having at least two polymerizable groups also include a liquid-crystalline group.

7. A method as claimed in claim 5, characterized in that (meth)acrylate groups are used as the polymerizable groups of the monomers.

8. A luminaire provided with a connection for a light source and with a cholesteric filter, characterized in that a switchable, cholesteric filter, as manufactured by means of the method claimed in claim 1 is used.