Composite membrane and use thereof for synthesis of hydrogen peroxide

• US 5,800,796 A
• Filed: 10/04/1996
• Issued: 09/01/1998
• Est. Priority Date: 10/06/1995
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Webb, Steven P., McIntyre, James A.
• Primary Examiner(s): LANGEL, WAYNE A
• Application Number:
  US08/725,786
• Time in Patent Office: 697 Days
• Field of Search: 422/211, 96/4, 96/7, 423/584
• US Class Current: 423/584
• CPC Class Codes: B01J 2231/60 Reduction reactions, e.g. hydrogenation
• CPC Class Codes: B01J 2231/70 Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
• CPC Class Codes: B01J 31/06 containing polymers organometallic polymers B01J31/123; polymer-bound organometallic complexes B01J31/165; coordination polymers B01J31/1691
• CPC Class Codes: B01J 31/10 sulfonated
• CPC Class Codes: B01J 31/26 containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
• CPC Class Codes: B01J 35/59 Membranes
• CPC Class Codes: C01B 15/029 Preparation from hydrogen and oxygen
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers

Abstract

This invention is a composite membrane for chemical synthesis, a chemical reactor into which the composite membrane might be incorporated, and a method of using the composite membrane. The composite membrane comprises a substrate, a first side, and a second side, wherein the substrate operatively connects the first side and second side, the first side comprises an oxidizing catalyst and the second side comprises a reducing catalyst. The reducing catalyst comprises, in elemental or combinative form, lanthanum, zinc, cerium, praeseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, bismuth, or indium. A chemical reactor utilizing this composite membrane can react hydrogen and oxygen to form hydrogen peroxide without direct mixture of the reactants.

Claims

1. A method for synthesis of hydrogen peroxide using a composite membrane having a substrate, a hydrogen contact side, and an oxygen contact side, wherein the method comprises:

(a) placing hydrogen in contact with the hydrogen contact side of the composite membrane to produce at least one electron and at least one proton;

(b) placing oxygen in contact with the oxygen contact side of the composite membrane; and

(c) conducting the at least one electron and the at least one proton produced in step (a) to an interface between the oxygen contact side of the composite membrane and the oxygen such that the at least one electron and the at least one proton react with the oxygen to form a reaction product comprising hydrogen peroxide

wherein the substrate operatively connects the hydrogen contact side and the oxygen contact side, the hydrogen contact side comprises an oxidizing catalyst, and the oxygen contact side comprises a reducing catalyst which comprises, in elemental or combinative form, lanthanum, zinc, cerium, praeseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, bismuth, or indium.

2. The method of claim 1 wherein the hydrogen in step (a) is provided as a hydrogen containing mixture.

3. The method of claim 2 wherein the hydrogen containing mixture comprises hydrogen and water.

4. The method of claim 1 wherein the hydrogen in step (a) is provided as a hydrogen containing compound.

5. The method of claim 1 wherein the oxygen in step (b) is provided as an oxygen containing mixture.

6. The method of claim 5 wherein the oxygen containing mixture comprises oxygen and water.

7. The method of claim 1 wherein the reactor is maintained at a temperature of from 2°

C. to 30°

C.

8. The method of claim 1 wherein the hydrogen and oxygen are placed in contact with the composite membrane at a pressure of greater than 100 psi (689 kPa).

9. The method of claim 1 wherein the reducing catalyst comprises, in elemental or combinative form, gadolinium, zinc, or lanthanum.

10. The method of claim 1 wherein the reducing catalyst is an oxide.

11. The method of claim 1 wherein the reducing catalyst is lanthanum phosphopolytungstate.

12. The method of claim 1 wherein the oxidizing catalyst comprises, in elemental or combinative form, palladium, platinum, or iridium.

13. The method of claim 1 wherein the substrate is a polymeric-based membrane.

14. The method of claim 13 wherein the polymeric-based membrane is organic.

15. The method of claim 14 wherein the organic, polymeric-based membrane comprises a polymeric perfluorosulfonic acid.